We report a facile fabrication of a high-performance supercapacitor (SC) using a flexible cellulose-based composite film of polyaniline (PANI), reduced graphene oxide (RGO), and silver nanowires (AgNWs). The flexibility, high capacitive behavior, cyclic stability, and enhanced rate capability of the entire device make it a good candidate for flexible and wearable SCs. Our results demonstrate that a capacitance as high as 73.4 F/g (1.6 F/cm2) at a discharge rate of 1.1 A/g is achieved. In addition, the SC shows a power density up to 468.8 W/kg and an energy density up to 5.1 Wh/kg. The flexibility of the composite film is owing to the binding effect of cellulose fibers as well as AgNWs. The superb electrochemical performance of the device is found to be mainly attributed to the synergistic effect between PANI/RGO/AgNWs ternary in a cushiony cellulose scaffold and porous structure of the composite.
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February 2015
Research-Article
Flexible Cellulose-Based Films of Polyaniline–Graphene–Silver Nanowire for High-Performance Supercapacitors
Ali Khosrozadeh,
Ali Khosrozadeh
Mem. ASME
Department of Mechanical Engineering,
University of Manitoba,
Winnipeg, MB R3T 5V6, Canada
e-mail: ali.khosrozadeh@umanitoba.ca
Department of Mechanical Engineering,
University of Manitoba,
Winnipeg, MB R3T 5V6, Canada
e-mail: ali.khosrozadeh@umanitoba.ca
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Mohammad Ali Darabi,
Mohammad Ali Darabi
Department of Mechanical Engineering,
University of Manitoba,
Winnipeg, MB R3T 5V6, Canada
e-mail: Darabima@myumanitoba.ca
University of Manitoba,
Winnipeg, MB R3T 5V6, Canada
e-mail: Darabima@myumanitoba.ca
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Malcolm Xing,
Malcolm Xing
Department of Mechanical Engineering;
Department of Biochemistry
and Medical Genetics;
and Medical Genetics;
Manitoba Institute of Child Health,
University of Manitoba,
Winnipeg, MB R3T 5V6, Canada
e-mail: malcolm.xing@umanitoba.ca
University of Manitoba,
Winnipeg, MB R3T 5V6, Canada
e-mail: malcolm.xing@umanitoba.ca
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Quan Wang
Quan Wang
Department of Mechanical Engineering,
Khalifa University,
P.O. Box 127788,
Abu Dhabi, United Arab Emirates;
Khalifa University,
P.O. Box 127788,
Abu Dhabi, United Arab Emirates;
Department of Mechanical Engineering,
University of Manitoba,
Winnipeg, MB R3T 5V6, Canada
e-mail: quan.wang@kustar.ac.ae
University of Manitoba,
Winnipeg, MB R3T 5V6, Canada
e-mail: quan.wang@kustar.ac.ae
Search for other works by this author on:
Ali Khosrozadeh
Mem. ASME
Department of Mechanical Engineering,
University of Manitoba,
Winnipeg, MB R3T 5V6, Canada
e-mail: ali.khosrozadeh@umanitoba.ca
Department of Mechanical Engineering,
University of Manitoba,
Winnipeg, MB R3T 5V6, Canada
e-mail: ali.khosrozadeh@umanitoba.ca
Mohammad Ali Darabi
Department of Mechanical Engineering,
University of Manitoba,
Winnipeg, MB R3T 5V6, Canada
e-mail: Darabima@myumanitoba.ca
University of Manitoba,
Winnipeg, MB R3T 5V6, Canada
e-mail: Darabima@myumanitoba.ca
Malcolm Xing
Department of Mechanical Engineering;
Department of Biochemistry
and Medical Genetics;
and Medical Genetics;
Manitoba Institute of Child Health,
University of Manitoba,
Winnipeg, MB R3T 5V6, Canada
e-mail: malcolm.xing@umanitoba.ca
University of Manitoba,
Winnipeg, MB R3T 5V6, Canada
e-mail: malcolm.xing@umanitoba.ca
Quan Wang
Department of Mechanical Engineering,
Khalifa University,
P.O. Box 127788,
Abu Dhabi, United Arab Emirates;
Khalifa University,
P.O. Box 127788,
Abu Dhabi, United Arab Emirates;
Department of Mechanical Engineering,
University of Manitoba,
Winnipeg, MB R3T 5V6, Canada
e-mail: quan.wang@kustar.ac.ae
University of Manitoba,
Winnipeg, MB R3T 5V6, Canada
e-mail: quan.wang@kustar.ac.ae
1Corresponding author.
Manuscript received May 23, 2015; final manuscript received August 4, 2015; published online September 10, 2015. Assoc. Editor: Roger Narayan.
J. Nanotechnol. Eng. Med. Feb 2015, 6(1): 011005 (5 pages)
Published Online: September 10, 2015
Article history
Received:
May 23, 2015
Revised:
August 4, 2015
Citation
Khosrozadeh, A., Ali Darabi, M., Xing, M., and Wang, Q. (September 10, 2015). "Flexible Cellulose-Based Films of Polyaniline–Graphene–Silver Nanowire for High-Performance Supercapacitors." ASME. J. Nanotechnol. Eng. Med. February 2015; 6(1): 011005. https://doi.org/10.1115/1.4031385
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