Skip to Main Content
Skip Nav Destination
ASTM Selected Technical Papers
Pesticide Formulation and Delivery Systems: 36th Volume, Emerging Trends Building on a Solid Foundation
By
Craig Poffenberger
Craig Poffenberger
Symposium Chairperson and STP Editor
1
Evonik Corporation
?
Richmond, VA,
US
Search for other works by this author on:
Justin Heuser
Justin Heuser
Symposium Chairperson and STP Editor
2
Evonik Corporation
?
Richmond, VA,
US
Search for other works by this author on:
ISBN:
978-0-8031-7635-5
No. of Pages:
222
Publisher:
ASTM International
Publication date:
2016

Using high-speed video techniques, the influence of diluted polyether siloxane emulsions on the breakup mechanism of liquid spray films was investigated. First, the fragmentation of a single drop in an air flow, the so-called bag breakup, was used as a model system to study the ability of the polyether siloxane emulsion to control the breakup process. What was learned from these model experiments was then transferred to spray experiments using classical agricultural flat-fan nozzles. These demonstrated that polyether siloxane emulsions cause the nucleation of holes in an expanding liquid film, which leads to an accelerated, more uniform, and earlier breakup. Image-based drop size measurements confirmed that the promoted lamella breakup in turn leads to a considerable reduction of drift-prone droplets in the spray. Low-speed wind tunnel spray studies were conducted in order verify the findings from the high-speed video experiments.

1.
Hazen
,
J. L.
1996
.
Guar as a drift control agent
. U.S. Patent 5,550,224, filed January 3,
1994
, and issued August 27,
1996
.
2.
Bronner
,
J. A.
,
Moore
,
J. D.
, and
Dale
,
P. R.
1985
.
Drift control concentrate
. U.S. Patent 4,510,081, filed February 15,
1983
, and issued April 9,
1985
.
3.
Rippstein
,
W. J.
1984
.
Drift influencing composition
. U.S. Patent 4,447,413, filed July 17,
1981
, and issued May 8,
1984
.
4.
Mun
,
R. P.
,
Young
,
B. W.
, and
Boger
,
D. V.
, “
Atomization of Dilute Polymer Solutions in Agricultural Spray Nozzles
,”
Journal of Non-Newtonian Fluid Mechanics
, Vol.
83
, No.
1
,
1999
, pp. 163–178.
5.
Rose
,
S. A. H.
,
Hey
,
S. M.
, and
Early
,
J. E.
,
Process for preparing and applying pesticide or herbicide formulation
. WO Patent WO2008101818 A2, filed February 8,
2008
, and issued August 28,
2008
.
6.
Downer
,
B. M.
,
Mei
,
L.
,
Liu
,
L.
,
Qin
,
K.
,
Tank
,
H.
,
Wilson
,
S. L.
, and
Zhang
,
H.
,
Amine and amine oxide surfactants for controlling herbicide spray drift
. U.S. Patent 20140179529 A1, filed February 27,
2014
, and issued June 26,
2014
.
7.
Worthley
,
R.
and
Bergmann
,
D.
Lecithin-containing drift reduction composition for use in spraying agricultural acreage
. U.S. Patent 6797673, filed December 18,
2002
, and issued September 28,
2004
.
8.
Qin
,
K.
,
Tank
,
H.
,
Wilson
,
S.
,
Liu
,
L.
,
Ouse
,
D. G.
, and
Li
,
M.
,
Controlling spray drift of pesticide with self-emulsifiable esters
. WO Patent 02010051435 A2, filed October 30,
2009
, and issued May 6,
2010
.
9.
Qin
,
K.
,
Cloeter
,
M.
,
Tank
,
H.
,
Liu
,
L.
,
Wilson
,
S.
, and
Yin
,
D.-W.
, “
Modeling the Spray Atomization of Emulsion Embedded Agricultural Solutions
,”
J. ASTM Intl.
, Vol.
7
, No.
10
,
2010
, pp. 1–9.
10.
Opfer
,
L.
, “
Controlling Liquid Atomization Using Dilute Emulsions: Migitation of Pesticide Spray Drift
,” PhD dissertation,
Technische Universität Darmstadt
, Germany,
2014
.
11.
Pugh
,
R.
, “
Foaming, Foam Films, Antifoaming and Defoaming
,”
Advances in Colloid and Interface Science
, Vol.
64
,
1996
, pp. 67–142.
12.
Venzmer
,
J.
, “
Grenzflächenchemische Spezialitäten
,”
Chemie in unserer Zeit
, Vol.
42
,
2008
, pp. 72–79.
13.
Denkov
,
N. D.
, “
Mechanisms of Foam Destruction by Oil-Based Antifoams
,”
Langmuir
, Vol.
20
, No.
22
,
2004
, pp. 9463–9505.
This content is only available via PDF.
You do not currently have access to this chapter.
Close Modal

or Create an Account

Close Modal
Close Modal