Historically, gas turbine fuels have been procured based on availability and low cost criteria. However,in the past few decades, with the growing concern over the negative environmental impacts produced by emissions, alternative fuels have been developed and tested under the objective of reducing such negative effects. The physical properties and broad chemical composition of fuels, including trace elements, may result in engine performance issues found only after extensive operation. This, in turn, results in higher maintenance and operation costs. This paper studies the feasibility of several renewable fuels for microturbine application, identifying key relationships between the physical and chemical properties, thermal stability, materials compatibility, and turbine performance.

References

1.
ASTM D1655-11b
,
2011
, “
Standard Specification for Aviation Turbine Fuels
,” American Society of Testing and Materials, West Conshohocken, PA.
2.
Edwards
,
T.
,
2007
, “
Advancements in Gas Turbine Fuels From 1943 to 2005
,”
ASME J. Eng. Gas Turbines Power
,
129
(1), pp.
13
20
.10.1115/1.2364007
3.
Lefebvre
,
A. H.
, and
Hallal
,
D. R.
,
2010
,
Gas Turbine Alternative Fuels and Emissions
,
CRC
,
Boca Raton, FL
.
4.
Campbell
,
A.
,
Goldmeer
,
J.
, and
Washam
,
R.
,
2008
, “
Heavy Duty Gas Turbines Fuel Flexibility
,” ASME Turbo Expo 2008, Berlin, Germany, June 9-13,
ASME
Paper No. GT2008-51368.10.1115/GT2008-51368
5.
Wong
,
O.
,
2010
, “
Design and Development of an Apparatus to Study Aviation Jet Fuel Thermal Stability
,” M.Sc. thesis, University of Toronto, Toronto, ON, Canada.
6.
Hazlet
,
R. N.
,
1991
,
Thermal Oxidation Stability of Aviation Turbine Fuels
,
American Society for Testing Materials
,
Philadelphia, PA
.
7.
Balster
,
L. M.
,
Corporan
,
E.
,
DeWitt
,
M. J.
,
Edwards
,
J. T.
,
Ervin
,
J. S.
,
Graham
,
J. L.
,
Lee
,
S.-Y.
,
Pal
,
S.
,
Phelps
,
D. K.
,
Rudnick
,
L. R.
,
Santoro
,
R. J.
,
Schobert
,
H. H.
,
Shafer
,
L. M.
,
Striebich
,
R. C.
,
West
,
Z. J.
,
Wilson
,
G. R.
,
Woodward
,
R.
, and
Zabarnick
,
S.
,
2008
, “
Development of an Advanced, Thermally Stable, Coal-Based Jet Fuel
,”
Fuel Process. Technol.
,
89
, pp.
364
378
.10.1016/j.fuproc.2007.11.018
8.
Andrésen
,
J. M.
,
Strohm
,
J. J.
,
Sun
,
L.
, and
Song
,
C.
,
2001
, “
Relationship Between the Formation of Aromatic Compounds and Solid Deposition During Thermal Degradation of Jet Fuels in the Pyrolytic Regime
,”
Energy Fuels
,
15
, pp.
714
723
.10.1021/ef000256q
9.
Ervin
,
J. S.
,
Ward
,
T. A.
,
Williams
,
T. F.
, and
Bento
,
J.
,
2003
, “
Surface Deposition Within Treated and Untreated Stainless Steel Tubes Resulting From Thermal-Oxidative and Paralytic Degradation of Jet Fuel
,”
Energy Fuels
,
17
, pp.
577
586
.10.1021/ef020180t
10.
G.
Knothe
,
J.
Van Gerpen
, and
J.
Krahl
, eds.,
The Biodiesel Handbook
,
AOCS
,
Champaign, IL
.
11.
Knothe
,
G.
, and
Dunn
,
R. O.
,
2003
, “
Dependence of Oil Stability Index of Fatty Compounds on Their Structure and Concentration and Presence of Metals
,”
J. Am. Oil Chem. Soc.
,
80
, pp.
1021
1026
.10.1007/s11746-003-0814-x
12.
Kalt
,
D. H.
,
1997
, “
Evaluation of JP-8+100 Fuel Compatibility With Aircraft Fuel System Materials: The Effect of Detergent/Dispersant on Aircraft Materials
,”
Proceedings of the 6th International Conference on Stability and Handling of Liquid Fuels
, Vancouver, BC, Canada, October 13–17.
13.
Giovanetti
,
A. J.
, and
Szetela
,
E. J.
,
1985
, “
Long Term Deposit Formation in Aviation Turbine Fuel at Elevated Temperature
,” United Technologies Research Center, Cleveland, OH, Report No. NASA CR-179579.
14.
Kline
,
S. J.
and
McClintock
,
A.
,
1953
, “
Describing Uncertainties Single-Sample Experiments
,”
Mech. Eng.
,
75
, pp.
3
8
.
15.
Muzzell
,
P. A.
,
McKay
,
B. J.
,
Sattler
,
E. R.
,
Stavinoha
,
L.
, and
Álvarez
,
R. A.
,
2007
, “
The Effect of Switch-Loading Fuels on Fuel-Wetted Elastomers
,”
SAE
Technical Paper 2007-01-1453.10.4271/2007-01-1453
16.
Muzzell
,
P.
,
Stavinoha
,
L.
, and
Chapin
,
R.
,
2005
, “
Synthetic Fischer-Tropsch (FT) JP-8/JP-5 Aviation Turbine Fuel Elastomer Compatibility
,” U.S. Army Tank-Automotive Research, Development and Engineering Center, Warren, MI.
17.
Corporan
,
E.
,
Edwards
,
T.
,
Shafer
,
L.
,
DeWitt
,
M. J.
,
Klingshirn
,
C.
,
Zabarnick
,
S.
,
West
,
Z.
,
Striebich
,
R.
,
Graham
,
J.
, and
Klein
,
J.
,
2011
, “
Chemical, Thermal Stability, Seal Swell, and Emissions Studies of Alternative Jet Fuels
,”
Energy Fuels
,
22
, pp.
955
966
.10.1021/ef101520v
18.
Moses
,
C. A.
,
2008
, “
Comparative Evaluation of Semi-Synthetic Jet Fuels
,” Southwest Research Institute, San Antonio, TX.
19.
Klingshirn
,
C. D.
,
DeWitt
,
M. J.
,
Striebich
,
R.
,
Anneken
,
D.
,
Shafer
,
L.
,
Corporan
,
E.
,
Wagner
,
M.
, and
Brigalli
,
D.
,
2011
, “
Hydroprocessed. Renewable Jet Fuel Evaluation, Performance, and Emissions in a T63 Turbine Engine
,” ASME Turbo Expo 2011, Vancouver, BC, Canada, June 6-10,
ASME
Paper No. GT2011-46572.10.1115/GT2011-46572
20.
Graham
,
J. L.
,
Striebich
,
R. C.
,
Myers
,
K. J.
,
Minus
,
D. K.
, and
Harrison
,
W. E.
III
, 2006, “
Swelling of Nitrile Rubber by Selected Aromatics Blended in Synthetic Jet Fuels
,”
Energy Fuels
,
20
, pp.
759
765
.10.1021/ef050191x
21.
Frame
,
E. A.
,
Bessee
,
G. B.
, and
Marbach
,
H. W.
,
1997
, “
Biodiesel Fuel Technology for Military Application
,” U.S. Army TARDEC Fuels and Lubricants Research Facility, Warren, MI, Interim Report No. TFLRF 317.
22.
Clark
,
R.
, and
Thomas
,
L.
,
1988
, “
An Investigation of the Physical and Chemical Factors Affecting the Performance on Fuel in the JFTOT
,”
SAE
Technical Paper No. 881533.10.4271/881533
23.
Taylor
,
W. F.
,
1968
, “
Kinetics of Deposit Formation From Hydrocarbons. 3. Heterogeneous and Homogeneous Metal Effects
,”
J. Appl. Chem. USSR
,
18
, p.
251
.10.1002/jctb.5010180806
24.
Stavinoha
,
L. L.
,
Naegli
,
D. W.
, and
McInnis
,
L.
,
1990
, “
The Role of Surface Composition in Fuel Deposition
,”
ACS National Meeting, Fuel Chemistry Pre-Prints
,
35
, pp.
1315
1323
.
25.
Tanabe
,
K.
,
Misono
,
M.
,
Ono
,
Y.
, and
Hattori
,
H.
,
1989
, “
New Solid Acids and Bases. Their Catalytic Properties
,”
Studies in Surface Science and Catalysis
, Vol.
51
,
Elsevier
,
New York
, pp.
60
64
.
26.
Mohan
,
A. R.
, and
Eser
,
S.
,
2010
, “
Analysis of Carbonaceous Solid Deposits From Thermal Oxidative Stressing of Jet-A Fuel on Iron- and Nickel-Based Alloy Surfaces
,”
Ind. Eng. Chem. Res.
,
49
, pp.
2722
2730
.10.1021/ie901283r
27.
Lamprech
,
D.
, “
Fischer-Tropsch Fuel for Use by the U.S. Military as Battlefield-Use Fuel of the Future
,”
Energy Fuels
,
21
, pp.
1448
1453
.10.1021/ef060607m
You do not currently have access to this content.