Abstract

Dissolution rate of 16 sulfonated dispersants was measured in both water and 32-0-0 liquid fertilizer. Two dispersants, BNA and UCA, having different dissolution rates, were used to granulate a 70 % Amicarbazone formulation. Extrusions were made on a MG-55 Multigranulator using both the dome and radial modes with 0.8 mm and 1.0 mm screens. BNA and UCA were included at levels of 5, 10, and 15 % of the formulation. The remaining 14 dispersants were compared at fixed levels of 10 % using only the 0.8 mm screen and dome mode. Premix water requirements varied according to dispersant chemistry. Granule disintegration was measured in hard water by number of inversions, ASTM E1945, and CIPAC MT-174. High level of dispersant, slow dissolution rate of dispersant, and larger diameter granules lead to reduced disintegration rate in water. In addition to these factors, disintegration in 32-0-0 was further affected by porosity of the granule.

References

1.
Martin
,
P. J.
, “
Mechanics of Paste Flow in Radial Screen Extruders
,” Doctorial Dissertation,
Department of Engineering, University of Cambridge
,
2002
.
2.
Delli Colli
,
H. T.
, and
I. W.
Doring
, “
The Physical Chemistry of WDGs: Porosity and Surfactant Dissolution as a Function of Dispersant Molecular Weight
,”
Pesticides Formulations and Applications Systems, 20th Volume
, STP 1400,
Alan K.
Viets
,
R. Scott
Tann
,
Jane C.
Mueninghoff
, Eds.,
ASTM International
,
West Conshohocken, PA
,
1999
, pp.
141
-
151
.
3.
Arakawa
,
T.
, and
J. O.
Narhi
, “
Solvent Modulation in Hydrophobic Interaction Chromatography
,”
Biotechnology Appl. BioChem.
, Vol.
13
,
1991
, pp.
151
-
172
.
This content is only available via PDF.
You do not currently have access to this content.