https://orcid.org/0000-0003-2063-5671
Abstract
This study evaluated whether use of a high-vinyl styrene-butadiene-styrene (SBS) copolymer can provide adequate phase stability to highly modified asphalt (HiMA). An asphalt binder was modified with 7.5 % high-vinyl SBS to produce HiMA. A conventional polymer-modified asphalt was produced with 4 % SBS without vinyl and, together with the base asphalt, considered as reference samples. In the first phase, samples were analyzed considering unaged and short-term aged conditions. The experimental procedure analyzed binder morphology using fluorescence microscopy and determined chemical functional groups through Fourier transform infrared spectroscopy (FTIR). Rheological behavior at intermediate temperatures was evaluated concerning dynamic shear modulus, phase angle, and linear amplitude sweep (LAS) tests at 20°C. High-temperature properties, including apparent viscosity, performance grade, aging index, and multiple stress creep and recovery (MSCR) test, were also assessed. In the second phase, unaged asphalt binders were subjected to storage stability test, and the top and bottom sections were evaluated through fluorescence microscopy, FTIR, LAS, and MSCR tests. The samples with 7.5 % high vinyl SBS exhibited enhanced fatigue tolerance in the LAS test compared to base asphalt (14.35 times higher at 15 % shear strain) and samples with 4 % SBS without vinyl (6.62 times higher at 15 % shear strain). Additionally, it displayed superior resistance to deformation accumulation at high temperatures (ε10 parameter from MSCR) compared to base asphalt (99.65 % smaller at 64°C) and samples with 4 % SBS without vinyl (93.05 % smaller at 64°C). However, the storage stability of the asphalt samples with 7.5 % high vinyl SBS was compromised due to phase separation, severely impacting the rheological performance at intermediate and high temperatures. It was concluded that the incorporation of high levels positively impacts mechanical/rheological performance, but the molecular characteristics of the high vinyl SBS are not capable of providing adequate storage stability at a content of 7.5 %.
Issue Section:
Technical Papers
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Standard Test Method for Flash and Fire Points by Cleveland Open Cup Tester
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Standard Test Method for Effect of Heat and Air on a Moving Film of Asphalt (Rolling Thin-Film Oven Test)
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, approved May 1, 2022
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Standard Test Method for Penetration of Bituminous Materials
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Standard Test Method for Softening Point of Bitumen (Ring and-Ball Apparatus)
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, 2012
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, 2022
).97.
Petroleum Products - Determination of the Flash and Fire Points by Cleveland Open Cup (in Portuguese)
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, 2014
).98.
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, NBR 15235 (Rio de Janeiro, Brazil: ABNT
, 2009
).99.
Bituminous Materials - Determination of Penetration (in Portuguese)
, NBR 6576 (Rio de Janeiro, Brazil: ABNT
, 2007
).100.
Asphaltic Binders - Determination of the Softening Point - Ring-and-Ball Method (in Portuguese)
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, 2016
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, 2015
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