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ASTM Selected Technical Papers
Pesticide Formulations and Delivery Systems: The Continued Evolution of Agrochemicals, 24th Volume
By
GR Goss
GR Goss
1
Oil-Dri Corporation
?
Chicago, IL Co-editor
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GC Volgas
GC Volgas
2
Helena Chemical Company
?
Memphis, TN Co-editor
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M Salyani
M Salyani
3
University of Florida
?
Lake Alfred, FL Symposium co-chairman and co-editor
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ISBN-10:
0-8031-3485-1
ISBN:
978-0-8031-3485-0
No. of Pages:
151
Publisher:
ASTM International
Publication date:
2005

Dissolution rate of 16 sulfonated dispersants was measured in both water and 32-0-0 liquid fertilizer. Two dispersants, BNA and UCA, having different dissolution rates, were used to granulate a 70 % Amicarbazone formulation. Extrusions were made on a MG-55 Multigranulator using both the dome and radial modes with 0.8 mm and 1.0 mm screens. BNA and UCA were included at levels of 5, 10, and 15% of the formulation. The remaining 14 dispersants were compared at fixed levels of 10 % using only the 0.8 mm screen and dome mode. Premix water requirements varied according to dispersant chemistry. Granule disintegration was measured in hard water by number of inversions, ASTM E l945, and CIPAC MT-174. High level of dispersant, slow dissolution rate of dispersant, and larger diameter granules lead to reduced disintegration rate in water. In addition to these factors, disintegration in 32-0-0 was further affected by porosity of the granule.

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Martin
,
P. J.
, “
Mechanics of Paste Flow in Radial Screen Extruders
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,
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.
2.
Delli Colli
,
H. T.
, and
Doring
I. W.
, “
The Physical Chemistry of WDGs: Porosity and Surfactant Dissolution as a Function of Dispersant Molecular Weight
,”
Pesticides Formulations and Applications Systems, 20th Volume
, STP 1400,
Viets
Alan K.
,
Scott Tann
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,
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Jane C.
, Eds.,
ASTM International
,
West Conshohocken, PA
,
1999
, pp. 141–151.
3.
Arakawa
,
T.
, and
Narhi
L. O.
, “
Solvent Modulation in Hydrophobic Interaction Chromatography
,”
Biotechnology Appl. BioChem.
, Vol.
13
,
1991
, pp. 151–172.
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