In 1997, the International Association for the Properties of Water and Steam (IAPWS) adopted a new formulation for the thermodynamic properties of water and steam for industrial use. This new formulation, called IAPWS Industrial Formulation 1997 for the Thermodynamic Properties of Water and Steam (IAPWS-IF97), replaces the previous industrial formulation, IFC-67, that had formed the basis for power-plant calculations and other applications in energy engineering since the late 1960’s. IAPWS-IF97 improves significantly both the accuracy and the speed of the calculation of the thermodynamic properties compared with IFC-67. The differences between IAPWS-IF97 and IFC-67 will require many users, particularly boiler and turbine manufacturers, to modify design and application codes. This paper summarizes the need and the requirements for such a new industrial formulation and gives the entire numerical information about the individual equations of IAPWS-IF97. Moreover, the scientific basis for the development of the equations is summarized and the achieved quality of IAPWS-IF97 is presented regarding the three criterions accuracy, consistency along region boundaries, and computation speed. For comparison, corresponding results for the previous standard IFC-67 are also presented. [S0742-4795(00)02201-8]

1.
International Formulation Committee of the 6th International Conference on the Properties of Steam, 1967, “The 1967 IFC Formulation for Industrial Use,” Verein Deutscher Ingenieure, Du¨sseldorf.
2.
Wagner, W., and Kruse, A., 1998, “Properties of Water and Steam/Zustandsgro¨ßn von Wasser und Wasserdampf/IAPWS-IF97,” Springer-Verlag, Berlin, Heidelberg.
3.
1999 JSME Steam Tables Based on IAPWS-IF97, 1999, The Japan Society of Mechanical Engineers, Tokyo.
4.
Parry, W. T., Bellows, J. C., Gallagher, J. S., and Harvey, A. H., 2000, “ASME International Steam Tables for Industrial Use,” ASME Press, New York.
5.
International Association for the Properties of Water and Steam, 1997, “IAPWS Industrial Formulation 1997 for the Thermodynamic Properties of Water and Steam,” IAPWS Release, IAPWS Secretariat.6
6.
Setzmann
,
U.
, and
Wagner
,
W.
,
1989
, “
A New Method for Optimizing the Structure of Thermodynamic Correlation Equations
,”
Int. J. Thermophys.
,
10
, pp.
1103
1126
.
7.
Preston-Thomas
,
H.
,
1990
, “
The International Temperature Scale of 1990 (ITS-90)
,”
Metrologia
,
27
, pp.
3
10
.
8.
International Association for the Properties of Water and Steam, 1996, “IAPWS Formulation 1995 for the Thermodynamic Properties of Ordinary Water Substance for General and Scientific Use,” IAPWS Release, IAPWS Secretariat.5
9.
Wagner, W., and Pruß, A., 1999, “The IAPWS Formulation 1995 for the Thermodynamic Properties of Ordinary Water Substance for General and Scientific Use,” to be submitted to J. Phys. Chem. Ref. Data.
1.
International Association for the Properties of Water and Steam, 1994, “Skeleton Tables 1985 for the Thermodynamic Properties of Ordinary Water Substance,” IAPWS Release, IAPWS Secretariat;
2.
also in: White, Jr., H. J., Sengers, J. V., Neumann, D. B., and Bellows, J. C., eds., 1995, “Physical Chemistry of Aqueous Systems: Meeting the Needs of Industry,” Proceedings of the 12th International Conference on the Properties of Water and Steam, Begell House, New York, pp. A13–A32.
1.
International Formulation Committee of ICPS, 1965, “Minutes of the Meeting of the International Formulation Committee of ICPS,” Prague.
2.
Cohen, E. R., and Taylor, B. N., 1986, “The 1986 Adjustment of the Fundamental Physical Constants,” CODATA Bulletin, No. 63, Committee on Data for Science and Technology, Int. Council of Scientific Unions, Pergamon Press, Oxford.
3.
Audi
,
G.
, and
Wapstra
,
A. H.
,
1993
, “
The 1993 Atomic Mass Evaluation. (I) Atomic Mass Table
,”
Nucl. Phys.
,
A565
, pp.
1
65
.
4.
IUPAC
,
1991
, “
Isotopic Compositions of the Elements 1989,” Commission on Atomic Weights and Isotopic Abundances. Subcommittee for Isotopic Abundance Measurements
,
Pure Appl. Chem.
,
63
, pp.
991
1002
.
1.
International Association for the Properties of Water and Steam, 1995, “Release on The Values of Temperature, Pressure and Density of Ordinary and Heavy Water Substances at Their Respective Critical Points,” IAPWS Secretariat;
2.
also in: White, Jr., H. J., Sengers, J. V., Neumann, D. B., and Bellows, J. C., eds., 1995, “Physical Chemistry of Aqueous Systems: Meeting the Needs of Industry,” Proceedings of the 12th International Conference on the Properties of Water and Steam, Begell House, New York, pp. A101–A102.
1.
Guildner
,
L. A.
,
Johnson
,
D. P.
, and
Jones
,
F. E.
,
1976
, “
Vapor Pressure of Water at Its Triple Point
,”
J. Res. Natl. Bur. Stand., Sect. A
,
80A
, pp.
505
521
.
2.
Setzmann
,
U.
, and
Wagner
,
W.
,
1991
, “
A New Equation of State and Tables of Thermodynamic Properties for Methane Covering the Range from the Melting Line to 625 K at Pressures up to 1000 MPa
,”
J. Phys. Chem. Ref. Data
,
20
, pp.
1061
1155
.
3.
Span
,
R.
, and
Wagner
,
W.
,
1996
, “
A New Equation of State for Carbon Dioxide Covering the Fluid Region from the Triple-Point Temperature to 1100 K at Pressures up to 800 MPa
,”
J. Phys. Chem. Ref. Data
,
25
, pp.
1509
1596
.
4.
Kruse, A., and Wagner, W., 1998, “Neue Zustandsgleichungen fu¨r industrielle Anwendungen im technisch relevanten Zustandsgebiet von Wasser,” Fortschr.-Ber. VDI. Reihe 6, Nr. 393, VDI-Verlag, Du¨sseldorf.
5.
Wagner, W., 1974, “Eine Mathematisch Statistische Methode zum Aufstellen Thermodynamischer Gleichungen—gezeigt am Beispiel der Dampfdruckkurve reiner fluider Stoffe,” Fortscher.-Ber, VDI-Z, Reihe 3, Nr. 39, VDI-Verlag, Du¨sseldorf.
6.
Kretzschmar, H.-J., Sto¨cker, I., Klinger, J., and Dittmann, A., 2000, “Calculation of Thermodynamic Derivatives of Water and Steam Using the New Industrial Formulation IAPWS-IF97,” Proceedings of the 13th International Conference on the Properties of Water and Steam, P. Tremaine, P. G. Hill, D. Irish, and P. V. Balakrishnan, eds., NRC Press, Ottawa.
1.
International Association for the Properties of Water and Steam, 1994, “Release on the Pressure along the Melting and the Sublimation Curves of Ordinary Water Substance,” in
Wagner
,
W.
,
Saul
,
A.
, and
Pruß
,
A.
,
1994
,
J. Phys. Chem. Ref. Data
,
23
, pp.
515
527
:
2.
also in White, Jr., H. J., Sengers, J. V., Neumann, D. B., and Bellows, J. C., eds., 1995, “Physical Chemistry of Aqueous Systems: Meeting the Needs of Industry,” Proceedings of the 12th International Conference on the Properties of Water and Steam, Begell House, New York, pp. A9–A12.
1.
Miyagawa, K., Spencer, R. C., McClintock, R. B., Bradly, H. W., Kodl, I., Perstrup, C., Parry, W. T., Rukes, B., Scala, M., and Smith, P. F., 1997, “Acceptance Test Report of Proposal of a New Industrial Formulation of IAPWS,” report, IAPWS Task Group NIF Evaluation.5
2.
Kretzschmar, H.-J., Oguchi, K., and Willkommen, Th., 2000, “Numerically Consistent Equations for Vapor Pressure psT and Saturation Temperature Tsp of Ordinary Water Substance,” to be submitted to Int. J. Thermophys.
3.
Willkommen, Th., Kretzschmar, H.-J., and Dittmann, A., 1995, “An Algorithm for Setting Up Numerically Consistent Forward and Backward Equations for Process Modelling,” in White, Jr., H. J., Sengers, J. V., Neumann, D. B., Bellows, J. C., eds., “Physical Chemistry of Aqueous Systems: Meeting the Needs of Industry,” Proceedings of the 12th International Conference on the Properties of Water and Steam, Begell House, New York, pp. 194–201.
4.
Zschunke
,
T.
,
Kretzschmar
,
H.-J.
, and
Dittmann
,
A.
,
1991
, “
Erstellung von konsistenten Zustandsgleichungen mit simultaner gleichma¨ßiger Approximation
,”
Brennstoff-Wa¨rme-Kraft
,
43
, pp.
567
570
.
5.
Maresˇ
,
R.
, and
Sifner
,
O.
,
1996
, “
Equation of State for Superheated Steam in the Range from 800 to 2000°C and Pressures up to 10 MPa
,”
Acta Tech. CSAV
,
41
, pp.
647
652
.
6.
Cooper
,
J. R.
,
1982
, “
Representation of the Ideal-Gas Thermodynamic Properties of Water
,”
Int. J. Thermophys.
,
3
, pp.
35
43
.
7.
Tru¨benbach, J., 1999, “Ein Algorithmus zur Aufstellung rechenzeitoptimierter Gleichungen fu¨r thermodynamische Zustandsgro¨ßen,” Fortscher.-Ber. VDI, Reihe 6, 417, VDI-Verlag, Du¨sseldorf.
8.
Willkommen, Th., 1996, “Ein Algorithmus zur Aufstellung numerisch konsistenter Gleichungen fu¨r die in Prozeßmodellierungen beno¨tigten thermodynamihen Umkehrfunktionen,” dissertation, Technische Universita¨t Dresden, Fakulta¨t Maschinenwesen, Dresden.
9.
Smukala, J., 1995, “Entwicklung eines Verfahrens zur Beru¨cksichtigung der numerischen Konsistenz bei der Aufstellung von Zustandsgleichungen in Form von Vorwa¨rts- und Ru¨ckwa¨rtsgleichungen,” Diplomarbeit, Lehrstuhl fu¨r Thermodynamik, Ruhr-Universita¨t Bochum, Bochum.
10.
McClintock, R. B., and Silvestri, G. J., 1968, Formulations and Iterative Procedures for the Calculation of Properties of Steam, ASME, New York.
You do not currently have access to this content.