Abstract

Rapid increases in the production of gypsum waste from the Flue Gas Desulphurization process necessitates that proper impoundments be built with an adequate understanding of the strength behavior of the sedimented gypsum slurry. This article presents laboratory experimental results that describe its physical characteristics and strength behavior. The physical characterization includes a particle size analysis and specific gravity of solids, which conform to ASTM standards. The strength behavior is described from a series of consolidated isotropically undrained triaxial compression tests that is performed at six levels of effective confining stress with two tests for each effective confining stress. The results and parameters are presented via critical state analyses in q-p’ and e-p’ spaces as well as a Mohr-Coulomb model. The analysis reveals two distinguishable regimes during shearing, which are classified as structured and destructured regimes, at which the sediment undergoes a change in strength behavior from being an intact structure to becoming a broken structure. A unique critical state line is found to be unparalleled with the isotropic compression line.

References

1.
Airey
,
D. W.
,
1993
, “
Triaxial Testing of Naturally Cemented Carbonate Soil
,”
J. Geotech. Eng.
, Vol. 
119
, No. 
9
, pp. 
1379
1397
, https://doi.org/10.1061/(ASCE)0733-9410(1993)119:9(1379)
2.
ACAA
2015
, “
2014 Coal Combustion Product (CCP) Production & Use Survey Report
,” American Coal Ash Association, Farmington Hills, MI, 1p. https://web.archive.org/web/20171106042718/https://www.acaa-usa.org/portals/9/Files/pDFs/2014ReportFinal.pdf (accessed 6 Nov. 2017).
3.
ANCOLD
2012
,
Guidelines on Tailings Dams: Planning, Design, Construction, Operation and Closure
,
Australian National Committee on Large Dams Incorporated
,
Hobart, Tasmania, Australia
, 78p.
4.
ASTM D422-63
1963
,
Standard Test Method for Particle-Size Analysis of Soils
(Withdrawn 2016),
ASTM International
,
West Conshohocken, PA
, www.astm.org
5.
ASTM D854-02
2002
,
Standard Test Methods for Specific Gravity of Soil Solids by Water Pycnometer
(Superseded),
ASTM International
,
West Conshohocken, PA
, www.astm.org
6.
ASTM D4767-11
2011
,
Standard Test Method for Consolidated Undrained Triaxial Compression Test for Cohesive Soils
,
ASTM International
,
West Conshohocken, PA
, www.astm.org
7.
Birss
,
F. W.
and
Thorvaldson
,
T.
,
1955
, “
The Hydration of Plaster of Paris
,”
Can. J. Chem.
, Vol. 
33
, No. 
5
, pp. 
870
880
, https://doi.org/10.1139/v55-105
8.
Burland
,
J. B.
,
1990
, “
On the Compressibility and Shear Strength of Natural Clays
,”
Géotechnique
, Vol. 
40
, No. 
3
, pp. 
329
378
.
9.
Castellanza
,
R.
,
Nova
,
R.
, and
Orlandi
,
G.
,
2010
, “
Evaluation and Remediation of an Abandoned Gypsum Mine
,”
J. Geotech. Geoenviron. Eng.
, Vol. 
136
, No. 
4
, pp. 
629
639
, https://doi.org/10.1061/(ASCE)GT.1943-5606.0000249
10.
Clifton
,
J. R.
,
1973
,
Some Aspects of the Setting and Hardening of Gypsum Plaster
,
Institute for Applied Technology, National Bureau of Standards
,
Washington, DC
, 33p.
11.
Cuccovillo
,
T.
and
Coop
,
M. R.
,
1999
, “
On the Mechanics of Structured Sands
,”
Géotechnique
, Vol. 
49
, No. 
6
, pp. 
741
760
.
12.
Desrues
,
J.
and
Georgopoulos
,
I.
,
2006
, “
An Investigation of Diffuse Failure Modes in Undrained Triaxial Tests on Loose Sand
,”
Soils Found.
, Vol. 
46
, No. 
5
, pp. 
585
594
.
13.
Griffin
,
A. R.
,
1996
, “
Engineering Properties and Disposal of Gypsum Waste
,”
Engineering Geology of Waste Disposal, Engineering Geology Special Publications
, Vol. 11,
Geological Society
,
London, United Kingdom
, pp. 
45
55
, https://doi.org/10.1144/GSL.ENG.1996.011.01.05
14.
Henkels
,
P. J.
and
Gaynor
,
J. C.
,
1996
, “
Characterizing Synthetic Gypsum for Wallboard Manufacture
,” presented at the
Spring National Meeting of the American Chemical Society
, New Orleans, LA,
American Chemical Society, Division of Fuel Chemistry
,
Washington, DC
, Vol. 41, No. 2, pp. 
569
574
.
15.
ICOLD
2001
,
Tailings Dams – Risk of Dangerous Occurrences: Lessons Learnt from Practical Experiences
, Bulletin No. 121,
International Commission on Large Dams (ICOLD)
,
Paris, France
.
16.
Jha
,
A. K.
and
Sivapullaiah
,
P. V.
,
2016
, “
Gypsum-Induced Volume Change Behavior of Stabilized Expansive Soil with Fly Ash-Lime
,”
Geotech. Test. J.
, Vol. 
39
, No. 
3
, pp. 
391
406
, https://doi.org/10.1520/GTJ20150017
17.
Kogel
,
J. E.
,
Trivedi
,
N. C.
,
Barker
,
J. M.
, and
Krukowski
,
S. T.
,
2006
,
Industrial Minerals & Rocks: Commodities, Markets, and Uses
, 7th ed.,
Society for Mining, Metallurgy and Exploration, Inc.
,
Englewood, CO
, 1548p.
18.
Karni
,
J.
and
Karni
,
E.
,
1995
, “
Gypsum in Construction: Origin and Properties
,”
Materials and Structures
, Vol. 
28
, No. 
2
, pp. 
92
100
, https://doi.org/10.1007/BF02473176
19.
Kovacs
,
F.
and
Molnar
,
J.
,
2003
, “
Basic Properties of Flue-Gas Desulfurization Gypsum
,”
Acta Montan. Slovaca
, Vol. 
8
, No. 
1
, pp. 
16
19
.
20.
Lewry
,
A. J.
and
Williamson
,
J.
,
1994
, “
The Setting of Gypsum Plaster: Part II: The Development of Microstructure and Strength
,”
J. Mater. Sci.
, Vol. 
29
, No. 
21
, pp. 
5524
5528
, https://doi.org/10.1007/BF00349943
21.
Low
,
H.
,
Phoon
,
K.
,
Tan
,
T.
, and
Leroueil
,
S.
,
2008
, “
Effect of Soil Microstructure on the Compressibility of Natural Singapore Marine Clay
,”
Can. Geotech. J.
, Vol. 
45
, No. 
2
, pp. 
161
176
, https://doi.org/10.1139/T07-075
22.
Luckevich
,
L. M.
and
Kuntze
,
R. A.
,
1984
, “
The Relationship between Water Demand and Particle Size Distribution of Stucco
,”
The Chemistry and Technology of Gypsum, ASTM STP861
,
Kuntze
R. A.
, Ed.,
ASTM International
,
West Conshohocken, PA
, pp. 
84
96
, https://doi.org/10.1520/STP30273S
23.
NIOSH
2016
, “
NIOSH Pocket Guide to Chemical Hazards
,” The National Institute for Occupational Safety and Health (NIOSH), https://web.archive.org/web/20171106043308/https://www.cdc.gov/niosh/npg/npgd0518.html, (accessed 6 Nov. 2017).
24.
Padevět
,
P.
,
Tesárek
,
P.
, and
Plachý
,
T.
,
2011
, “
Evolution of Mechanical Properties of Gypsum in Time
,”
Int. J. Mech.
, Vol. 
5
, No. 
1
, pp. 
1
9
.
25.
Ridge
,
M. J.
and
Boell
,
G. R.
,
1962
, “
Physical Properties of Calcined Gypsum
,”
J. Chem. Technol. Biotechnol.
, Vol. 
12
, No. 
10
, pp. 
437
444
, https://doi.org/10.1002/jctb.5010121003
26.
Singh
,
N. B.
and
Middendorf
,
B.
,
2007
, “
Calcium Sulphate Hemihydrate Hydration Leading to Gypsum Crystallization
,”
Prog. Cryst. Growth Charact. Mater.
, Vol. 
53
, No. 
1
, pp. 
57
77
, https://doi.org/10.1016/j.pcrysgrow.2007.01.002
27.
Taha
,
R.
,
1993
, “
Environmental and Engineering Properties of Flue Gas Desulfurization Gypsum
,”
Transp. Res. Rec.
, Vol. 1424,
Washington, DC
, pp. 
14
19
.
28.
Tastan
,
E. O.
and
Carraro
,
J. A. H.
,
2013
, “
A New Slurry-Based Method of Preparation of Hollow Cylinder Specimens of Clean and Silty Sands
,”
Geotech. Test. J.
, Vol. 
36
, No. 
6
, pp. 
811
822
, https://doi.org/10.1520/GTJ20130056
29.
USCOLD
1994
,
Tailings Dam Incidents
,
U.S. Committee on Large Dams
,
Denver, CO
, 82p.
30.
VandenBerge
,
D. R.
,
Brandon
,
T. L.
, and
Duncan
,
J. M.
,
2014
, “
Triaxial Tests on Compacted Clays for Consolidated-Undrained Conditions
,”
Geotech. Test. J.
, Vol. 
37
, No. 
4
, pp. 
705
716
, https://doi.org/10.1520/GTJ20130202
31.
Wong
,
L. N. Y.
and
Jong
,
M. C.
,
2013
, “
Water Saturation Effects on the Brazilian Tensile Strength of Gypsum and Assessment of Cracking Processes Using High-Speed Video
,”
Rock Mech. Rock Eng.
, Vol. 
47
, No. 
4
, pp. 
1103
1115
, https://doi.org/10.1007/s00603-013-0436-1
32.
Yu
,
Q. L.
and
Brouwers
,
H. J. H.
,
2011
, “
Microstructure and Mechanical Properties of β-Hemihydrate Produced Gypsum: An Insight from Its Hydration Process
,”
Constr. Build. Mater.
, Vol. 
25
, No. 
7
, pp. 
3149
3157
, https://doi.org/10.1016/j.conbuildmat.2010.12.005
33.
Zhou
,
Z.
,
Mitchell
,
C.
,
Buchanan
,
F.
, and
Dunne
,
N.
,
2013
, “
Effects of Heat Treatment on the Mechanical and Degradation Properties of 3D-Printed Calcium-Sulphate-Based Scaffolds
,”
ISRN Biomater.
, Vol. 
2013
,
750720
, https://doi.org/10.5402/2013/750720
34.
Zhu
,
W.
,
Wang
,
R.
,
Zuo
,
J.
,
Lin
,
C.
, and
Min
,
F.
,
2014
, “
Improved Isotropically Consolidated Undrained Triaxial Test Method for Non-Self-Supporting Materials
,”
Geotech. Test. J.
, Vol. 
37
, No. 
4
, pp. 
652
662
, https://doi.org/10.1520/GTJ20130114
This content is only available via PDF.
You do not currently have access to this content.