A simple and mass productive extrusion technique was applied to fabricate anode-supported tubular solid oxide fuel cells (SOFCs). A standard NiO/8YSZ (nickel oxide/8 mol % yttria stabilized zirconia) cermet anode, 8YSZ electrolyte, and lanthanum strontium manganite (La0.8Sr0.2MnO3) cathode were used as the material components. Secondary electron microscopy images indicated that vacuum infiltration method successfully generated the thin electrolyte layer (about 15μm) with a structurally effective three phase boundaries. Fabricated unit cell showed the open circuit voltage of 1.12 V without any fuel leaking problems. Electrochemical tests showed a maximum power density up to 0.30Wcm2 at 800°C, implying the good performance as tubular SOFCs. This study verified that the extrusion aided by vacuum infiltration process could be a promising technique for mass production of tubular SOFCs.

1.
Yamamoto
,
O.
, 2000, “
Solid Oxide Fuel Cells: Fundamental Aspects and Prospects
,”
Electrochim. Acta
0013-4686,
45
, pp.
2423
2435
.
2.
Blum
,
L.
,
Meulenberg
,
W. A.
,
Nabielek
,
H.
, and
Steinberger-Wilckens
,
R.
, 2005, “
Worldwide SOFC Technology Overview and Benchmark
,”
Int. J. Appl. Cerm. Technol.
,
2
(
6
), pp.
482
492
.
3.
Lashtabeg
,
A.
, and
Skinner
,
S. J.
, 2006, “
Solid Oxide Fuel Cells—A Challenge for Materials Chemists
,”
J. Mater. Chem.
0959-9428,
16
, pp.
3161
3170
.
4.
Dokiya
,
M.
, 2002, “
SOFC System and Technology
,”
Solid State Ionics
0167-2738,
152–153
, pp.
383
392
.
5.
Song
,
J. -H.
,
Sammes
,
N. M.
,
Park
,
S. -I.
,
Boo
,
S.
,
Kim
,
H. -S.
,
Moon
,
H.
, and
Hyun
,
S. -H.
, 2008, “
Fabrication and Characterization of Anode-Supported Planar Solid Oxide Fuel Cell Manufactured by a Tape Casting Processes
,”
ASME J. Fuel Cell Sci. Technol.
1550-624X,
5
(
2
), p.
021003
.
6.
Song
,
J. -H.
,
Park
,
S. -I.
,
Lee
,
J. -H.
, and
Kim
,
H. -S.
, 2008, “
Fabrication and Characteristics of an Anode-Supported Thin-Film Electrolyte Fabricated by the Tape Casting Method for IT-SOFC
,”
J. Mater. Process. Technol.
0924-0136,
198
, pp.
414
418
.
7.
Jones
,
F. G. E.
,
Connor
,
P. A.
,
Feighery
,
A. J.
,
Nairn
,
J.
,
Rennie
,
J.
, and
Irvine
,
J. T. S.
, 2007, “
SOFCRoll Development at St. Andrews Fuel Cells Ltd
,”
ASME J. Fuel Cell Sci. Technol.
1550-624X,
4
, pp.
138
142
.
8.
Kiviaho
,
J.
,
Halinen
,
M.
,
Noponen
,
M.
,
Saarinen
,
J.
,
Simell
,
P.
, and
Rosenberg
,
R.
, 2007, “
Solid Oxide Fuel Cell System Development in VTT
,”
ASME J. Fuel Cell Sci. Technol.
1550-624X,
4
, pp.
392
396
.
9.
Lang
,
M.
,
Szabo
,
P.
,
Iihan
,
Z.
,
Cinque
,
S.
,
Franco
,
T.
, and
Schiller
,
G.
, 2007, “
Development of Solid Oxide Fuel Cells and Shorts Stacks for Mobile Application
,”
ASME J. Fuel Cell Sci. Technol.
1550-624X,
4
, pp.
384
391
.
10.
Sammes
,
N. M.
,
Du
,
Y.
, and
Bove
,
R.
, 2005, “
Design and Fabrication of a 100 W Anode Supported Micro-Tubular SOFC Stack
,”
J. Power Sources
0378-7753,
145
, pp.
428
434
.
11.
George
,
R. A.
, 2000, “
Status of Tubular SOFC Field Unit Demonstrations
,”
J. Power Sources
0378-7753,
86
, pp.
134
139
.
12.
Kendall
,
K.
,
Minh
,
N. Q.
, and
Singhal
,
S. C.
, 2003, “
Cell and Stack Designs
,”
High Temperature and Solid Fuel Cells
,
S. C.
Singhal
and
K.
Kendall
, eds.,
Elsevier
,
New York
, Chapter 8, pp.
197
228
.
13.
2007, “
Acumentrics Produces Power From Biogas
,”
Fuel Cells Bull.
1464-2859,
12
, pp.
5
6
.
14.
Sammes
,
N. M.
, and
Du
,
Y.
, 2007, “
Fabrication and Characterization of Tubular Solid Oxide Fuel Cells
,”
Int. J. Appl. Ceram. Technol.
1546-542X,
4
(
2
), pp.
89
102
.
15.
Pusz
,
J.
,
Mohammadi
,
A.
, and
Sammes
,
N. M.
, 2006, “
Fabrication and Performance of Anode-Supported Micro-Tubular Solid Oxide Fuel Cells
,”
ASME J. Fuel Cell Sci. Technol.
1550-624X,
3
, pp.
482
486
.
16.
Du
,
Y.
, and
Sammes
,
N. M.
, 2004, “
Fabrication and Properties of Anode-Supported Tubular Solid Oxide Fuel Cells
,”
J. Power Sources
0378-7753,
136
, pp.
66
71
.
17.
Du
,
Y.
,
Sammes
,
N. M.
,
Tompsett
,
G. A.
,
Zhang
,
D.
,
Swan
,
J.
, and
Bowden
,
M.
, 2003, “
Extruded Tubular Strontium- and Magnesium-Doped Lanthanum Gallate, Gadolinium-Doped Ceria, and Yttria-stabilized Electrolyte
,”
J. Electrochem. Soc.
0013-4651,
150
(
1
), pp.
A74
A78
.
18.
Suzuki
,
T.
,
Yamaguchi
,
T.
,
Fujishiro
,
Y.
, and
Awano
,
M.
, 2006, “
Improvement of SOFC Performance Using a Microtubular, Anode-Supported SOFC
,”
J. Electrochem. Soc.
0013-4651,
153
(
5
), pp.
A925
A928
.
19.
Suzuki
,
T.
,
Yamaguchi
,
T.
,
Fujishiro
,
Y.
, and
Awano
,
M.
, 2007, “
Current Collecting Efficiency of Micro Tubular SOFCs
,”
J. Power Sources
0378-7753,
163
, pp.
737
742
.
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