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ASTM Selected Technical Papers
Computer Modeling in CorrosionAvailable to Purchase
By
RS Munn
RS Munn
1
Naval Underwater Systems Center
?
New London, Connecticut
;
Symposium Chairman and Editor
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ISBN-10:
0-8031-1473-7
ISBN:
978-0-8031-1473-9
No. of Pages:
302
Publisher:
ASTM International
Publication date:
1992

A microcomputer-based software package is described that successfully models polarization curves and simulates redox behavior of a wide variety of electrochemical reactions. It also enables experimentally obtained polarization scans to be plotted over the computed scans for comparison. The paper defines an electrochemical model using established theoretical foundations and describes the means of achieving good computer representations of laboratory data. A description is given of the model, some of the applications to analysis of corrosion mechanisms, and aspects of its use in corrosion control. Applications discussed include the effect of electrolyte dilution for the purposes of scale modeling, and the introduction of paint films. Use of the model to investigate passivating systems by the simulation of the electrochemical corrosion behavior of stainless steels is described. By rapid investigation of changes in a large number of system and environmental parameters, the value of the model for corrosion education and as a research tool for advancing the theoretical foundations of corrosion will be demonstrated.

1.
Stern
,
M.
, and
Geary
,
A. L.
, “
Electrochemical Polarization: I—A Theoretical Analysis of the Shape of Polarization Curves
,”
Journal of the Electrochemical Society
 0013-4651, Vol.
104
, No.
1
,
1957
, pp. 56–63.
2.
Pye
,
E. L
,
Pye
,
M. L.
, and
Brock
,
F. H.
, “
Pol-Plot: Basic Electrodic Software: Simple to Complex
,” paper 102, NACE, Corrosion '88,
St. Louis
,
1988
.
3.
Rochini
,
G.
, “
Extension of Stern and Geary's Method for Calculating the Electrochemical Parameters with Interl Code
,” Paper 103, NACE, Corrosion '88,
St. Louis
,
1988
.
4.
Rochini
,
G.
, “
Determination of the Validity Interval of Linear Approximation Method with Interl Code
,” Paper 105, NACE, Corrosion '88,
St. Louis
,
1988
.
5.
Hines
,
J. G.
, “
Analysis of Complex Polarisation Curves
,”
British Corrosion Journal
 0007-0599, Vol.
18
, No.
1
,
1983
, pp. 10–14.
6.
Mansfeld
,
F.
,
Corrosion
, Vol.
29
,
1983
, p. 397.
7.
Costa
,
J. M.
and
Vilarassa
,
M.
, “
Microcomputer Programs for Corrosion Education
,” Institution of Corrosion Science and Technology, in
Proceedings
, U.K. Corrosion '88, Vol.
III
,
1988
, pp. 99–110.
8.
Devereaux
,
O. F.
, “
Polarization Curve Fitting by Computer Modelling
,”
Corrosion
, Vol.
35
,
1979
, p. 125.
9.
Trethewey
,
K. R.
, and
Keenan
,
J. S.
, “
The SIMPLER Computer Corrosion Modelling System
,”
Corrosion Prevention and Control
 0010-9371, Vol.
38
, No.
4
,
1991
, pp. 89–96.
10.
Shrier
,
L. L.
,
Corrosion
,
Newnes-Butterworths
,
London
, 2nd ed., pp. 1:52–1:110.
11.
Reiger
,
P. H.
,
Electrochemistry
,
Prentice-Hall
,
Englewood Cliffs, N.J.
,
1987
, pp. 269–293.
12.
Pourbaix
,
M.
,
Atlas of Electrochemical Equilibria in Aqueous Solutions
,
Pergamon Press
,
Oxford
,
1966
.
13.
Shrier
,
L. L.
,
Corrosion
,
Newnes-Butterworths
,
London
, 2nd ed., p. 21:36.
14.
Trethewey
,
K. R.
,
Marsh
,
D. J.
,
Every
,
P. D.
,
Dyson
,
P.
, and
Roberge
,
P. R.
, “
An Electrochemical Model of the Corrosion of Steel in Flowing Natural Seawater Using the Rotating Cylinder Electrode
,”
Corrosion
(submitted for publication).
15.
Shrier
,
L. L.
,
Corrosion
,
Newnes-Butterworths
,
London
, 2nd ed., p. 1:87.
16.
Trethewey
,
K. R.
and
Tighe-Ford
,
D. J.
, “
Polarisation Characteristics of Ship Hull Materials
,” Eighth Inter-Naval Corrosion Conference,
Monterey, Calif.
,
04
1992
, to be presented.
17.
Tighe-Ford
,
D. J.
, “
Pre-Design Considerations for Impressed Current Cathodic Protection Systems
,” presented to U.K. Corrosion '90,
10
1990
,
Institution of Corrosion Science and Technology
,
P.O. Box 253, Leighton Buzzard Beds, U.K
.
18.
Trethewey
,
K. R.
,
Keenan
,
J. S.
, and
Wilson
,
I.
, “
Analysis of the Electrochemical Behaviour of Stainless Steels Using the SIMPLER Computer Model
,”
Corrosion Prevention and Control
 0010-9371, Vol.
38
, No.
5
,
1991
, pp. 115–118.
19.
Verinck
,
E. D.
and
Heidersbach
,
R. H.
, “
Evaluation of the Tendency for Dealloying in Metal Systems
,” in
Localised Corrosion: Cause of Metal Failure
, ASTM STP 516,
American Society for Testing and Materials
,
Philadelphia
,
1972
, pp. 303–332.
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