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ASTM Selected Technical Papers
Materials Characterization by Thermomechanical Analysis
By
AT Riga
AT Riga
1
Lubrizol Corporation
?
Wickliffe, OH 44092
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MC Neag
MC Neag
2
Glidden Company
?
Strongsville, OH 44136
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ISBN-10:
0-8031-1434-6
ISBN:
978-0-8031-1434-0
No. of Pages:
203
Publisher:
ASTM International
Publication date:
1991

This paper provides both in-plane and out-of-plane coefficient of thermal expansions (CTEs) of a high-performance QUATREX 5010 epoxy/Kevlar-120 fabric composite printed circuit board (PCB). Although both a quartz push-rod dilatometer and a thermomechanical analyzer (TMA) were used to measure the in-plane CTEs, the results indicate that the dilatometer is a better choice for accurate, precise determinations, especially for Kevlar/epoxy composites that had a CTE of 3.5 ppm/°C in the x and y direction. Based on our past experience testing various composite PCB materials based on E-glass, quartz, and Kevlar reinforcements, epoxy, polyimide, BT/epoxy, cyanate ester, and so forth, we recommend the dilatometer for accurately measuring the in-plane CTEs of Kevlar- and quartz-reinforced PCBs, which generally are below 9 ppm/°C. The TMA method, which is a faster and easier method than the dilatometer method, can be used reliably for accurately measuring the in-plane CTEs of E-glass-reinforced PCBs, which generally range from 12 to 16 ppm/°C.

1.
Ibrahim
,
A. M.
,
Green
,
K. A.
,
Djordjevic
,
B. B.
, and
Venables
,
J. D.
, “
Dimensionally Stable, High Performance, QUATREX Epoxy Composites for Advanced Printed Circuit Boards -I
,”
Proceedings of the International SAMPE Symposium
, Vol.
32
,
04
1987
, pp. 1238–1249.
2.
Ibrahim
,
A. M.
, “
Processing-Structure-Property Relationships of Dimensionally Stable, High Performance QUATREX Epoxy/E-Glass Composites for Advanced Circuit Board Applications
,” presented at IPC Fall Meeting,
San Diego, CA
,
1986
.
3.
Ibrahim
,
A. M.
,
Shah
,
T. K.
,
Matienzo
,
L. J.
, and
Venables
,
J. D.
, “
Thermoplastic-Based Composites with Low CTE for Space Structures and Circuit Board Applications
,”
Proceedings of the International SAMPE Symposium Exhibit
, Vol.
31
,
04
1986
, pp. 669–680.
4.
Ibrahim
,
A. M.
,
Cozzo
,
T.
, and
Klemens
,
M.
, “
Processing and Thermophysical Properties Evaluation of New High Performance Composites of Potential Surface Mount Technology (SMT) Substrates
,”
10th Symposium on Thermophysical Properties
,
NBS
,
Gaithersburg, MD
,
06
1989
.
5.
Ibrahim
,
A. M.
and
Klemens
,
M. L.
, “
Processing and Properties of Quartz-Fabric-Reinforced IP-600 Composites for Advanced Printed Circuit Boards (PCBs)
,” presented at the
23rd ACS Middle Atlantic Regional Meeting
,
Cherry Hill, NJ
,
05
1989
.
6.
Ibrahim
,
A. M.
, “
Quartz-Fabric-Reinforced Thermoset and Thermoplastic Composites for SMT-PCBs for Military Applications
,”
Proceedings of the 3rd International SAMPE Electronics Conference
,
06
1989
, pp. 1266–1280.
7.
Ibrahim
,
A. M.
, “
Acetylene-Terminated Polyimide Composites for Advanced Electronic Packaging Applications
,” presented at the
Materials Research Society (MRS) Meeting
,
San Diego, CA
,
04
1989
, proceedings in press.
8.
Ibrahim
,
A. M.
and
Cozzo
,
T. F.
, “
Low Dielectric Constant Cyanate Ester Matrix Materials for Advanced Chip-on-Board (COB) Applications
,” presented at the
ACS Middle Atlantic Regional Meeting
,
Cherry Hill, NJ
,
05
1989
.
9.
Ibrahim
,
A. M.
, “
Importance of the Coefficient of Thermal Expansion (CTE) in the Printed Circuit (PC) Industry
,” presented at the
10th International Thermal Expansion Symposium
,
Boulder, CO
,
06
1989
.
10.
Ibrahim
,
A. M.
, “
Surface Mount Technology (SMT) Substrate Materials Requirements-A Brief Review
,” in
Proceedings of Materials Research Society (MRS) Symposium on Electronic Packaging Materials Science
, Vol.
18
,
1988
, p. 159.
11.
Ibrahim
,
A. M.
, “
Review of Performance and Reliability Requirements of SMT PCB Substrate Materials for Military Applications
,” presented/published in the
Proceedings of the 8th Annual International Electronics Packaging Society (IEPS) Conference
,
Dallas, TX
,
11
1988
, pp. 87–104.
12.
Ibrahim
,
A. M.
, “
SMT Demands on PCB Substrates
,”
Printed Circuit Fabrication (PC FAB)
,
07
1989
, p. 22.
13.
Ibrahim
,
A. M.
, “
New Requirements for Surface Mount Technology (SMT) Printed Circuit Board (PCB) Composites for Military Applications
,” presented at
Electronic Packaging and Interconnections International Conference
,
Florence, Italy
,
10
1989
.
14.
Love
,
G. F.
,
IPC Technical Review
,
1981
, pp. 12–19.
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