Alloy 800HT is one promising candidate for use as a fuel cladding material in supercritical water-cooled rectors. In the present study, specific thermomechanical processing (TMP) was used to study the effects of grain size and grain boundary character distribution (GBCD) on the oxidation behavior of alloy 800HT in supercritical water (SCW). The processed samples were exposed to SCW at 600°C and 25 MPa for 100, 300, and 1000 h. The results showed that grain size and grain boundaries are important factors that affect the oxidation behavior of alloy 800HT in SCW. We also found that TMP improves the adhesion and integrity of the oxide scale.
Issue Section:
Research Papers
References
1.
Sun
, C.
, Hui
, R.
, Qu
, W.
, and Yick
, S.
, 2009
, “Progress in Corrosion Resistant Materials for Supercritical Water Reactors
,” Corros. Sci.
, 51
(11
), pp. 2508
–2523
. 0010-938X10.1016/j.corsci.2009.07.0072.
Kritzer
, P.
, 2004
, “Corrosion in High-Temperature and Supercritical Water and Aqueous Solutions: A Review
,” J. Supercrit. Fluids
, 29
(1–2
), pp. 1
–29
.10.1016/S0896-8446(03)00031-73.
Zhang
, L.
, Bao
, Y.
, and Tang
, R.
, 2012
, “Selection and Corrosion Evaluation Tests of Candidate SCWR Fuel Cladding Materials
,” Nucl. Eng. Des.
, 249
, pp. 180
–187
. 0029-549310.1016/j.nucengdes.2011.08.0864.
U.S. DOE Nuclear Energy Research Advisory Committee and the Generation IV International Forum
, 2002
, “A Technology Roadmap for Generation IV Nuclear Energy Systems
,” U.S. DOE Nuclear Energy Research Advisory Committee and the Generation IV International Forum
.5.
Azevedo
, C. R. F.
, 2011
, “Selection of Fuel Cladding Material for Nuclear Fission Reactors
,” Eng. Fail. Anal.
, 18
(8
), pp. 1943
–1962
. 1350-630710.1016/j.engfailanal.2011.06.0106.
The OECD Nuclear Energy Agency for the Gen IV International Forum
, 2014
, “Technology Roadmap Update for Generation IV Nuclear Energy Systems
,” The OECD Nuclear Energy Agency for the Gen IV International Forum
.7.
Fulger
, M.
, Mihalache
, M.
, Ohai
, D.
, Fulger
, S.
, and Valeca
, S.C.
, 2011
, “Analyses of Oxide Films Grown on AISI 304L Stainless Steel and Incoloy 800HT Exposed to Supercritical Water Environment
,” J. Nucl. Mater.
, 415
(2
), pp. 147
–157
. 0022-311510.1016/j.jnucmat.2011.05.0078.
Tan
, L.
, Allen
, T.R.
, and Yang
, Y.
, 2011
, “Corrosion Behavior of Alloy 800H (Fe–21Cr–32Ni) in Supercritical Water
,” Corros. Sci.
, 53
(2
), pp. 703
–711
. 0010-938X10.1016/j.corsci.2010.10.0219.
Ren
, W.
, and Swindeman
, R.
, 2010
, “A Review of Alloy 800H for Applications in the Gen IV Nuclear Energy Systems
,” Proceedings of the ASME Pressure Vessels and Piping Conference 2010
, Bellevue, Washington
, ASME
, Washington, DC
.10.
Roy
, A.K.
, and Virupaksha
, V.
, 2007
, “Performance of Alloy 800H for High-Temperature Heat Exchanger Applications
,” Mater. Sci. Eng. A
, 452–453
, pp. 665
–672
.11.
Was
, G.S.
, Ampornrat
, P.
, Gupta
, G.
, Teysseyre
, S.
, West
, E. A.
, Allen
, T.R.
, Sridharan
, K.
, Tan
, L.
, Chen
, Y.
, Ren
, X.
, and Pisterb
, C.
, 2007
, “Corrosion and Stress Corrosion Cracking in Supercritical Water
,” J. Nucl. Mater.
, 371
(1–3
), pp. 176
–201
. 0022-311510.1016/j.jnucmat.2007.05.01712.
Tan
, L.
, Sridharan
, K.
, and Allen
, T. R.
, 2006
, “The Effect of Grain Boundary Engineering on the Oxidation Behavior of INCOLOY Alloy 800H in Supercritical Water
,” J. Nucl. Mater.
, 348
(3
), pp. 263
–271
. 0022-311510.1016/j.jnucmat.2005.09.02313.
Tan
, L.
, Ren
, X.
, Sridharan
, K.
, and Allen
, T.R.
, 2008
, “Effect of Shot-Peening on the Oxidation of Alloy 800H Exposed to Supercritical Water and Cyclic Oxidation
,” Corros. Sci.
, 50
(7
), pp. 2040
–2046
.14.
Fulger
, M.
, Ohai
, D.
, Mihalache
, M.
, Pantiru
, M.
, and Malinovschi
, V.
, 2009
, “Oxidation Behavior of Incoloy 800 Under Simulated Supercritical Water Conditions
,” J. Nucl. Mater.
, 385
(2
), pp. 288
–293
. 0022-311510.1016/j.jnucmat.2008.12.00415.
Van Nieuwenhove
, R.
, Balak
, J.
, Toivonen
, A.
, Pentiilä
, S.
, and Ehrnsten
, U.
, 2007
, “Investigation of Coatings, Applied by PVD, for the Corrosion Protection of Materials in Supercritical Water
,” 6th International Symposium on Supercritical Water-Cooled Reactors
, Shenzhen, China
.16.
Tan
, L.
, Allen
, T. R.
, and Busby
, J. T.
, 2013
, “Grain Boundary Engineering for Structure Materials of Nuclear Reactors
,” J. Nucl. Mater.
, 441
(1–3
), pp. 661
–666
. 0022-311510.1016/j.jnucmat.2013.03.05017.
Humphreys
, F.J.
, and Hatherly
, M.
, 2004
Recrystallization and Related Annealing Phenomena
, Elsevier
, Oxford
.18.
Akhiani
, H.
, Nezakat
, M.
, Sonboli
, A.
, and Szpunar
, J.
, 2014
, “The Origin of Annealing Texture in a Cold-Rolled Incoloy 800H/HT After Different Strain Paths
,” Mater. Sci. Eng. A.
, 619
, pp. 334
–344
.10.1016/j.msea.2014.09.09319.
Akhiani
, H.
, Nezakat
, M.
, and Szpunar
, J.A.
, 2014
, “Evolution of Deformation and Annealing Textures in Incoloy 800H/HT via Different Rolling Paths and Strains
,” Mater. Sci. Eng. A.
, 614
, pp. 250
–263
.10.1016/j.msea.2014.07.03520.
Penttilä
, S.
, Toivonen
, A.
, Li
, J.
, Zheng
, W.
, and Novotny
, R.
, 2013
, “Effect of Surface Modification on the Corrosion Resistance of Austenitic Stainless Steel 316L in Supercritical Water Conditions
,” J. Supercrit. Fluids
, 81
, pp. 157
–163
.10.1016/j.supflu.2013.05.00221.
Mahboubi
, S.
, Button
, G.A.
, and Kish
, J.
, 2014
, “Oxide Scales Formed on Austinitic Fe-Cr-Ni Alloys Exposed to Supercritical Water: Role of Alloying Elements
,” 19th Pacific Basin Nuclear Conference
, Vancouver
.22.
Akhiani
, H.
, Nezakat
, M.
, Penttilä
, S.
, and Szpunar
, J.
, 2015
, “The Oxidation Resistance of Thermo-Mechanically Processed Incoloy 800HT in Supercritical Water
,” J. Supercrit. Fluids
, 101
, pp. 150
–160
.10.1016/j.supflu.2015.03.01923.
Litz
, J.
, Rahmel
, A.
, and Schorr
, M.
, 1988
, “Selective Carbide Oxidation and Internal Nitridation of the Ni-Base Superalloys IN 738 LC and IN 939 in Air
,” Oxid. Met.
, 30
(1–2
), pp. 95
–105
. 0030-770X10.1007/BF0065664624.
Tan
, L.
, Rakotojaona
, L.
, Allen
, T.R.
, Nanstad
, R.K.
, and Busby
, J.T.
, 2011
, “Microstructure Optimization of Austenitic Alloy 800H (Fe–21Cr–32Ni)
,” Mater. Sci. Eng. A
, 528
(6
), pp. 2755
–2761
.10.1016/j.msea.2010.12.05225.
26.
Birks
, N.
, Meier
, G. H.
, and Pettit
, F.S.
, 2006
, High-Temperature Oxidation of Metals
, 2nd ed., Cambridge University Press
, New York
.27.
Krupp
, U.
, and Christ
, H.
, 2000
, “Selective Oxidation and Internal Nitridation During High-Temperature Exposure of Single-Crystalline Nickel-Base Superalloys
,” Metall. Mater. Trans. A
, 31
(1
), pp. 47
–56
.10.1007/s11661-000-0051-028.
Durham
, R.N.
, Gleeson
, B.
, and Young
, D. J.
, 1998
, “Factors Affecting Chromium Carbide Precipitate Dissolution During Alloy Oxidation
,” Oxid. Met.
, 50
(1–2
), pp. 139
–165
. 0030-770X29.
Ostwald
, C.
, and Grabke
, H. J.
, 2004
, “Initial Oxidation and Chromium Diffusion. I. Effects of Surface Working on 9–20% Cr Steels
,” Corros. Sci.
, 46
(5
), pp. 1113
–1127
. 0010-938X10.1016/j.corsci.2003.09.00430.
Favergeon
, J.
, Valot
, C.
, Montesin
, T.
, and Bertrand
, G.
, 2002
, “Texture Effects on Zircaloy Oxidation: Experiment and Simulation
,” Mater. Sci. Forum.
, 408–412
, pp. 999
–1006
.10.4028/www.scientific.net/MSF.408-41231.
Berthod
, P.
, 2007
, “Influence of Chromium Carbides on the High Temperature Oxidation Behavior and on Chromium Diffusion in Nickel-Base Alloys
,” Oxid. Met.
, 68
(1–2
), pp. 77
–96
. 0030-770X10.1007/s11085-007-9062-132.
Chu
, W.F.
, and Rahmel
, A.
, 1980
, “The Conversion of Chromium Oxide to Chromium Carbide Cr2O3
,” Oxid. Met.
, 15
(3–4
), pp. 331
–337
. 0030-770X10.1007/BF0105883333.
Akhiani
, H.
, Nezakat
, M.
, Sanayei
, M.
, and Szpunar
, J.
, 2015
, “The Effect of Thermo-Mechanical Processing on Grain Boundary Character Distribution in Incoloy 800H/HT
,” Mater. Sci. Eng. A.
, 626
, pp. 51
–60
.10.1016/j.msea.2014.12.04634.
Thomson
, C.B.
, and Randle
, V.
, 1997
, “The Effects of Strain Annealing on Grain Boundaries and Secure Triple Junctions in Nickel 200
,” J. Mater. Sci.
, 32
(7
), pp. 1909
–1914
. 0022-246110.1023/A:1018573327408Copyright © 2016 by ASME
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