The composite electrode of La0.6Sr0.4Co0.2Fe0.8O3 (LSCF) and Ag was examined as an air electrode for intermediate-temperature solid oxide fuel cells. Two types of LSCF/Ag composite electrodes were prepared. One was made by firing the printed sheet of LSCF-GDC (10mol%Gd2O3 doped CeO2)-Ag powder mixture on the GDC/8mol%Y2O3 doped zirconia (YSZ) electrolyte, and the other was prepared by firing the LSCF electrode on GDC/YSZ infiltrating a AgNO3 solution in the pores of the electrode. In both cases, the cathode polarization overpotentials were reduced by the addition of Ag into LSFC. The power density of anode support cells with the LSCF electrode was increased from 0.28Wcm2to0.34Wcm2 at 600°C by infiltrating a AgNO3 solution into the electrode.

1.
Tai
,
L. W.
,
Narsarallah
,
M. M.
,
Anderson
,
H. U.
,
Sparim
,
D. M.
, and
Sehlin
,
S. R.
, 1995, “
Structure and Electrical Properties of La1−xSrxCo1−yFeyO3 Part 2. The System La1−xSrxCo0.2Fe0.8O3
,”
Solid State Ionics
0167-2738,
76
, pp.
273
283
.
2.
Sshibzada
,
M.
,
Benson
,
S. J.
,
Rdkin
,
R. A.
, and
Kilner
,
J. A.
, 1998, “
Pd-Promoted La0.6Sr0.4Co0.2Fe0.8O3 Cathode
,”
Solid State Ionics
0167-2738,
113–115
, pp.
285
290
.
3.
Zhang
,
J.
,
Ji
,
Y.
,
Gao
,
H.
,
He
,
T.
, and
Liu
,
J.
, 2005, “
Composite Cathode La0.6Sr0.4Co0.2Fe0.8O3–Sm0.1Ce0.9O1.95–Ag for Intermediate-Temperature Solid Oxide Fuel Cells
,”
J. Alloys Compd.
0925-8388,
395
, pp.
322
325
.
4.
Lee
,
K. T.
, and
Manthiram
,
A.
, 2006, “
Electrochemical Performance of Nd0.6Sr0.4Co0.5Fe0.5O3–Ag Composite Cathode in Intermediate Temperature Solid Oxide Fuel Cell
,”
J. Power Sources
0378-7753,
160
, pp.
903
908
.
5.
Wang
,
S.
,
Kato
,
T.
,
Nagata
,
S.
,
Honda
,
T.
,
Kaneko
,
T.
,
Iwashita
,
N.
, and
Dokiya
,
M.
, 2002, “
Performance of a La0.6Sr0.4Co0.8Fe0.2O3–Ce0.8Gd0.2O1.9–Ag Cathode for Ceria Electrolyte SOFCs
,”
Solid State Ionics
0167-2738,
146
, p.
203
.
6.
Sasaki
,
K.
,
Hosoda
,
K.
,
Lan
,
T. N.
,
Yasumoto
,
K.
,
Wang
,
S.
, and
Dokiya
,
M.
, 2004, “
A g-Zr(Sc)O2 Cermet Cathode for Reduced Temperature SOFCs
,”
Solid State Ionics
0167-2738,
174
, pp.
97
102
.
You do not currently have access to this content.