The combustion related properties of vegetable oils are somewhat similar to diesel oil. Neat vegetable oils or their blends with diesel, however, pose various long-term problems in compression ignition engines, e.g., poor atomization characteristics, ring-sticking, injector coking, injector deposits, injector pump failure, and lube oil dilution by crank-case polymerization. These undesirable features of vegetable oils are because of their inherent properties like high viscosity, low volatility, and polyunsaturated character. Linseed oil methyl ester (LOME) was prepared using methanol for long-term engine operations. The physical and combustion-related properties of the fuels thus developed were found to be closer to that of the diesel oil. A blend of 20 percent was selected as optimum biodiesel blend. Two similar new engines were completely disassembled and subjected to dimensioning of various vital moving parts and then subjected to long-term endurance tests on 20 percent biodiesel blend and diesel oil, respectively. After completion of the test, both the engines were again disassembled for physical inspection and wear measurement of various vital parts. The physical wear of various vital parts, injector coking, carbon deposits on piston, and ring sticking were found to be substantially lower in case of 20 percent biodiesel-fuelled engine. The lubricating oil samples drawn from both engines were subjected to atomic absorption spectroscopy for measurement of various wear metal traces present. AAS tests confirmed substantially lower wear and thus improved life for biodiesel operated engines.

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