This paper presents a study on using high-pressure ammonia and abrasive ammonia jets for cutting and washout of chemical weapons. The work focused on chemical rocket M55 simulants. A test chamber was built to cut M60 training and M61 practice rockets at Redstone Arsenal by Teledyne-Commodore who developed a complete destruction process using alkali metals dissolved in anhydrous ammonia to form the aggressive solvated electron technology (SET™) solution. The rocket is loaded in a rotary chuck and stationary cutting/piercing nozzles were used to cut and drill through the rocket. This approach was found to be effective due to minimizing the number of moving parts. High-pressure direct drive and intensifier pumps were developed for this application. It was found that intensifier-based pumps are more suitable for robust field use. The abrasive ammonia jets performed well for cutting the rocket metal shell (aluminum and steel) casing as well as the outside fiberglass case. A wash-out-ammonia jet lance has also been found to completely wash out the simulant materials. Over 20 rockets were successfully cut by Teledyne personnel without any incidents. It was concluded that the use of anhydrous ammonia has numerous advantages over conventional water for chemical weapon demilitarization applications.

1.
Hendrickson, K. A., Losee, L. A., Stevens, P. M., and Mitchell, D. H., 1993, “Materials Hazards Testing in Support of the Army Large Rocket Motor Demilitarization Pilot Plant Materials,” Hercules Aerospace Company, Magna, UT, Joint 1993 JANAF Propulsion Meeting and 30th JANAF Combustion Subcommittee Meeting, Monterey, CA, [unclassified—approved for public release; unlimited distribution], Nov.
2.
Melvin, W. S., and Graham, J., 1993, “Method to Demilitarize Extract, and Recover Ammonium Perchlorate from Composite Propellant Using Liquid Ammonia,” U.S. Patent No. 4854982, Oct.
3.
Melvin, W. S., 1994, “Method to Extract and Recover Nitramine Oxidizers from Solid Propellants Using Liquid Ammonia”, U.S. Patent No. 5,285,995, Feb.
4.
Lienhard, J. H., and Day, J. B., 1970 “The Breakup of Superheated Liquid Jets,” ASME J. Basic Eng., Sept., pp. 515–522.
5.
Dunsky, C., and Hashish, M., 1995, “Feasibility Study of the Use of Ultrahigh Pressure Liquified Gas Jets for Machining of Nuclear Fuel Pins,” Proc. 8th American Water Jet Conference, Houston, TX, Aug., pp. 505–517.
6.
Dunsky, C., and Hashish, M., 1996, “Observations on Cutting with Abrasive-Cryogenic Jets,” Proc. 13th Int. Water Jet Cutting Technology Conference, BHR Group, Sardinia, Italy, Oct., pp. 679–690.
7.
Savanik, G., 1994, “Nitrogen Jet” Jet News, Waterjet Technology Association, Feb.
8.
Lauriente, D. H., 1995, Chemical Economics Handbook, cited in http://www-cmrc.sri.com/CIN.
9.
National Institute of Standards and Technology (NIST), 1998, “Saturation Properties for Ammonia–Pressure Increments,” from NIST Standard Reference Database, NIST Chemistry WebBook, http://webbook.nist.gov/cgi.
10.
Pinevich, G., 1948, Kholod. Tekh. Vol. 20, No. 3, pp. 30, as cited in Jolly, W. L., and Hallada, C. J., 1965, “Liquid Ammonia,” Non-Aqueous Solvent Systems, T. C. Waddington, ed., Academic Press, pp. 1–45.
11.
Stairs, R. A., and Sienko, M. J., 1956, J. Amer. Chem. Soc., 78, pp. 920, as cited in Jolly, W. L., and Hallada, C. J., 1965, “Liquid Ammonia,” Non-Aqueous Solvent Systems, T. C. Waddington, ed., Academic Press, pp. 1–45.
12.
Hashish, M., 1989, “Pressure Effects in Abrasive-Waterjet Machining,” ASME J. Eng. Mater. Technol., 111, pp. 221–228.
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