Abstract
Sodium-ion batteries are considered as one of the most promising energy storage technologies that may replace lithium-ion batteries in the future. NaODFB, a new chelated sodium salt with the specific structural, has not been widely concerned by researchers. In this work, the compatibility of different NaODFB-based ether electrolytes in half-cell/full-cell systems with Na3V2(PO4)3 (NVP) cathode materials was compared. The correlation between the electrochemical performance of NVP@C/Na half cells in NaODFB-based ether electrolytes and the composition of the cathode electrolyte interface (CEI) film on the electrode surface was analyzed by electrochemical tests and other characterizations to better understand the important role of NaODFB-based ether electrolytes in the formation of the CEI film on the electrode material surface. This research provides a novel idea for the industrial design of Na-ion battery electrolyte and has significant guidance for the application of NaODFB in Na-ion battery.
Issue Section:
Research Papers
References
1.
Bao
, W.
, Qian
, G.
, Zhao
, L.
, Yu
, Y.
, Su
, L.
, Cai
, X.
, Zhao
, H.
, et al, 2020
, “Simultaneous Enhancement of Interfacial Stability and Kinetics of Single-Crystal LiNi0.6Mn0.2Co0.2O2 Through Optimized Surface Coating and Doping
,” Nano Lett.
, 20
(12
), pp. 8832
–8840
. 2.
Bi
, Y.
, Tao
, J.
, Wu
, Y.
, Li
, L.
, Xu
, Y.
, Hu
, E.
, Wu
, B.
, et al, 2020
, “Reversible Planar Gliding and Microcracking in a Single-Crystalline Ni-Rich Cathode
,” Science
, 370
(6522
), pp. 1313
–1317
. 3.
Yao
, L.
, Li
, Y.
, Gao
, X.
, Cai
, M.
, Jin
, J.
, Yang
, J.
, Xiu
, T.
, Song
, Z.
, Badding
, M. E.
, and Wen
, Z.
, 2021
, “Microstructure Boosting the Cycling Stability of LiNi0.6Co0.2Mn0.2O2 Cathode Through Zr-Based Dual Modification
,” Energy Storage Mater.
, 36
, pp. 179
–185
. 4.
Chen
, M.
, Pan
, Z.
, Jin
, X.
, Chen
, Z.
, Zhong
, Y.
, Wang
, X.
, Qiu
, Y.
, Xu
, M.
, Li
, W.
, and Zhang
, Y.
, 2019
, “A Highly Integrated All-Manganese Battery With Oxide Nanoparticles Supported on the Cathode and Anode by Super-Aligned Carbon Nanotubes
,” J. Mater. Chem. A
, 7
(9
), pp. 4494
–4504
. 5.
Lei
, D.
, He
, Y. B.
, Huang
, H.
, Yuan
, Y.
, Zhong
, G.
, Zhao
, Q.
, Hao
, X.
, et al, 2019
, “Cross-Linked Beta Alumina Nanowires With Compact Gel Polymer Electrolyte Coating for Ultra-Stable Sodium Metal Battery
,” Nat. Commun.
, 10
(1
), p. 4244
. 6.
Cui
, X.
, Wang
, S.
, Ye
, X.
, Fan
, X.
, Gao
, C.
, Quan
, Y.
, Wen
, S.
, Cai
, X.
, Huang
, J.
, and Li
, S.
, 2021
, “Insights Into the Improved Cycle and Rate Performance by Ex-Situ F and In-Situ Mg Dual Doping of Layered Oxide Cathodes for Sodium-Ion Batteries
,” Energy Storage Mater.
, 45
, pp. 1153
–1164
. 7.
Huang
, Y.
, Zhao
, L.
, Li
, L.
, Xie
, M.
, Wu
, F.
, and Chen
, R.
, 2019
, “Electrolytes and Electrolyte/Electrode Interfaces in Sodium-Ion Batteries: From Scientific Research to Practical Application
,” Adv. Mater.
, 31
(21
), p. e1808393
. 8.
Kim
, S.-W.
, Seo
, D.-H.
, Ma
, X.
, Ceder
, G.
, and Kang
, K.
, 2012
, “Electrode Materials for Rechargeable Sodium-Ion Batteries: Potential Alternatives to Current Lithium-Ion Batteries
,” Adv. Energy Mater.
, 2
(7
), pp. 710
–721
. 9.
Eshetu
, G. G.
, Grugeon
, S.
, Kim
, H.
, Jeong
, S.
, Wu
, L.
, Gachot
, G.
, Laruelle
, S.
, Armand
, M.
, and Passerini
, S.
, 2016
, “Comprehensive Insights Into the Reactivity of Electrolytes Based on Sodium Ions
,” ChemSusChem
, 9
(5
), pp. 462
–471
. 10.
Ponrouch
, A.
, Monti
, D.
, Boschin
, A.
, Steen
, B.
, Johansson
, P.
, and Palacín
, M. R.
, 2015
, “Non-Aqueous Electrolytes for Sodium-Ion Batteries
,” J. Mater. Chem. A
, 3
(1
), pp. 22
–42
. 11.
Eshetu
, G. G.
, Diemant
, T.
, Hekmatfar
, M.
, Grugeon
, S.
, Behm
, R. J.
, Laruelle
, S.
, Armand
, M.
, and Passerini
, S.
, 2019
, “Impact of the Electrolyte Salt Anion on the Solid Electrolyte Interphase Formation in Sodium Ion Batteries
,” Nano Energy
, 55
, pp. 327
–340
. 12.
Ould
, D. M. C.
, Menkin
, S.
, O'Keefe
, C. A.
, Coowar
, F.
, Barker
, J.
, Grey
, C. P.
, and Wright
, D. S.
, 2021
, “New Route to Battery Grade NaPF6 for Na-Ion Batteries: Expanding the Accessible Concentration
,” Angew. Chem. Int. Ed.
, 60
(47
), pp. 24882
–24887
. 13.
Zhu
, Y.
, Luo
, X.
, Zhi
, H.
, Liao
, Y.
, Xing
, L.
, Xu
, M.
, Liu
, X.
, Xu
, K.
, and Li
, W.
, 2018
, “Diethyl(Thiophen-2-Ylmethyl) Phosphonate: A Novel Multifunctional Electrolyte Additive for High Voltage Batteries
,” J. Mater. Chem. A
, 6
(23
), pp. 10990
–11004
. 14.
Zhu
, Y.
, Luo
, X.
, Zhi
, H.
, Yang
, X.
, Xing
, L.
, Liao
, Y.
, Xu
, M.
, and Li
, W.
, 2017
, “Structural Exfoliation of Layered Cathode Under High Voltage and Its Suppression by Interface Film Derived From Electrolyte Additive
,” ACS Appl. Mater. Interfaces
, 9
(13
), pp. 12021
–12034
. 15.
Geng
, C.
, Buchholz
, D.
, Kim
, G. T.
, Carvalho
, D. V.
, Zhang
, H.
, Chagas
, L. G.
, and Passerini
, S.
, 2018
, “Influence of Salt Concentration on the Properties of Sodium-Based Electrolytes
,” Small Methods
, 3
(4
), p. 1800208
. 16.
Du
, K.
, Rudola
, A.
, and Balaya
, P.
, 2021
, “Investigations of Thermal Stability and Solid Electrolyte Interphase on Na2Ti3O7/C As a Non-Carbonaceous Anode Material for Sodium Storage Using Non-flammable Ether-Based Electrolyte
,” ACS Appl. Mater. Interfaces
, 13
(10
), pp. 11732
–11740
. 17.
Ge
, C.
, Wang
, L.
, Xue
, L.
, Wu
, Z.-S.
, Li
, H.
, Gong
, Z.
, and Zhang
, X.-D.
, 2014
, “Synthesis of Novel Organic-Ligand-Doped Sodium Bis(Oxalate)-Borate Complexes With Tailored Thermal Stability and Enhanced Ion Conductivity for Sodium Ion Batteries
,” J. Power Sources
, 248
, pp. 77
–82
. 18.
Gao
, L.
, Chen
, J.
, Liu
, Y.
, Yamauchi
, Y.
, Huang
, Z.
, and Kong
, X.
, 2018
, “Revealing the Chemistry of an Anode-Passivating Electrolyte Salt for High Rate and Stable Sodium Metal Batteries
,” J. Mater. Chem. A
, 6
(25
), pp. 12012
–12017
. 19.
Chen
, J.
, Huang
, Z.
, Wang
, C.
, Porter
, S.
, Wang
, B.
, Lie
, W.
, and Liu
, H. K.
, 2015
, “Sodium-Difluoro(oxalato)borate (NaDFOB): A New Electrolyte Salt for Na-Ion Batteries
,” Chem. Commun.
, 51
(48
), pp. 9809
–9812
. 20.
Lee
, M.
, Hong
, J.
, Lopez
, J.
, Sun
, Y.
, Feng
, D.
, Lim
, K.
, Chueh
, W. C.
, Toney
, M. F.
, Cui
, Y.
, and Bao
, Z.
, 2017
, “High-Performance Sodium–Organic Battery by Realizing Four-Sodium Storage in Disodium Rhodizonate
,” Nature Energy
, 2
(11
), pp. 861
–868
. 21.
Sadan
, M. K.
, Kim
, H.
, Kim
, C.
, Cha
, S. H.
, Cho
, K.-K.
, Kim
, K.-W.
, Ahn
, J.-H.
, and Ahn
, H.-J.
, 2020
, “Enhanced Rate and Cyclability of a Porous Na3V2(PO4)3 Cathode Using Dimethyl Ether As the Electrolyte for Application in Sodium-Ion Batteries
,” J. Mater. Chem. A
, 8
(19
), pp. 9843
–9849
. 22.
Wang
, J.
, Zhao
, D.
, Cong
, Y.
, Zhang
, N.
, Wang
, P.
, Fu
, X.
, and Cui
, X.
, 2021
, “Analyzing the Mechanism of Functional Groups in Phosphate Additives on the Interface of LiNi0.8Co0.15Al0.05O2 Cathode Materials
,” ACS Appl. Mater. Interfaces
, 13
(14
), pp. 16939
–16951
. 23.
Dong
, H.
, Fu
, X.
, Wang
, J.
, Wang
, P.
, Ding
, H.
, Song
, R.
, Wang
, S.
, Li
, R.
, and Li
, S.
, 2021
, “In-Situ Construction of Porous Si@C Composites With LiCl Template to Provide Silicon Anode Expansion Buffer
,” Carbon
, 173
, pp. 687
–695
. 24.
Dong
, H.
, Wang
, J.
, Ding
, H.
, Wang
, P.
, Song
, R.
, Zhang
, N.
, Li
, F.
, and Li
, S.
, 2021
, “The Mosaic Structure Design to Improve the Anchoring Strength of SiOx@C@Graphite Anode
,” Mater. Today Chem.
, 22
, p. 100599
.25.
Dong
, H.
, Wang
, J.
, Wang
, P.
, Ding
, H.
, Song
, R.
, Zhang
, N.-S.
, Zhao
, D.-N.
, Zhang
, L.-J.
, and Li
, S.-Y.
, 2022
, “Effect of Temperature on Formation and Evolution of Solid Electrolyte Interphase on Si@Graphite@C Anodes
,” J. Energy Chem.
, 64
, pp. 190
–200
. 26.
Wang
, J.
, Dong
, H.
, Wang
, P.
, Fu
, X.-L.
, Zhang
, N.-S.
, Zhao
, D.-N.
, Li
, S.-Y.
, and Cui
, X.-L.
, 2022
, “Adjusting the Solvation Structure With Tris(Trimethylsilyl)Borate Additive to Improve the Performance of LNCM Half Cells
,” J. Energy Chem.
, 67
, pp. 55
–64
. 27.
Du
, K.
, Guo
, H.
, Hu
, G.
, Peng
, Z.
, and Cao
, Y.
, 2013
, “Na3V2(PO4)3 as Cathode Material for Hybrid Lithium Ion Batteries
,” J. Power Sources
, 223
, pp. 284
–288
. 28.
Feng
, P.
, Wang
, W.
, Wang
, K.
, Cheng
, S.
, and Jiang
, K.
, 2017
, “Na3V2(PO4)3/C Synthesized by a Facile Solid-Phase Method Assisted With Agarose As a High-Performance Cathode for Sodium-Ion Batteries
,” J. Mater. Chem. A
, 5
(21
), pp. 10261
–10268
. 29.
Jiang
, X.
, Yang
, L.
, Ding
, B.
, Qu
, B.
, Ji
, G.
, and Lee
, J. Y.
, 2016
, “Extending the Cycle Life of Na3V2(PO4)3 Cathodes in Sodium-Ion Batteries Through Interdigitated Carbon Scaffolding
,” J. Mater. Chem. A
, 4
(38
), pp. 14669
–14674
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