Producer gas from biomass gasification contains impurities like tars, particles, alkali salts, and sulfur/nitrogen compounds. As a result, a number of process steps are required to condition the producer gas before utilization as a syngas and further upgrading to final chemicals and fuels. Here, we study the concept of using molten carbonate electrolysis cells (MCEC) both to clean and to condition the composition of a raw syngas stream, from biomass gasification, for further upgrading into synthetic natural gas (SNG). A mathematical MCEC model is used to analyze the impact of operational parameters, such as current density, pressure and temperature, on the quality and amount of syngas produced. Internal rate of return (IRR) is evaluated as an economic indicator of the processes considered. Results indicate that, depending on process configuration, the production of SNG can be boosted by approximately 50–60% without the need of an additional carbon source, i.e., for the same biomass input as in standalone operation of the GoBiGas plant.
Issue Section:
Energy Systems Analysis
References
1.
IEA
, 2013
, “Secure and Efficient Electricity Supply
,” International Energy Agency, Paris, France.2.
Koytsoumpa
, E.-I.
, Bergins
, C.
, Buddenberg
, T.
, Wu
, S.
, Sigurbjörnsson
, Ó.
, Tran
, K. C.
, and Kakaras
, E.
, 2016
, “The Challenge of Energy Storage in Europe: Focus on Power to Fuel
,” ASME J. Energy Resour. Technol.
, 138
(4
), p. 042002.3.
Mesfun
, S.
, Sanchez
, D. L.
, Leduc
, S.
, Wetterlund
, E.
, Lundgren
, J.
, Biberacher
, M.
, and Kraxner
, F.
, 2017
, “Power-to-Gas and Power-to-Liquid for Managing Renewable Electricity Intermittency in the Alpine Region
,” Renewable Energy
, 107
, pp. 361
–372
.4.
Chen
, L.
, Chen
, F.
, and Xia
, C.
, 2014
, “Direct Synthesis of Methane From CO2–H2O Co-Electrolysis in Tubular Solid Oxide Electrolysis Cells
,” Energy Environ. Sci.
, 7
(12
), pp. 4018
–4022
.5.
Gaudillere
, C.
, Navarrete
, L.
, and Serra
, J. M.
, 2014
, “Syngas Production at Intermediate Temperature Through H2O and CO2 Electrolysis With a Cu-Based Solid Oxide Electrolyzer Cell
,” Int. J. Hydrogen Energy
, 39
(7
), pp. 3047
–3054
.6.
Giglio
, E.
, Lanzini
, A.
, Santarelli
, M.
, and Leone
, P.
, 2015
, “Synthetic Natural Gas Via Integrated High-Temperature Electrolysis and Methanation—Part I: Energy Performance
,” J. Energy Storage
, 1
, pp. 22
–37
.7.
Graves
, C.
, Ebbesen
, S. D.
, and Mogensen
, M.
, 2011
, “Co-Electrolysis of CO2 and H2O in Solid Oxide Cells: Performance and Durability
,” Solid State Ionics
, 192
(1
), pp. 398
–403
.8.
Javad Kasaei
, M.
, Gandomkar
, M.
, and Nikoukar
, J.
, 2017
, “Optimal Operational Scheduling of Renewable Energy Sources Using Teaching–Learning Based Optimization Algorithm by Virtual Power Plant
,” ASME J. Energy Resour. Technol.
, 139
(6
), p. 062003.9.
Hulteberg
, P. C.
, and Karlsson
, H. T.
, 2009
, “A Study of Combined Biomass Gasification and Electrolysis for Hydrogen Production
,” Int. J. Hydrogen Energy
, 34
(2
), pp. 772
–782
.10.
Clausen
, L. R.
, Houbak
, N.
, and Elmegaard
, B.
, 2010
, “Technoeconomic Analysis of a Methanol Plant Based on Gasification of Biomass and Electrolysis of Water
,” Energy
, 35
(5
), pp. 2338
–2347
.11.
McKellar
, M. G.
, O'Brien
, J. E.
, Stoots
, C. M.
, and Hawkes
, G. L.
, 2007
, “Process Model for the Production of Syngas Via High Temperature Co-Electrolysis
,” ASME
, 6
, pp. 691
–699
.12.
McKellar
, M. G.
, Hawkes
, G. L.
, and O'Brien
, J. E.
, 2008
, “The Production of Syngas Via High Temperature Electrolysis and Biomass Gasification
,” ASME
Paper No. IMECE2008-68900
. 13.
Dean
, J.
, Braun
, R.
, Penev
, M.
, Kinchin
, C.
, and Muñoz
, D.
, 2011
, “Leveling Intermittent Renewable Energy Production Through Biomass Gasification-Based Hybrid Systems
,” ASME J. Energy Resour. Technol.
, 133
(3
), p. 031801. 14.
Tanaka
, Y.
, Mesfun
, S.
, Umeki
, K.
, Toffolo
, A.
, Tamaura
, Y.
, and Yoshikawa
, K.
, 2015
, “Thermodynamic Performance of a Hybrid Power Generation System Using Biomass Gasification and Concentrated Solar Thermal Processes
,” Appl. Energy
, 160
, pp. 664
–672
.15.
El-Emam
, R. S.
, and Dincer
, I.
, 2016
, “Assessment and Evolutionary Based Multi-Objective Optimization of a Novel Renewable-Based Polygeneration Energy System
,” ASME J. Energy Resour. Technol.
, 139
(1
), p. 012003. 16.
Sadeghi
, S.
, and Ameri
, M.
, 2014
, “Exergy Analysis of Photovoltaic Panels-Coupled Solid Oxide Fuel Cell and Gas Turbine-Electrolyzer Hybrid System
,” ASME J. Energy Resour. Technol.
, 136
(3
), p. 031201. 17.
Hu
, L.
, Lindbergh
, G.
, and Lagergren
, C.
, 2016
, “Performance and Durability of the Molten Carbonate Electrolysis Cell and the Reversible Molten Carbonate Fuel Cell
,” J. Phys. Chem. C
, 120
(25
), pp. 13427
–13433
.18.
Di Giulio
, N.
, Bosio
, B.
, Cigolotti
, V.
, and Nam
, S. W.
, 2012
, “Experimental and Theoretical Analysis of H2S Effects on MCFCs
,” Int. J. Hydrogen Energy
, 37
(24
), pp. 19329
–19336
.19.
Alamia
, A.
, Larsson
, A.
, Breitholtz
, C.
, and Thunman
, H.
, 2017
, “Performance of Large-Scale Biomass Gasifiers in a Biorefinery, a State-of-the-Art Reference
,” Int. J. Energy Res.
, 41
(14
), pp. 2001
–2019
.20.
Clarke
, S. H.
, Dicks
, A. L.
, Pointon
, K.
, Smith
, T. A.
, and Swann
, A.
, 1997
, “Catalytic Aspects of the Steam Reforming of Hydrocarbons in Internal Reforming Fuel Cells
,” Catal Today
, 38
(4
), pp. 411
–423
.21.
Kowalik
, P.
, Antoniak-Jurak
, K.
, Błesznowski
, M.
, Herrera
, M. C.
, Larrubia
, M. A.
, Alemany
, L. J.
, and Pieta
, I. S.
, 2015
, “Biofuel Steam Reforming Catalyst for Fuel Cell Application
,” Catal Today
, 254
, pp. 129
–134
.22.
Stoots
, C. M.
, O'Brien
, J. E.
, Herring
, J. S.
, and Hartvigsen
, J. J.
, 2009
, “Syngas Production Via High-Temperature Coelectrolysis of Steam and Carbon Dioxide
,” ASME J. Fuel Cell Sci. Technol.
, 6
(1
), p. 011014
.23.
Zarzycki
, R.
, and Panowski
, M.
, 2017
, “Analysis of the Flue Gas Preparation Process for the Purposes of Carbon Dioxide Separation Using the Adsorption Methods
,” ASME J. Energy Resour. Technol.
, 140
(3
), p. 032008. 24.
Hu
, L.
, Rexed
, I.
, Lindbergh
, G.
, and Lagergren
, C.
, 2014
, “Electrochemical Performance of Reversible Molten Carbonate Fuel Cells
,” Int. J. Hydrogen Energy
, 39
(23
), pp. 12323
–12329
.25.
Hu
, L.
, Lindbergh
, G.
, and Lagergren
, C.
, 2016
, “Operating the Nickel Electrode With Hydrogen-Lean Gases in the Molten Carbonate Electrolysis Cell (MCEC)
,” Int. J. Hydrogen Energy
, 41
(41
), pp. 18692
–18698
.26.
Li
, X. T.
, Grace
, J. R.
, Lim
, C. J.
, Watkinson
, A. P.
, Chen
, H. P.
, and Kim
, J. R.
, 2004
, “Biomass Gasification in a Circulating Fluidized Bed
,” Biomass Bioenergy
, 26
(2
), pp. 171
–193
.27.
Mesfun
, S.
, and Toffolo
, A.
, 2015
, “Integrating the Processes of a Kraft Pulp and Paper Mill and Its Supply Chain
,” Energy Convers. Manage.
, 103
, pp. 300
–310
.28.
Lazzaretto
, A.
, and Toffolo
, A.
, 2008
, “A Method to Separate the Problem of Heat Transfer Interactions in the Synthesis of Thermal Systems
,” Energy
, 33
(2
), pp. 163
–170
.29.
Kemp
, C.-I.
, 2007
, Pinch Analysis and Process Integration: A User Guide on Process Integration for the Efficient Use of Energy
, 2nd ed., Butterworth-Heinemann
, Oxford, UK
.30.
Alamia
, A.
, Thunman
, H.
, and Seemann
, M.
, 2016
, “Process Simulation of Dual Fluidized Bed Gasifiers Using Experimental Data
,” Energy Fuels
, 30
(5
), pp. 4017
–4033
.31.
Andersson
, J.
, Lundgren
, J.
, and Marklund
, M.
, 2014
, “Methanol Production Via Pressurized Entrained Flow Biomass Gasification —Techno-Economic Comparison of Integrated Vs. Stand-Alone Production
,” Biomass Bioenergy
, 64
, pp. 256
–268
.32.
Zhang
, W.
, He
, J.
, Engstrand
, P.
, and Björkqvist
, O.
, 2015
, “Economic Evaluation on Bio-Synthetic Natural Gas Production Integrated in a Thermomechanical Pulp Mill
,” Energies
, 8
(11
), pp. 12795
–12809
.33.
Della Pietra
, M.
, McPhail
, S. J.
, Prabhakar
, S.
, Desideri
, U.
, Nam
, S. W.
, and Cigolotti
, V.
, 2016
, “Accelerated Test for MCFC Button Cells: First Findings
,” Int. J. Hydrogen Energy
, 41
(41
), pp. 18807
–18814
.34.
Heyne
, S.
, and Harvey
, S.
, 2014
, “Impact of Choice of CO2 Separation Technology on Thermo-Economic Performance of Bio-SNG Production Processes
,” Int. J. Energy Res.
, 38, pp. 299
–318
.35.
Mesfun
, S.
, Anderson
, J.-O.
, Umeki
, K.
, and Toffolo
, A.
, 2016
, “Integrated SNG Production in a Typical Nordic Sawmill
,” Energies
, 9
(5
), p. 333
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