Abstract
In a deep geological repository (DGR) for the long-term disposal of radioactive waste, gases (e.g., hydrogen (H2), carbon dioxide (CO2) and methane (CH4)) can be generated through a number of processes, such as corrosion of various metals and alloys and degradation of organic materials. If gas induced pressure exceeds the containment capacity of the engineered barrier systems (EBS) or the host rock, the gases could migrate through these barriers and potentially expose people and the environment to radiation. Therefore, a good understanding on the long-term performance of these barriers against gas migration is an important component in DGR design and safety assessment. In the present work, a numerical model has been developed to simulate the diffusion of CO2 (one of the gas species) in the near field of a DGR with the generation from related chemical reactions. The generation of CO2 was investigated to determine if it is a critical factor to impact the DGR safety under Canadian geological formations. A commercial computational fluid dynamics (CFD) code, ANSYS Fluent was used for the calculations. The model considered pH and temperature effects on CO2 migration under Canadian DGR geochemistry conditions.
