Abstract

This article focuses on the transport properties of concretes reinforced with different amounts (0.05–0.5 wt.%) of pristine and functionalized carbon nanotubes (CNTs) with distinct aspect ratios (300, 667). To this end, concretes with different water-to-cement ratios were tested at distinct ages in terms of capillary absorption and oxygen permeability. The results show the ability of CNTs to decrease both capillary water absorption and oxygen permeability up to 42 and 71 %, respectively, depending on the type and amount of CNTs. Compressive strength increased up to 21 %. The best performance was found for 0.1 % CNTs of a lower aspect ratio. Higher amounts of CNTs did not lead to a proportional reduction of transport properties. CNTs were more effective in dried concrete compared to saturated ones where they could better participate in the pore refinement and microcrack retention. Transport properties correlated well with compressive strength, but oxygen permeability was greater affected by the incorporation of CNTs than other tested properties.

References

1.
Khatri
R. P.
and
Sirivivatnanon
V.
, “
Methods for the Determination of Water Permeability of Concrete
,”
ACI Materials Journal
94
, no. 
3
(May
1997
):
257
261
.
2.
Li
C. Q.
,
Zheng
J. J.
,
Lawanwisut
W.
, and
Melchers
R. E.
, “
Concrete Delamination Caused by Steel Reinforcement Corrosion
,”
Journal of Materials in Civil Engineering
19
, no. 
7
(July
2007
):
591
600
. https://doi.org/10.1061/(ASCE)0899-1561(2007)19:7(591)
3.
Monteiro
P. J. M.
and
Kurtis
K. E.
, “
Time to Failure for Concrete Exposed to Severe Sulfate Attack
,”
Cement and Concrete Research
33
, no. 
7
(July
2003
):
987
993
. https://doi.org/10.1016/S0008-8846(02)01097-9
4.
Šelih
J.
, “
Performance of Concrete Exposed to Freezing and Thawing in Different Saline Environments
,”
Journal of Civil Engineering and Management
16
, no. 
2
(October
2010
):
306
311
. https://doi.org/10.3846/jcem.2010.35
5.
Neville
A.
,
Properties of Concrete
(
London, UK
:
Pitman Publishing Ltd
,
1995
).
6.
Hall
C.
and
Yau
M. H. R.
, “
Water Movement in Porous Building Materials—IX. The Water Absorption and Sorptivity of Concretes
,”
Building and Environment
22
, no. 
1
(
1987
):
77
82
. https://doi.org/10.1016/0360-1323(87)90044-8
7.
Garboczi
E. J.
, “
Microstructure and Transport Properties of Concrete
,” in
Performance Criteria for Concrete Durability
, ed.
Kropp
J.
and
Hilsdorf
H. K.
(
London, UK
:
E & FN Spon
,
1995
),
126
133
.
8.
Kropp
J.
, “
Relations between Transport Characteristics and Durability
,” in
Performance Criteria for Concrete Durability
, ed.
Kropp
J.
and
Hilsdorf
H. K.
(
London, UK
:
E & FN Spon
,
1995
),
65
90
.
9.
Klinkenberg
L. J.
,
The Permeability of Porous Media to Liquids and Gas, Document API-41-200
(
New York
:
American Petroleum Institute
,
1941
).
10.
Real
S.
and
Bogas
J. A.
, “
Oxygen Permeability of Structural Lightweight Aggregate Concrete
,”
Construction and Building Materials
137
(April
2017
):
21
34
. https://doi.org/10.1016/j.conbuildmat.2017.01.075
11.
Abbas
A.
,
Carcasses
M.
, and
Ollivier
J.-P.
, “
Gas Permeability of Concrete in Relation to Its Degree of Saturation
,”
Materials and Structures
32
, no. 
1
(January
1999
):
3
8
. https://doi.org/10.1007/BF02480405
12.
Grube
H.
and
Lawrence
C. D.
, “
Permeability of Concrete to Oxygen
,” in
RILEM Seminar on Durability of Concretes Structures under Normal Outdoor Exposure
(
Cham, Switzerland
:
Springer Nature
,
1984
),
68
79
.
13.
Dinku
A.
and
Reinhardt
H. W.
, “
Gas Permeability Coefficient of Cover Concrete as a Performance Control
,”
Materials and Structures
30
, no. 
7
(August
1997
):
387
393
. https://doi.org/10.1007/BF02498560
14.
Martys
N. S.
and
Ferraris
C. F.
, “
Capillary Transport in Mortars and Concrete
,”
Cement and Concrete Research
27
, no. 
5
(May
1997
):
747
760
. https://doi.org/10.1016/S0008-8846(97)00052-5
15.
RILEM “
TC 116-PCD: Permeability of Concrete as a Criterion of Its Durability. Final Report: Concrete Durability—An Approach towards Performance Testing
,”
Materials and Structures
32
, no. 
217
(April
1999
):
163
173
. https://doi.org/10.1007/BF02481509
16.
Mehta
P. K.
and
Monteiro
P. J. M.
,
Concrete: Microstructure, Properties, and Materials
(
New York
:
McGraw-Hill Education
,
2006
).
17.
Bogas
J. A.
,
Gomes
M. G.
, and
Real
S.
, “
Capillary Absorption of Structural Lightweight Aggregate Concrete
,”
Materials and Structures
48
, no. 
9
(September
2015
):
2869
2883
. https://doi.org/10.1617/s11527-014-0364-x
18.
Ollivier
J.-P.
,
Massat
M.
, and
Parrott
L.
, “
Parameters Influencing Transport Characteristics
,” in
Performance Criteria for Concrete Durability
, ed.
Kropp
J.
and
Hilsdorf
H. K.
(
London, UK
:
E & FN Spon
,
1995
),
33
92
.
19.
Jayapalan
A. R.
,
Lee
B. Y.
,
Fredrich
S. M.
, and
Kurtis
K. E.
, “
Influence of Additions of Anatase TiO2 Nanoparticles on Early-Age Properties of Cement-Based Materials
,”
Transportation Research Record
2141
, no. 
1
(January
2010
):
41
46
. https://doi.org/10.3141%2F2141-08
20.
Nazari
A.
and
Riahi
S.
, “
The Effects of Zinc Dioxide Nanoparticles on Flexural Strength of Self-Compacting Concrete
,”
Composites Part B: Engineering
42
, no. 
2
(March
2011
):
167
175
. https://doi.org/10.1016/j.compositesb.2010.09.001
21.
Ahmed
H.
,
Bogas
J. A.
,
Guedes
M.
, and
Pereira
M. F. C.
, “
Dispersion and Reinforcement Efficiency of Carbon Nanotubes in Cementitious Composites
,”
Magazine of Concrete Research
71
, no. 
8
(April
2019
):
408
423
. https://doi.org/10.1680/jmacr.17.00562
22.
Hawreen
A.
,
Bogas
J. A.
, and
Dias
A. P. S.
, “
On the Mechanical and Shrinkage Behavior of Cement Mortars Reinforced with Carbon Nanotubes
,”
Construction and Building Materials
168
(April
2018
):
459
470
. https://doi.org/10.1016/j.conbuildmat.2018.02.146
23.
Carriço
A.
,
Bogas
J. A.
,
Hawreen
A.
, and
Guedes
M.
, “
Durability of Multi-Walled Carbon Nanotube Reinforced Concrete
,”
Construction and Building Materials
164
(March
2018
):
121
133
. https://doi.org/10.1016/j.conbuildmat.2017.12.221
24.
Nochaiya
T.
and
Chaipanich
A.
, “
Behavior of Multi-Walled Carbon Nanotubes on the Porosity and Microstructure of Cement-Based Materials
,”
Applied Surface Science
257
, no. 
6
(January
2011
):
1941
1945
. https://doi.org/10.1016/j.apsusc.2010.09.030
25.
Makar
J. M.
and
Chan
G. W.
, “
Growth of Cement Hydration Products on Single-Walled Carbon Nanotubes
,”
Journal of the American Ceramic Society
92
, no. 
6
(June
2009
):
1303
1310
. https://doi.org/10.1111/j.1551-2916.2009.03055.x
26.
Hawreen
A.
,
Bogas
J.
, and
Guedes
M.
, “
Mechanical Behavior and Transport Properties of Cementitious Composites Reinforced with Carbon Nanotubes
,”
Journal of Materials in Civil Engineering
30
, no. 
10
(October
2018
): 04018257. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002470
27.
Musso
S.
,
Tulliani
J.-M.
,
Ferro
G.
, and
Tagliaferro
A.
, “
Influence of Carbon Nanotubes Structure on the Mechanical Behavior of Cement Composites
,”
Composites Science and Technology
69
, nos. 
11–12
(September
2009
):
1985
1990
. https://doi.org/10.1016/j.compscitech.2009.05.002
28.
Abu Al-Rub
R. K.
,
Ashour
A. I.
, and
Tyson
B. M.
, “
On the Aspect Ratio Effect of Multi-Walled Carbon Nanotube Reinforcements on the Mechanical Properties of Cementitious Nanocomposites
,”
Construction and Building Materials
35
(October
2012
):
647
655
. https://doi.org/10.1016/j.conbuildmat.2012.04.086
29.
Zou
B.
,
Chen
S. J.
,
Korayem
A. H.
,
Collins
F.
,
Wang
C. M.
, and
Duan
W. H.
, “
Effect of Ultrasonication Energy on Engineering Properties of Carbon Nanotube Reinforced Cement Pastes
,”
Carbon
85
(April
2015
):
212
220
. https://doi.org/10.1016/j.carbon.2014.12.094
30.
Hawreen
A.
and
Bogas
J. A.
, “
Influence of Carbon Nanotubes on Steel–Concrete Bond Strength
,”
Materials and Structures
51
, no. 
6
(December
2018
): 155. https://doi.org/10.1617/s11527-018-1279-8
31.
Han
B.
,
Yang
Z.
,
Shi
X.
, and
Yu
X.
, “
Transport Properties of Carbon-Nanotube/Cement Composites
,”
Journal of Materials Engineering and Performance
22
, no. 
1
(January
2013
):
184
189
. https://doi.org/10.1007/s11665-012-0228-x
32.
Guedes
M.
,
Ahmed
H. H.
,
Bogas
J.
, and
Olhero
S.
, “
Experimental Procedure for Evaluation of CNT Dispersion in High pH Media Characteristic of Cementitious Matrixes
” (paper presentation, First Congress of Tests and Experimentation in Civil Engineering,
Lisbon, Portugal
, June 4,
2016
).
33.
Hawreen
A.
and
Bogas
J. A.
, “
Creep, Shrinkage and Mechanical Properties of Concrete Reinforced with Different Types of Carbon Nanotubes
,”
Construction and Building Materials
198
(February
2019
):
70
81
. https://doi.org/10.1016/j.conbuildmat.2018.11.253
34.
Bogas
J. A.
,
Hawreen
A.
,
Olhero
S.
,
Ferro
A. C.
, and
Guedes
M.
, “
Selection of Dispersants for Stabilization of Unfunctionalized Carbon Nanotubes in High pH Aqueous Suspensions: Application to Cementitious Matrices
,”
Applied Surface Science
463
(January
2019
):
169
181
. https://doi.org/10.1016/j.apsusc.2018.08.196
35.
Cement. Composition, Specifications and Conformity Criteria for Common Cements
, BS EN197-1:2011 (
London, UK
:
British Standards Institution
,
2011
).
36.
Concrete. Specification, Performance, Production and Conformity
, BS EN206-1:2000 (
London, UK
:
British Standards Institution
,
2000
).
37.
Testing Hardened Concrete. Compressive Strength of Test Specimens
(Superseded), BS EN12390-3:2009 (
London, UK
:
British Standards Institution
,
2009
).
38.
Concrete. Determination of Water Absorption by Capillarity
(in Portuguese), LNEC E393:1993 (
Lisbon, Portugal
:
Laboratório Nacional de Engenharia Civil
,
1993
).
39.
Concrete: Determination of Oxygen Permeability
(in Portuguese), LNEC E392:1993 (
Lisbon, Portugal
:
Laboratório Nacional de Engenharia Civil
,
1993
).
40.
Nasibulina
L. I.
,
Anoshkin
I. V.
,
Nasibulin
A. G.
,
Cwirzen
A.
,
Penttala
V.
, and
Kauppinen
E. I.
, “
Effect of Carbon Nanotube Aqueous Dispersion Quality on Mechanical Properties of Cement Composite
,”
Journal of Nanomaterials
2012
(January
2012
): 169262. https://doi.org/10.1155/2012/169262
41.
Hall
C.
, “
Water Sorptivity of Mortars and Concretes: A Review
,”
Magazine of Concrete Research
41
, no. 
147
(June
1989
):
51
61
. https://doi.org/10.1680/macr.1989.41.147.51
42.
Castro
J.
,
Bentz
D.
, and
Weiss
J.
, “
Effect of Sample Conditioning on the Water Absorption of Concrete
,”
Cement and Concrete Composites
33
, no. 
8
(September
2011
):
805
813
. https://doi.org/10.1016/j.cemconcomp.2011.05.007
43.
Parrott
L. J.
, “
Water Absorption in Cover Concrete
,”
Materials and Structures
25
, no. 
5
(June
1992
):
284
292
. https://doi.org/10.1007/BF02472669
44.
Söylev
T. A.
and
Özturan
T.
, “
Durability, Physical and Mechanical Properties of Fiber-Reinforced Concretes at Low-Volume Fraction
,”
Construction and Building Materials
73
(December
2014
):
67
75
. https://doi.org/10.1016/j.conbuildmat.2014.09.058
45.
Toutanji
H. A.
, “
Properties of Polypropylene Fiber Reinforced Silica Fume Expansive-Cement Concrete
,”
Construction and Building Materials
13
, no. 
4
(June
1999
):
171
177
. https://doi.org/10.1016/S0950-0618(99)00027-6
46.
Miloud
B.
, “
Permeability and Porosity Characteristics of Steel Fiber Reinforced Concrete
,”
Asian Journal of Civil Engineering (Building and Housing)
6
, no. 
4
(October
2005
):
317
330
.
47.
Huang
W.
, “
Improving the Properties of Cement–Fly Ash Grout Using Fiber and Superplasticizer
,”
Cement and Concrete Research
31
, no. 
7
(July
2001
):
1033
1041
. https://doi.org/10.1016/S0008-8846(01)00527-0
48.
Yazdanbakhsh
A.
and
Grasley
Z.
, “
The Theoretical Maximum Achievable Dispersion of Nanoinclusions in Cement Paste
,”
Cement and Concrete Research
42
, no. 
6
(June
2012
):
798
804
. https://doi.org/10.1016/j.cemconres.2012.03.001
49.
Geiker
M.
,
Grube
H.
,
Luping
T.
,
Nilsson
L.
, and
Andrade
C.
, “
Laboratory Test Methods
,” in
Performance Criteria for Concrete Durability
, ed.
Kropp
J.
and
Hilsdorf
H. K.
(
London, UK
:
E & FN Spon
,
1995
),
213
252
.
50.
Kameche
Z. A.
,
Ghomari
F.
,
Choinska
M.
, and
Khelidj
A.
, “
Assessment of Liquid Water and Gas Permeabilities of Partially Saturated Ordinary Concrete
,”
Construction and Building Materials
65
(August
2014
):
551
565
. https://doi.org/10.1016/j.conbuildmat.2014.04.137
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