Abstract

Currently, foam concrete is commonly used for various construction applications such as partitions, filling grades, road embankment infills, and sound and heat insulation. It is to be noted that the foam production parameters have significant influence on the cellular structure of foam concrete, which governs the material properties of concrete. Hence, in an attempt to improve the foam quality, the present work focuses on evaluation of the suitability of viscosity enhancing agent carboxymethyl cellulose (CMC) in performance improvement of foam produced with surfactant sodium lauryl sulfate (SLS) for use in foam concrete production. Firstly, the influence of the addition of CMC on behavior of foam produced with surfactant SLS was studied by evaluating essential characteristics such as foam density, foam stability, and viscosity of surfactant solution. As a next step, the microstructure of foam and its behavior in cement slurry and mortar at the optimized concentrations of SLS and CMC were studied. Experimental studies revealed that the addition of 0.2 % CMC to 2.5 % SLS surfactant solution resulted in a 134 % increase in viscosity of surfactant solution, which eventually resulted in tremendous improvement in foam quality in terms of 34 % reduction in foam drainage (at the 5th minute after foam generation) and 22 % reduction in larger size foam bubbles (D90). Furthermore, as the air void microstructure of foam concrete is dependent on the foam bubble sizes, the reduction in foam bubble sizes resulted in 20 % enhancement in compressive strength of foam concrete. The addition of CMC is also found to affect the workability of foam concrete mixes, which is evident from the reduction in flow spread and the increase in flow time. Also, as the foam has retarding properties, the increase in foam content is found to increase the demolding time requirement of foam concrete specimens.

References

1.
Amran
Y.
,
Farzadnia
N.
, and
Ali
A.
, “
Properties and Applications of Foamed Concrete; A Review
,”
Construction and Building Materials
101
, Part
1
(December
2015
):
990
1005
, https://doi.org/10.1016/j.conbuildmat.2015.10.112
2.
Sun
C.
,
Zhu
Y.
,
Guo
J.
,
Zhang
Y.
, and
Sun
G.
, “
Effects of Foaming Agent Type on the Workability, Drying Shrinkage, Frost Resistance and Pore Distribution of Foamed Concrete
,”
Construction and Building Materials
186
(October
2018
):
833
839
, https://doi.org/10.1016/j.conbuildmat.2018.08.019
3.
Ranjani
G. I. S.
and
Ramamurthy
K.
, “
Analysis of the Foam Generated Using Surfactant Sodium Lauryl Sulfate
,”
International Journal of Concrete Structures and Materials
4
, no. 
1
(
2010
):
55
62
, https://doi.org/10.4334/IJCSM.2010.4.1.055
4.
Karthikeyan
B.
,
Selvaraj
R.
, and
Saravanan
S.
, “
Mechanical Properties of Foam Concrete
,”
International Journal of Earth Sciences and Engineering
8
, no. 
2
(April
2015
):
115
119
.
5.
Falliano
D.
,
De Domenico
D.
,
Ricciardi
G.
, and
Gugliandolo
E.
, “
Experimental Investigation on the Compressive Strength of Foamed Concrete: Effect of Curing Conditions, Cement Type, Foaming Agent and Dry Density
,”
Construction and Building Materials
165
(March
2018
):
735
749
, https://doi.org/10.1016/j.conbuildmat.2017.12.241
6.
Standard Test Method for Foaming Agents for Use in Producing Cellular Concrete Using Preformed Foam
, ASTM C796/C796M-19 (
West Conshohocken, PA
:
ASTM International
, approved July 1,
2019
), https://doi.org/10.1520/C0796_C0796M-19
7.
Siva
M.
,
Ramamurthy
K.
, and
Dhamodharan
R.
, “
Sodium Salt Admixtures for Enhancing the Foaming Characteristics of Sodium Lauryl Sulphate
,”
Cement and Concrete Composites
57
(March
2015
):
133
141
, https://doi.org/10.1016/j.cemconcomp.2014.12.011
8.
Ospanova
Z. B.
,
Musabekov
K. B.
, and
Asadov
M. M.
, “
An Effect of Surfactants of Different Nature on Stabilization of Foaming Systems Containing Polyvinyl Alcohol
,”
Russian Journal of Applied Chemistry
87
, no. 
3
(
2014
):
355
359
, https://doi.org/10.1134/S1070427214030185
9.
Mirhosseini
H.
,
Tan
C. P.
,
Aghlara
A.
,
Hamid
N. S. A.
,
Yusof
S.
, and
Chern
B. H.
, “
Influence of Pectin and CMC on Physical Stability, Turbidity Loss Rate, Cloudiness and Flavor Release of Orange Beverage Emulsion During Storage
,”
Carbohydrate Polymers
73
, no. 
1
(July
2008
):
83
91
, https://doi.org/10.1016/j.carbpol.2007.11.002
10.
Çolak
A.
, “
Density and Strength Characteristics of Foamed Gypsum
,”
Cement and Concrete Composites
22
, no. 
3
(June
2000
):
193
200
, https://doi.org/10.1016/S0958-9465(00)00008-1
11.
Zhu
X.
,
Zhan
F.
,
Zhao
Y.
,
Han
Y.
,
Chen
X.
, and
Li
B.
, “
Improved Foaming Properties and Interfacial Observation of Sodium Caseinate-Based Complexes: Effect of Carboxymethyl Cellulose
,”
Food Hydrocolloids
105
(August
2020
): 105758, https://doi.org/10.1016/j.foodhyd.2020.105758
12.
Ospanova
Z.
,
Musabekov
K.
,
Aidarova
S.
,
Adilbekova
A.
,
Esimova
O.
, and
Kerimkulova
M.
, “
Effect of Sodium Carboxymethylcellulose on the Surface Tension of Alkylsulphates
,”
Materials Research Innovations
19
, no. sup
5
(
2015
):
S5-1172
S5-1174
, https://doi.org/10.1179/1432891714Z.0000000001272
13.
Powale
R. S.
and
Bhagwat
S. S.
, “
Influence of Electrolytes on Foaming of Sodium Lauryl Sulfate
,”
Journal of Dispersion Science and Technology
27
, no. 
8
(
2006
):
1181
1186
, https://doi.org/10.1080/01932690600859804
14.
Nambiar
E. K. K.
and
Ramamurthy
K.
, “
Fresh State Characteristics of Foam Concrete
,”
Journal of Materials Civil Engineering
20
, no. 
2
(
2008
):
111
117
, https://doi.org/10.1061/(ASCE)0899-1561(2008)20:2(111)
15.
Kearsley
E.
and
Visagie
M.
, “
Micro-Properties of Foamed Concrete
,” in
Proceedings of the International Conference on Specialist Techniques and Materials for Construction, ed. R. K. Dhir and N. A. Henderson
(
London
:
Thomas Telford Publishing
,
1999
),
173
184
.
16.
Panesar
D. K.
, “
Cellular Concrete Properties and the Effect of Synthetic and Protein Foaming Agents
,”
Construction and Building Materials
44
(July
2013
):
575
584
, https://doi.org/10.1016/j.conbuildmat.2013.03.024
17.
Samson
G.
,
Phelipot-Mardelé
A.
, and
Lanos
C.
, “
Thermal and Mechanical Properties of Gypsum–Cement Foam Concrete: Effects of Surfactant
,”
European Journal of Environmental and Civil Engineering
21
, no. 
12
(
2017
):
1502
1521
, https://doi.org/10.1080/19648189.2016.1177601
18.
Kuzielová
E.
,
Pach
L.
, and
Palou
M.
, “
Effect of Activated Foaming Agent on the Foam Concrete Properties
,”
Construction and Building Materials
125
(October
2016
):
998
1004
, https://doi.org/10.1016/j.conbuildmat.2016.08.122
19.
Liu
C.
,
Luo
J.
,
Li
Q.
,
Gao
S.
,
Su
D.
,
Zhang
J.
, and
Chen
S.
, “
Calcination of Green High-Belite Sulphoaluminate Cement (GHSC) and Performance Optimizations of GHSC-Based Foamed Concrete
,”
Materials & Design
182
(November
2019
): 107986, https://doi.org/10.1016/j.matdes.2019.107986
20.
She
W.
,
Du
Y.
,
Miao
C.
,
Liu
J.
,
Zhao
G.
,
Jiang
J.
, and
Zhang
Y.
, “
Application of Organic- and Nanoparticle-Modified Foams in Foamed Concrete: Reinforcement and Stabilization Mechanisms
,”
Cement and Concrete Research
106
(April
2018
):
12
22
, https://doi.org/10.1016/j.cemconres.2018.01.020
21.
Kearsley
E. P.
and
Wainwright
P. J.
, “
The Effect of Porosity on the Strength of Foamed Concrete
,”
Cement and Concrete Research
32
, no. 
2
(February
2002
):
233
239
, https://doi.org/10.1016/S0008-8846(01)00665-2
22.
Nambiar
E. K. K.
and
Ramamurthy
K.
, “
Air‐Void Characterisation of Foam Concrete
,”
Cement and Concrete Research
37
, no. 
2
(February
2007
):
221
230
, https://doi.org/10.1016/j.cemconres.2006.10.009
23.
Nambiar
E. K. K.
and
Ramamurthy
K.
, “
Shrinkage Behavior of Foam Concrete
,”
Journal of Materials in Civil Engineering
21
, no. 
11
(November
2009
):
631
636
, https://doi.org/10.1061/(ASCE)0899-1561(2009)21:11(631)
24.
Chindaprasirt
P.
and
Rattanasak
U.
, “
Shrinkage Behavior of Structural Foam Lightweight Concrete Containing Glycol Compounds and Fly Ash
,”
Materials & Design
32
, no. 
2
(February
2011
):
723
727
, https://doi.org/10.1016/j.matdes.2010.07.036
25.
G. Indu Siva Ranjani and
Ramamurthy
K.
, “
Behaviour of Foam Concrete Under Sulphate Environments
,”
Cement and Concrete Composites
34
, no. 
7
(August
2012
):
825
834
, https://doi.org/10.1016/j.cemconcomp.2012.03.007
26.
Ordinary Portland Cement – Specification (Sixth Revision)
, IS 269:2015 (New Delhi, India:
Bureau of Indian Standards
,
2015
).
27.
Gido
S. P.
,
Hirt
D. E.
,
Montgomery
S. M.
,
Prud’homme
R. K.
, and
Rebenfeld
L.
, “
Foam Bubble Size Measured Using Image Analysis before and after Passage through a Porous Medium
,”
Journal of Dispersion Science and Technology
10
, no. 
6
(
1989
):
785
793
, https://doi.org/10.1080/01932698908943199
28.
Hirt
D. E.
,
Prud’homme
R. K.
, and
Rebenfeld
L.
, “
Characterization of Foam Cell Size and Foam Quality Using Factorial Design Analyses
,”
Journal of Dispersion Science and Technology
8
, no. 
1
(
1987
):
55
73
, https://doi.org/10.1080/01932698708943592
29.
Foam Liquids, Fire Extinguishing (Concentrates, Foam, Fire Extinguishing)
, Defstand 42-40/2 (
2002
) (London:
UK Ministry of Defence Standards
).
30.
National Institutes of Health “
ImageJ
,”
National Institutes of Health
,
2006
, http://web.archive.org/web/20200808050434/https://imagej.nih.gov/ij/
31.
Standard Specification for Flow Table for Use in Tests of Hydraulic Cement (Superseded)
, ASTM C230/C230M-14 (
West Conshohocken, PA
:
ASTM International
, approved October 1,
2014
), https://doi.org/10.1520/C0230_C0230M-14
32.
Jones
M. R.
,
McCarthy
M. J.
, and
McCarthy
A.
, “
Moving Fly Ash Utilisation in Concrete Forward: A UK Perspective
,” in
2003 International Ash Utilization Symposium
(
Lexington, KY
:
Center for Applied Energy Research, University of Kentucky
,
2003
), paper 113.
33.
Siva
M.
,
Ramamurthy
K.
, and
Dhamodharan
R.
, “
Development of a Green Foaming Agent and Its Performance Evaluation
,”
Cement and Concrete Composites
80
(July
2017
):
245
257
, https://doi.org/10.1016/j.cemconcomp.2017.03.012
34.
Standard Test Method for Compressive Strength of Lightweight Insulating Concrete (Superseded)
, ASTM C495/C495M-12 (
West Conshohocken, PA
:
ASTM International
, approved April 1,
2012
), https://doi.org/10.1520/C0495_C0495M-12
35.
Jones
M. R.
and
McCarthy
A.
, “
Behaviour and Assessment of Foamed Concrete for Construction Applications
,” in
Use of Foamed Concrete in Construction
, ed.
Dhir
R. K
,
Newlands
M. D.
, and
McCarthy
A.
(
London
:
Thomas Telford Publishing
,
2005
),
61
88
.
36.
Nambiar
E. K. K.
and
Ramamurthy
K.
, “
Influence of Filler Type on the Properties of Foam Concrete
,”
Cement and Concrete Composites
28
, no. 
5
(May
2006
):
475
480
, https://doi.org/10.1016/j.cemconcomp.2005.12.001
37.
Kashani
A.
,
Ngo
T. D.
,
Nguyen
T. N.
,
Hajimohammadi
A.
,
Sinaie
S.
, and
Mendis
P.
, “
The Effects of Surfactants on Properties of Lightweight Concrete Foam
,”
Magazine of Concrete Research
72
, no. 
4
(February
2020
):
163
172
, https://doi.org/10.1680/jmacr.18.00242
38.
Sharma
M. K.
and
Sharma
G. D.
, eds.,
Particle Technology and Surface Phenomena in Minerals and Petroleum
(
New York
:
Springer
,
1991
).
39.
Grządka
E.
, “
The Adsorption Layer in the System: Carboxymethylcellulose/Surfactants/NaCl/MnO2
,”
Journal of Surfactants and Detergents
15
, no. 
4
(
2012
):
513
521
, https://doi.org/10.1007/s11743-012-1340-5
40.
Osei-Bonsu
K.
,
Shokri
N.
, and
Grassia
P.
, “
Fundamental Investigation of Foam Flow in a Liquid-Filled Hele-Shaw Cell
,”
Journal of Colloid and Interface Science
462
(January
2016
):
288
296
, https://doi.org/10.1016/j.jcis.2015.10.017
41.
Kroezen
A. B. J.
,
Wassink
J. G.
, and
Schipper
C. A. C.
, “
The Flow Properties of Foam
,”
Journal of the Society of Dyers and Colourists
104
, no. 
10
(October
1988
):
393
400
, https://doi.org/10.1111/j.1478-4408.1988.tb01138.x
42.
Standard Specification for Foaming Agents Used in Making Preformed Foam for Cellular Concrete (Superseded)
, ASTM C869/C869M-11 (
West Conshohocken, PA
:
ASTM International
, approved July 1,
2011
), https://doi.org/10.1520/C0869_C0869M-11
43.
Sathya Narayanan
J.
and
Ramamurthy
K.
, “
Identification of Set-Accelerator for Enhancing the Productivity of Foam Concrete Block Manufacture
,”
Construction and Building Materials
37
(December
2012
):
144
152
, https://doi.org/10.1016/j.conbuildmat.2012.07.025
44.
Jones
M.
, “
Foamed Concrete for Structural Use
,” in
Proceedings of One Day Seminar on Foamed Concrete: Applications and Latest Technological Developments
(
Loughborough, UK
:
Loughborough University
,
2001
),
28
60
.
45.
Mishra
P. C.
,
Singh
V. K.
,
Narang
K. K.
, and
Singh
N. K.
, “
Effect of Carboxymethyl-Cellulose on the Properties of Cement
,”
Materials Science and Engineering: A
357
, nos. 
1–2
(September
2003
):
13
19
, https://doi.org/10.1016/S0921-5093(02)00832-8
46.
Ramamurthy
K.
and
Narayanan
N.
, “
Factors Influencing the Density and Compressive Strength of Aerated Concrete
,”
Magazine of Concrete Research
52
, no. 
3
(June
2000
):
163
168
, https://doi.org/10.1680/macr.2000.52.3.163
47.
Kearsley
E. P.
and
Wainwright
P. J.
, “
Porosity and Permeability of Foamed Concrete
,”
Cement and Concrete Research
31
, no. 
5
(May
2001
):
805
812
, https://doi.org/10.1016/S0008-8846(01)00490-2
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