This paper focuses on the fabrication of micro-coplanar interdigitated single chamber solid oxide fuel cell (μ-SC-SOFC) using a combination of micropatterning technique and thin-film deposition technology. Photolithography was used to generate the micro-interdigitated photoresist patterns on the substrates. Pulsed laser deposition (PLD) method was used to deposit thin films of microstructured electrolytes yttrium stabilized zirconia (YSZ) and electrodes (anode: YSZ + NiO and cathode: lanthanum strontium ferrous cobalt (LSCF)). Process parameters were optimized to obtain consistent functional microstructure and crystal morphology. This research shows good potential for combinatorial manufacturing methods to fabricate high quality and repeatable micro fuel cell components.

References

References
1.
Jose
,
L. G.
,
Hyun
,
J. I.
,
Crumlin
,
E.
,
Barbastathis
,
G.
, and
Shao-Horn
,
Y.
,
2007
, “
Recent Advances in Microdevices for Electrochemical Energy Conversion and Storage
,”
Int. J. Energy Res.
,
31
(
6–7
), pp.
548
575
.10.1002/er.1280
2.
Yano
,
M.
,
Tomita
,
A.
,
Sano
,
M.
, and
Hibino
,
T.
,
2007
, “
Recent Advances in Single-Chamber Solid Oxide Fuel Cells: A Review
,”
Solid State Ionics
,
177
(
39–40
), pp.
3351
3359
.10.1016/j.ssi.2006.10.014
3.
Hibino
,
T.
, and
Iwahara
,
H.
,
1993
, “
Simplification of Solid Oxide Fuel Cell System Using Partial Oxidation of Methane
,”
Chem. Lett.
,
22
(
7
), pp.
1131
1134
.10.1246/cl.1993.1131
4.
Riess
,
I.
,
van der Put
,
P. J.
, and
Schoonman
,
J.
,
1995
, “
Solid Oxide Fuel Cells Operating on Uniform Mixtures of Fuel and Air
,”
Solid State Ionics
,
82
(
1–2
), pp.
1
4
.10.1016/0167-2738(95)00210-W
5.
van Gool
,
W.
,
1956
, “
The Possible Use of Surface Migration in Fuel Cells and Heterogeneous Catalysis
,”
Philips Res. Rep.
,
20
, pp.
81
93
.
6.
Louis
,
G. A.
,
Lee
,
J. M.
,
Maricle
,
D. L.
, and
Trocciola
,
J. C.
,
1981
, “
Solid Electrolyte Electrochemical Cell
,” U.S. Patent 4,248,941.
7.
Dyer
,
C. K.
,
1990
, “
A Novel Thin-Film Electrochemical Device for Energy Conversion CuO
,”
Nature
,
343
(
6258
), pp.
547
548
.10.1038/343547a0
8.
Cavalca
,
C. A.
,
Larsen
,
G.
,
Vayenas
,
C. G.
, and
Haller
,
G. L.
,
1993
, “
Electrochemical Modification of Methanol Oxidation Selectivity and Activity on a Platinum Single-Pellet Catalytic Reactor
,”
J. Phys. Chem.
,
97
(
23
), pp.
6115
6119
.10.1021/j100125a005
9.
Hibino
,
T.
,
Ushiki
,
K.
, and
Kuwahara
,
Y.
,
1996
, “
New Concept for Simplifying SOFC System
,”
Solid State Ionics
,
91
(
1–2
), pp.
69
74
.10.1016/S0167-2738(96)00437-7
10.
Chung
,
C. Y.
, and
Chung
,
Y. C.
,
2006
, “
Performance Characteristics of Micro Single-Chamber Solid Oxide Fuel Cell: Computational Analysis
,”
J. Power Sources
,
154
(
1
), pp.
35
41
.10.1016/j.jpowsour.2005.03.229
11.
Buergler
,
B. E.
,
Ochsner
,
M.
,
Vuillemin
,
S.
, and
Gauckler
,
L. J.
,
2007
, “
From Macro- to Micro-Single Chamber Solid Oxide Fuel Cells
,”
J. Power Sources
,
171
(
2
), pp.
310
320
.10.1016/j.jpowsour.2007.06.204
12.
Ahn
,
S.
,
Lee
,
J.
,
Kim
,
J.
, and
Moon
,
J.
,
2006
, “
Single-Chamber Solid Oxide Fuel Cell With Micropatterned Interdigitated Electrodes
,”
Electrochem. Solid-State Lett.
,
9
(
5
), pp.
A228
A231
.10.1149/1.2180537
13.
Zhao
,
X.
,
Evans
,
J. R. G.
,
Edirisinghe
,
M. J.
, and
Song
,
J. H.
,
2002
, “
Direct Ink-Jet Printing of Vertical Walls
,”
J. Am. Ceram. Soc.
,
85
(
8
), pp.
2113
2115
.10.1111/j.1151-2916.2002.tb00414.x
14.
Tohver
,
V.
,
Morissettle
,
S. L.
,
Lewis
,
J. A.
,
Tuttle
,
B. A.
,
Voigt
,
J. A.
, and
Dimos
,
D. B.
,
2002
, “
Direct-Write Fabrication of Zinc Oxide Varistors
,”
J. Am. Ceram. Soc.
,
85
(
1
), pp.
123
128
.10.1111/j.1151-2916.2002.tb00052.x
15.
Lewis
,
J. A.
,
Smay
,
J. E.
,
Stuecker
,
J.
, and
Cesarano
,
J.
,
2006
, “
Direct Ink Writing of Three-Dimensional Ceramic Structures
,”
J. Am. Ceram. Soc.
,
89
(
12
), pp.
3599
3609
.10.1111/j.1551-2916.2006.01382.x
16.
Kim
,
Y. B.
,
Ahn
,
S. J.
,
Moon
,
J.
,
Kim
,
J.
, and
Lee
,
H. W.
,
2006
, “
Direct Write Fabrication of Integrated Planar Solid Oxide Fuel Cells
,”
J. Electroceram.
,
17
(
2–4
), pp.
683
687
.10.1007/s10832-006-6005-1
17.
Kuhn
,
M.
,
Napporn
,
T.
,
Meunier
,
M.
,
Therriault
,
D.
, and
Vengallatore
,
S.
,
2007
, “
Fabrication and Testing of Coplanar Single-Chamber Micro Solid Oxide Fuel Cells With Geometrically Complex Electrodes
,”
J. Power Sources
,
177
(
1
), pp.
148
153
.10.1016/j.jpowsour.2007.11.013
18.
Kuhn
,
M.
,
Napporn
,
T.
,
Meunier
,
M.
,
Vengallatore
,
S.
, and
Therriault
,
D.
,
2008
, “
Direct-Write Microfabrication of Single-Chamber Micro Solid Oxide Fuel Cells
,”
J. Micromech. Microeng.
,
18
(
1
), p.
15005
.10.1088/0960-1317/18/1/015005
19.
Infortuna
,
A.
,
Harvey
,
A. S.
, and
Gauckler
,
L. J.
,
2008
, “
Microstructures CGO and YSZ Thin Films by Pulsed Laser Deposition
,”
Adv. Funct. Mater.
,
18
(
1
), pp.
127
135
.10.1002/adfm.200700136
20.
Wang
,
Z.
,
Weng
,
W.
,
Chen
,
K.
,
Shen
,
G.
,
Du
,
P.
, and
Han
,
G.
,
2008
, “
Preparation and Performance of Nanostructured Porous Thin Cathode for Low-Temperature Solid Oxide Fuel Cells by Spin-Coating Method
,”
J. Power Sources
,
175
(
1
), pp.
430
435
.10.1016/j.jpowsour.2007.09.092
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