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J. Carrera
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Journal Articles
M. Hernández-Ortiz, J. D. Lozano-López, S. M. Durón, M. Galván-Valencia, Y. Estevez-Martínez, H. A. Durán-Muñoz, J. Carrera-Escobedo, O. Guirette-Barbosa, I. Ortiz-Medina, L. A. Ramírez-Hernández, V. M. Castaño-Meneses
Article Type: Research-Article
J. Micro Nano-Manuf. March 2019, 7(1): 011002.
Paper No: JMNM-18-1023
Published Online: May 15, 2019
Abstract
Various nanocarbons (NCs) were used to study their surface groups under standardized Bohem titration, including: multiwalled carbon nanotube (CNT), graphene (G), Vulcan carbon (VC), and nanodiamond (ND). Endpoint-measured titration using second derivative method to quantify carboxylic, lactonic, and phenolic groups created on treated carbon surfaces shows a high precision comparable to other recent reports and with errors of 1 order of magnitude lower. The results exhibit major concentration of carboxyl group increased after the NCs were oxidized compared to the amount of other functional groups like phenols and lactonic groups. It is important highlight, the concentration ratio of carboxyl group with VC:VC-O was showed at 1:77, exhibited a major result regarding other NCs which exhibited ratios of 1:4.5, 1:1.4, and 1:2.5 for ND:ND-O, CNT:CNT-O, and G:G-O, respectively. It is concluded that VC is a NC that competes and excels in its capacity of oxidation with respect to the popular NCs as CNT, graphene (G), and ND.
Proceedings Papers
Proc. ASME. ETCE2002, Engineering Technology Conference on Energy, Parts A and B, 29-35, February 4–5, 2002
Paper No: ETCE2002/CAE-29009
Abstract
The effects of buoyancy on the flow regimes of submerged gas injection were studied in this investigation. A capillary tube submerged in water was used for gas injection in microgravity and terrestrial conditions, and the resulting flow regimes and bubble sizes were documented. The effects of liquid co-flow and reduced surface tension were also analyzed. Under reduced gravity, three flow regimes were observed over the range of conditions tested. At low gas flow rates, the bubbles did not detach from the injector, forming an interconnected bubble cluster that adhered to the injector. Single bubbles started detaching and moving away from the injector when the Weber number reached a value around 3. At gas flow rates corresponding to a Weber number value of 10, the bubble coalescence regime was observed near the injector. It was found that the absence of buoyancy prevented the formation of the jetting regime. For all gas throughputs, the co-flowing liquid aided the detachment of the bubbles, resulting in the generation of more uniform bubbles than in quiescent liquids. The presence of co-flow resulted in a smaller bubble size accompanied by an increased frequency of bubble formation. Reduced surface tension produced a similar effect, resulting in smaller bubbles.