Falling particle receivers are being evaluated as an alternative to conventional fluid-based solar receivers to enable higher temperatures and higher efficiency power cycles with direct storage for concentrating solar power applications. This paper presents studies of the particle mass flow rate, velocity, particle-curtain opacity and density, and other characteristics of free-falling ceramic particles as a function of different discharge slot apertures. The methods to characterize the particle flow are described, and results are compared to theoretical and numerical models for unheated conditions.

Several studies predict an economic benefit of using nitrate-based salts instead of the current synthetic oil within a solar parabolic trough field. However, the expected economic benefit can only be realized if the reliability and optical performance of the salt trough system is comparable to today’s oil trough. Of primary concern is whether a salt-freeze accident and subsequent thaw will lead to damage of the heat collection elements (HCEs). This topic was investigated by experiments and analytical analysis. Results to date suggest that damage will not occur if the HCEs are not completely filled with salt. However, if the HCE is completely filled at the time of the freeze, the subsequent thaw can lead to plastic deformation and significant bending of the absorber tube.

Metal-oxide based thermochemical cycles, such as those including a class of iron containing materials commonly known as ferrites, involve two reaction steps: a thermal reduction at temperatures up to 1600 °C driven by a solar energy input, and a lower temperature exothermic oxidation in the presence of either carbon dioxide or water. In order to maximize performance, the reactive materials must be arranged into structures that provide an effective interface for the direct absorption of concentrated solar energy and also have relatively high surface area to support rapid chemical reactions. In this paper we discuss the attributes of reactive structures for solar thermochemical processes as well as some of the fabrication techniques currently under development at Sandia National Labs. One of these structures has been demonstrated on-sun in a two step carbon dioxide splitting cycle. The results, given in this paper, indicate that performance may be improved as the fraction of the total directly illuminated surface area is increased, reducing the need to rely on conduction or convection to distribute heat throughout the material.

A prototype direct absorption central receiver, called the solid particle receiver (SPR), was recently built and tested on-sun at Sandia National Laboratories. The SPR consists of a 6 m tall cavity through which a 1 m wide curtain of spherical ceramic particles is dropped and directly heated with concentrated solar energy. The focus of this current effort is to provide an experimental basis for the validation of computational models that have been created to support the development of the solid particle receiver as a solar interface for thermochemical hydrogen and solar power systems. In this paper we present detailed information on the design and construction of the receiver as well as test data including the temperature change of the particles and internal cavity walls. We conclude with a discussion of the steps needed to demonstrate the overall feasibility of the SPR concept.

The solid particle receiver (SPR) is a direct absorption central receiver that can provide a solar interface with thermal storage for thermochemical hydrogen production processes requiring heat input at temperatures up to 1000 C. In operation, a curtain consisting of ∼690 μm ceramic particles is dropped within the receiver cavity and directly illuminated by concentrated solar energy. The heated particles exit the receiver and may either be stored or sent through a heat exchanger to provide process heat input. The performance of the receiver is dependent on the characteristics of the particle flow including velocity and opacity (optical density). In addition, because the SPR will have an open aperture there is also a possibility that the flow may be disturbed by high ambient winds. Computational models have been and are currently being used to simulate receiver performance at power levels up to several MW t . However, due to the complex two-phase nature of the solid particle flow, such models rely on experimental data both to provide physical input, such as boundary conditions, as well as to provide a point of comparison for model validation. In this paper, we present experimental results from tests performed using a small scale unheated solid particle curtain. These tests focus on the measurement of the flow characteristics of the solid particle curtain as it falls from a near-zero velocity discharge slot to a collection point three meters below. The results include measured values for the variation of velocity, solids volume fraction, curtain width, and curtain opacity along the length of the curtain.

Solar thermo-chemical processes often require high temperatures that can be achieved by direct absorption of solar energy. The solid particle solar receiver can be used to heat ceramic particles that may serve as a heat transfer and storage medium or as a substrate on which chemical reaction may be performed directly. Using solid particles enclosed in a cavity to absorb concentrated solar radiation can provide efficient absorption of concentrated sunlight. In this work, different solid particle solar receiver designs have been investigated by using computation fluid dynamics (CFD) technique. The gas particle flow with the solid particle solar receiver was simulated by using two-way coupled Euler-Lagrange method. The direct illumination energy source that results from incident solar radiation was predicted by a solar load model using a solar ray tracing algorithm. The detailed information to guide the experiment, such as the particle and gas velocity, temperature, particle solid volume fraction, and cavity efficiency under different designs has been analyzed.

Solar power towers can be used to make hydrogen on a large scale. Electrolyzers could be used to convert solar electricity produced by the power tower to hydrogen, but this process is relatively inefficient. Rather, efficiency can be much improved if solar heat is directly converted to hydrogen via a thermochemical process. In the research summarized here, the marriage of a high-temperature (∼1000 °C) power tower with a sulfuric acid/hybrid thermochemical cycle (SAHT) was studied. The concept combines a solar power tower, a solid-particle receiver, a particle thermal energy storage system, and a hybrid-sulfuric-acid cycle. The cycle is “hybrid” because it produces hydrogen with a combination of thermal input and an electrolyzer. This solar thermochemical plant is predicted to produce hydrogen at a much lower cost than a solar-electrolyzer plant of similar size. To date, only small lab-scale tests have been conducted to demonstrate the feasibility of a few of the subsystems and a key immediate issue is demonstration of flow stability within the solid-particle receiver. The paper describes the systems analysis that led to the favorable economic conclusions and discusses the future development path.

A detailed three dimensional computational fluid dynamics (CFD) analysis on gas-particle flow and heat transfer inside a solid particle solar receiver, which utilizes free-falling particles for direct absorption of concentrated solar radiation, is presented. The two-way coupled Euler-Lagrange method is implemented and includes the exchange of heat and momentum between the gas phase and solid particles. A two band discrete ordinate method is included to investigate radiation heat transfer within the particle cloud and between the cloud and the internal surfaces of the receiver. The direct illumination energy source that results from incident solar radiation was predicted by a solar load model using a solar ray tracing algorithm. Two kinds of solid particle receivers, each having a different exit condition for the solid particles, are modeled to evaluate the thermal performance of the receiver. Parametric studies, where the particle size and mass flow rate are varied, are made to determine the optimal operating conditions. The results also include detailed information for the particle and gas velocity, temperature, particle solid volume fraction, and cavity efficiency.

A transient model of the cathode catalyst layer of a proton exchange membrane fuel cell is presented. The catalyst layer structure can be described as a superposition of the polymer membrane, the backing layer, and some additional platinum particles. The model, which incorporates some of the features of the pseudo-homogeneous models currently present in the literature, considers the kinetics of the electrochemical reaction taking place at the platinum surface, the proton transport through the polymer agglomerates, and the oxygen and water transport within the pores as well as the membrane material of the catalyst layer. Due to the lower porosity of this region and the higher liquid water content, the catalyst layer can be current limiting in the fuel cell. Furthermore, since the cost of the catalyst material is critical, it is important to have a model predicting the effective utilization of this catalyst layer as well as one, which gives insights into how it might be improved. Equations are presented for the mass conservation of reactants and products, the electrical and ionic currents, and the conservation of energy. A discussion of a number of the closure relations such as the Butler-Volmer equation employed is included as is a discussion of the initial and boundary conditions applied. The mathematical model is solved using a finite elements approach developed at I.U.S.T.I.