This paper discusses some of the advanced concepts and research and development associated with implementing catalytic combustion to achieve ultra-low-NOx emissions in the next generation of land-based gas turbine engines. In particular, the paper presents current development status and design challenges being addressed by Siemens Westinghouse Power Corp. for large industrial engines (>200 MW) and by Solar Turbines for smaller engines (<20 MW) as part of the U.S. Department of Energy’s (DOE) Advanced Turbine Systems (ATS) program. Operational issues in implementing catalytic combustion and the current needs for research in catalyst durability and operability are also discussed. This paper indicates how recent advances in reactor design and catalytic coatings have made catalytic combustion a viable technology for advanced turbine engines and how further research and development may improve catalytic combustion systems to better meet the durability and operability challenges presented by the high-efficiency, ultra-low emissions ATS program goals. [S0742-4795(00)01502-7]

Issue Section:
Gas Turbines: Combustion and Fuel
Keywords:
gas turbines, catalysis, catalysts, design engineering, air pollution, combustion
Topics:
Catalysts, Combustion, Combustion chambers, Design, Emissions, Engines, Gas turbines, Turbines, Combustion systems, Temperature, Nitrogen oxides, Fuels, Solar energy
1.
Schlegel, A., Strichsbier, M., Mongia, R., and Dibble, R. W., 1996, “A Comparison of the Influence of Fuel/Air Unmixedness on NOx Emissions in Lean Premixed, Non-Catalytic and Catalytically Stabilized Combustion,” ASME Paper 96-GT-306.
2.
Dutta, P., Cowell, L. H., Yee, D. K., and Dalla Betta, R. A., 1997, “Design and Evaluation of a Single-Can Full Scale Catalytic Combustion System for Ultra-Low Emissions Industrial Gas Turbines,” ASME Paper 97-GT-292.
3.
Smith, D. A., Frey, S. F., Stansel, D. M., and Razdan, M. K., 1997, “Low Emissions Combustion System for The Allison ATS Engine,” ASME Paper 97-GT-311.
4.
Etemad
,
S.
,
Karim
,
H.
,
Smith
,
L. L.
, and
Pfefferle
,
W. C.
,
1999
,
Catal. Today
,
47
, Nos.
1–4
, pp.
305
–
313
.
5.
Dalla Betta, R. A., Schlatter, J. C., Nickolas, S. G., Yee, D. K., Shoji, T., 1997, “Single-Digit in a Full-Scale Catalytic Combustor,” ASME Paper 97-GT-57.
6.
Dalla Betta, R. A., et al., 1993, U.S. Patent No. 5,248,251.
7.
Dutta, P., 1997, Proc. of the Quadrennial Intl. Conference on Power Stations, Association des Ingenieurs de Montefiore, Liege, Belgium, pp. 267–272.
8.
Cowell, L. H., and Roberts, P. B., 1995, U.S. Patent No. 5,452,574.
9.
Dutta, P., Yee, D. K., and Dalla Betta, R. A., 1997, “Catalytic Combustor Development for Ultra-Low Emissions Industrial Gas Turbines,” ASME Paper 97-GT-497.
10.
Quinlan, M. A., Wise, H., and McCarty, J. G., 1989, GRI-Report No. 89/0141.
11.
Heck, R. M., and Farrauto, R. J., 1995, Catalytic Air Pollution Control, Van Nostrand Reinhold, New York.
12.
McCarty
,
J. G.
, and
Chang
,
Y.
,
1994
,
Scr. Metall. Mater.
,
31
, No.
8
, pp.
1115
–
1120
.
13.
Su
,
S. C.
,
Carstens
,
J. N.
, and
Bell
,
A. T.
,
1998
,
J. Catal.
,
176
, pp.
125
–
135
.
14.
Trimm, D. L., 1993, Proc. of Intl. Workshop on Catalytic Combustion, H. Arai, ed., Catalysis Society of Japan, Tokyo, pp. 46–55.
15.
Rodriguez
,
N. M.
,
Oh
,
S. G.
,
Dalla Betta
,
R. A.
, and
Baker
,
R. T. K.
,
1995
,
J. Catal.
,
157
, pp.
676
–
686
.
16.
Lyubovsky, M., Weber, R., and Pfefferle, L., 1996, Twenty-Sixth Symp. (Intl.) on Combustion, The Combustion Institute, Pittsburgh, PA, pp. 1779–1787.
17.
Sadamori, H., Tanioka, T., and Matuhisa, T., 1993, Proc. of Intl. Workshop on Catalytic Combustion, H. Arai, ed., Catalysis Society of Japan, Tokyo, pp. 158–161.
18.
Schlegel, A., Buser, S., Benz, P., Bockhorn, H., and Mauss, F., 1994, Twenty-Fifth Symp. (Intl.) on Combustion, The Combustion Institute, Pittsburgh, PA, pp. 1019–1026.
19.
Chou, T. C., Kennelly, T., and Farrauto, R. J., 1992, U.S. Patent No. 5,102,639.
20.
Pfefferle, W. C., et al., 1995, U.S. Patent No. 5,601,426.
21.
Mongia, R. K., Dibble, R. W., and Lovett, J., 1998, “Measure of Air-Fuel Ratio Fluctuations Caused by Combustor Driven Oscillations,” ASME Paper 98-GT-304.
22.
Spadaccini
,
L. J.
, and
Colket
, III,
M. B.
,
1994
,
Prog. Energy Combust. Sci.
,
20
, pp.
431
–
460
.
23.
Fredrik
,
A.
,
Ahlstom-Silversan
,
C.
, and
Odenbrand
,
C.
,
1997
,
Appl. Catal., A
,
157
, pp.
157
–
175
.
24.
Cybulski
,
A.
, and
Moulin
,
J. A.
,
1994
,
Catal. Rev. Sci. Eng.
,
36
, No.
2
, pp.
179
–
270
.
25.
Kolaczowski
,
S. T.
,
1995
,
Trans. Inst. Chem. Eng.
,
73
(A), pp.
168
–
190
.
26.
Deutschmann, O., Gorablski, C. T., Schmidt, L. D., Raja, L. L., Kee, R. J., and Warnatz, J., 1998, “Comparison of Navier–Stokes, Boundary-Layer, and Plug-Flow Models for Simulating Flow in a Catalytic-Combustion Honeycomb Channel,” Poster presented to 27th Symposium (Intl.) on Combustion, Boulder, Colorado.
27.
Bond, T. C., Noguchi, R. A., Chou, C. P., Mongia, R. K., Dibble, R. W., Chen, J. Y., 1997, Twenty-Sixth Symp. (Intl.) Comb., The Combustion Institute, Pittsburgh, PA, pp. 1771–1778.
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