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ASTM Selected Technical Papers
Zirconium in the Nuclear Industry
By
RB Adamson
RB Adamson
1
General Electric Company
,
Pleasanton, California
;
symposium chairman and co-editor
Search for other works by this author on:
LFP Van Swam
LFP Van Swam
2
Exxon Nuclear Company, Inc.
,
Richland, Washington
;
symposium editorial chairman and co-editor
Search for other works by this author on:
ISBN-10:
0-8031-0935-0
ISBN:
978-0-8031-0935-3
No. of Pages:
846
Publisher:
ASTM International
Publication date:
1987

This paper reviews the state-of-the-art experimental work performed in several countries with respect to the acceptance criteria established for the emergency core cooling (ECC) in a loss-of-coolant accident (LOCA) of light water reactors (LWRs). It covers in detail oxidation, embrittlement, plastic deformation, and coolability of deformed rod bundles.

The main test results are discussed on the basis of research work performed at the Karlsruhe Nuclear Research Center (KfK) within the framework of the Nuclear Safety Project (PNS). Reference is made to test data obtained in other countries.

The paper concludes that the major mechanisms and consequences of oxidation, deformation, and emergency core cooling are sufficiently investigated in order to provide a reliable data base for safety assessments and licensing of LWRs. All test data prove that the ECC criteria are conservative and that the coolability of a LWR and the public safety in a LOCA can be maintained.

1.
Mann
,
C. A.
,
Hindle
,
E. D.
, and
Parsons
,
P. D.
, “
The Deformation of PWR Fuel in a LOCA
,”
U.K. Atomic Energy Authority Northern Division Report
ND-R-701 (S),
04
1982
.
2.
Pickman
,
D. O.
and
Fiege
,
A.
, “
Fuel Behavior under DBA Conditions
,” KfK 3880/1,
12
1984
, pp. 73-94.
3.
Scatena
,
G. J.
, “
Fuel Cladding Embrittlement During a Loss-of-Coolant Accident
,” NEDO-10674,
10
1972
.
4.
Parsons
,
P. D.
and
Miller
,
W. N.
, “
The Oxidation Kinetics of Zirconium Alloys Applicable to Loss-of-Coolant Accidents
,” A Review of Published Data, ND-R-7(S),
10
1977
.
5.
Ocken
,
H.
, “
An Improved Evaluation Model for Zircaloy Oxidation
,”
Nuclear Technology
, Vol.
47
,
1980
, pp. 343-357.
6.
Cathcart
,
J. V.
 et al
, “
Zirconium Metal-Water Oxidation Kinetics—IV: Reaction Rate Studies
,” ORNL/NUREG-17,
08
1977
.
7.
Biederman
,
R. R.
,
Sisson
,
R. D.
, Jr.
,
Jones
,
J. K.
, and
Dobson
,
W. G.
, “
A Study of Zircaloy-4-Steam Oxidation Reaction Kinetics
,” EPRI NP-734,
04
1978
.
8.
Urbanic
,
V. F.
and
Heidrick
,
T. R.
, “
High Temperature Oxidation of Zircaloy-2 and Zircaloy-4 in Steam
,”
Journal of Nuclear Materials
, Vol.
75
,
1978
, pp. 251-261.
9.
Suzuki
,
M.
,
Kawasaki
,
S.
, and
Furuta
,
T.
, “
Zircaloy-Steam Reaction and Embrittlement of the Oxidized Zircaloy Tube under Postulated Loss-of-Coolant Accident Conditions
,” JAERI-M 6879,
12
1976
.
10.
Brown
,
A. F.
,
Tucker
,
M. O.
,
Healey
,
T.
, and
Simpson
,
C. J.
, “
Oxide/α and α/β Phase Interface Advance Kinetics in Steam Oxidized Zircaloy-2
,” RD/B/N4882,
07
1980
.
11.
Leistikow
,
S.
,
Schanz
,
G.
, and
v. Berg
,
H.
, “
Kinetics and Morphology of Isothermal Steam Oxidation of Zircaloy-4 at 700–1300°C
,” KfK 2587,
03
1978
.
12.
Baker
,
L.
and
Just
,
L. C.
, “
Studies of Metal-Water Reactions at High Temperatures
,”
Experimental and Theoretical Studies of the Zirconium-Water Reaction
, ANL-6548,
05
1962
.
13.
Sawatzky
,
A.
,
Ledoux
,
G. A.
, and
Jones
,
S.
, “
The Oxidation of Zirconium During a High-Temperature Transient
,” in
Zirconium in the Nuclear Industry (Third Conference)
, ASTM STP 633,
American Society for Testing and Materials
,
Philadelphia
,
1977
, pp. 134-149.
14.
Leistikow
,
S.
,
Schanz
,
G.
, and
v. Berg
,
H.
, “
Investigations into the Temperature-Transient Steam Oxidation of Zircaloy-4 Cladding Material under Hypothetical PWR Loss-of-Coolant Accident Conditions
,” KfK 2810,
04
1979
.
15.
Malang
,
S.
, “
SIMTRAN-I—A Computer Code for the Simultaneous Calculation of Oxygen Distributions and Temperature Profiles in Zircaloy During Exposure to High-Temperature Oxidizing Environments
,” ORNL-5083,
11
1975
.
16.
Dobson
,
W. G.
and
Biederman
,
R. R.
, “
ZORO-1—A Finite Difference Computer Model for Zircaloy-4 Oxidation in Steam
,” EPRI-NP-347,
12
1976
.
17.
Malang
,
S.
and
Neitzel
,
H. J.
, “
Modelling of Zircaloy-Steam-Oxidation under Severe Fuel Damage Conditions
,”
OECD-NEA-CSNI/IAEA Specialists Meeting on Water Reactor Fuel Safety and Fission Product Release in Off-Normal and Accident Conditions
,
Risø National Laboratory
,
Denmark
,
05
1983
, Summary Report IWGFPT/16, pp. 213-219.
18.
Suzuki
,
M.
and
Kawasaki
,
S.
, “
Development of Computer Code PRECIP-II for Calculations of Zr-Steam Reaction
,”
Journal of Nuclear Science and Technology
, Vol.
17
,
1980
, pp. 291-300.
19.
Hofmann
,
P.
and
Neitzel
,
H. J.
, “
External and Internal Reaction of Zircaloy Tubing with Oxygen and UO2 and Its Modelling
,”
Fifth International Meeting on Thermal Nuclear Reactor Safety
,
Karlsruhe, FRG
,
09
1984
,
Proceedings
, Vol.
2
, KfK 3880/2, Dec. 1984, pp. 1015-1025.
20.
Hofmann
,
P.
and
Politis
,
C.
, “
The Kinetics of the Uranium Dioxide-Zircaloy Reactions at High Temperatures
,”
Journal of Nuclear Materials
, Vol.
87
,
1979
, pp. 375-397.
21.
Hofmann
,
P.
and
Kerwin-Peck
,
D.
, “
UO2/Zircaloy-4 Chemical Interactions from 1000 to 1700°C under Isothermal and Transient Temperature Conditions
,”
Journal of Nuclear Materials
, Vol.
124
,
1984
, pp. 80-105.
22.
Hofmann
,
P.
and
Spino
,
J.
, “
Stress Corrosion Cracking of Zircaloy-4 Cladding at Elevated Temperatures and Its Relevance to Transient LWR Fuel Rod Behaviour
,”
Journal of Nuclear Materials
, Vol.
125
,
1984
, pp. 85-95.
23.
Furuta
,
T.
,
Hashimoto
,
M.
,
Otomo
,
T.
,
Kawasaki
,
S.
, and
Honma
,
K.
, “
Deformation and Inner Oxidation of the Fuel Rod in a Loss-of-Coolant Accident Condition
,” JAERI-M 6339,
11
1975
.
24.
Furuta
,
T.
,
Uetsuka
,
H.
,
Kawasaki
,
S.
,
Hashimoto
,
M.
, and
Otomo
,
T.
, “
Extent of Oxide Layer at the Inner Surface of Burst Cladding
,” JAERI-M 9475,
04
1981
.
25.
Furuta
,
T.
and
Kawasaki
,
S.
, “
Reaction Behaviour of Zircaloy-4 in Steam Hydrogen Mixtures at High Temperature
,”
Journal of Nuclear Materials
, Vol.
105
,
1982
, pp. 119-131.
26.
Seiffert
,
S. L.
and
Hobbins
,
R. R.
, “
Oxidation and Embrittlement of Zircaloy-4 Cladding from High Temperature Film Boiling Operation
,” NUREG/CR-0517, TREE-1327, R3,
04
1979
.
27.
Karb
,
E. H.
,
Prüssmann
,
M.
,
Sepold
,
L.
,
Hofmann
,
P.
, and
Schanz
,
G.
, “
LWR Fuel Rod Behaviour in the FR2 In-pile Tests Simulating the Heatup Phase of a LOCA—Final Report
,” KfK 3346,
03
1983
.
28.
Hofmann
,
P.
,
Petersen
,
C.
,
Schanz
,
G.
, and
Zimmermann
,
H.
, “
In-pile Experimente zum Brennstabverhalten beim Kühlmittelverluststörfall: Ergebnisse der zerstörenden Nachuntersuchungen der Versuchsserie G (35000 MWd/tU)
,” KfK 3433,
06
1983
.
29.
Furuta
,
T.
,
Kawasaki
,
S.
,
Hashimoto
,
M.
, and
Otomo
,
T.
, “
Influence of Deformation on the Subsequent Steam Oxidation of Zircaloy Cladding
,” JAERI-M 6869,
12
1976
.
30.
Bradhurst
,
D. H.
and
Heuer
,
P. M.
, “
The Effects of Deformation on the High-Temperature Steam Oxidation of Zircaloy-2
,”
Journal of Nuclear Materials
, Vol.
55
,
1975
, pp. 311-326.
31.
Leistikow
,
S.
and
Kraft
,
S.
, “
Creep Rupture Testing of Zircaloy-4 Tubing under Superimposed High-Temperature Steam Oxidation at 900°C
,” in
Proceedings
,
6th European Congress on Metallic Corrosion
,
London
,
09
1977
, pp. 577-584.
32.
Hofmann
,
P.
, “
Über die mechanische Beanspruchung von Zirkonium, Zircaloy und anderen Werkstoffen durch die Bildung von Oxidschichten (Literaturstudie)
,” KfK Ext. 6/77-2,
06
1977
.
33.
Bocek
,
M.
and
Petersen
,
C.
, “
The Influence of Oxide Coatings on the Ductility of Zircaloy-4
,”
Journal of Nuclear Materials
, Vol.
80
,
1979
, pp. 303-313.
34.
Leistikow
,
S.
,
Kraft
,
R.
, and
Pott
,
E.
, “
Is Air a Suitable Environment for Simulation of Zircaloy/Steam High-Temperature Oxidation within Engineering Experiments?
” presented at
European Symposium on the Interaction Between Corrosion and Mechanical Stress at High Temperatures
,
Petten, The Netherlands
,
05
1980
.
35.
Leistikow
,
S.
and
Kraft
,
R.
, “
Kriech-Berst-Untersuchungen zum Kühlmittelverlust-Störfallverhalten von Zircaloy-4-Hüllrohren in Argon und Wasserdampf
,” in
Proceedings
,
Reaktortagung Hannover
,
FRG
,
04
1978
, pp. 549-552.
36.
Raff
,
S.
,
Bocek
,
M.
, and
Meyder
,
R.
, “
Mechanical Properties of Zircaloy—NORA
,” presented at
Seventh Water Reactor Safety Research Information Meeting
,
Gaithersburg, Md.
, 5–9 Nov. 1979.
37.
Chung
,
H. M.
,
Garde
,
A. M.
, and
Kassner
,
T. F.
, “
Mechanical Properties of Zircaloy Containing Oxygen
,” in
Light-Water-Reactor Safety Research Program, Quarterly Progress Report
, April–June 1975, ANL-75-58, pp. 47-83.
38.
Uetsuka
,
H.
,
Furuta
,
T.
, and
Kawasaki
,
S.
, “
Zircaloy-4 Cladding Embrittlement Due to Inner Surface Oxidation under Simulated Loss-of-Coolant Condition
,”
Journal of Nuclear Science and Technology
, Vol.
18
,
1981
, pp. 705-717.
39.
Uetsuka
,
H.
,
Furuta
,
T.
, and
Kawasaki
,
S.
, “
Zircaloy Cladding Embrittlement Due to Inner Surface Oxidation During a LOCA—Inner Surface Oxidation Experiment using a Simulated Fuel Rod (2)—Influences of UO2-Steam Reaction and Rapid Cooling
,” JAERI-M 9681,
08
1981
.
40.
Hobson
,
D. O.
and
Rittenhouse
,
P. L.
, “
Embrittlement of Zircaloy-Clad Fuel Rods by Steam During LOCA Transients
,” ORNL 4758,
01
1972
.
41.
Pawel
,
R. E.
, “
Oxygen Diffusion in Beta Zircaloy During Steam Oxidation
,”
Journal of Nuclear Materials
, Vol.
50
,
1974
, pp. 247-258.
42.
Chung
,
H. M.
and
Kassner
,
T. F.
, “
Embrittlement Criteria for Zircaloy Fuel Cladding Applicable to Accident Situations in Light-Water-Reactors—Summary Report
,” NUREG/CR-1344,
01
1980
.
43.
Furuta
,
T.
,
Uetsuka
,
H.
, and
Kawasaki
,
S.
, “
Estimation of Conservatism of Present Embrittlement Criteria for Zircaloy Fuel Cladding under LOCA
,” in
Zirconium in the Nuclear Industry: Sixth International Symposium
, ASTM STP 824,
American Society for Testing and Materials
,
Philadelphia
,
1984
, pp. 734-746.
44.
Haggag
,
F. M.
, “
Zircaloy Cladding Embrittlement Criteria: Comparison of In-Pile and Out-of-Pile Results
,” NUREG/CR-2757, EGG-2123, R3,
07
1982
.
45.
Busby
,
C. C.
and
Marsh
,
K. B.
, “
High Temperature Deformation and Burst Characteristics of Recrystallized Zircaloy-4 Tubing
,” WAPD-TM-900,
01
1970
.
46.
Hobson
,
D. O.
and
Rittenhouse
,
P. L.
, “
Deformation and Rupture Behavior of Light Water Reactor Fuel Cladding
,” ORNL-4727,
10
1971
.
47.
Hardy
,
D. G.
, “
High Temperature Expansion and Rupture Behavior of Zircaloy Tubing
,” presented at
ANS Topical Meeting on Water Reactor Safety
, CONF-730304,
Salt Lake City
,
03
1973
.
48.
Chapman
,
R. H.
, “
Multirod Burst Test Program—Quarterly Progress Report for April-June 1977
,” ORNL/NUREG/TM-135,
12
1977
.
49.
Chung
,
H. M.
and
Kassner
,
T. F.
, “
Deformation Characteristics of Zircaloy Cladding in Vacuum and Steam under Transient-Heating Conditions: Summary Report
,” NUREG/CR-0344,
07
1978
.
50.
Burman
,
D. L.
 et al
, “
Comparison of Westinghouse LOCA Burst Test Results with ORNL and other Program Results
,” presented at
CSNI Specialist Meeting on Safety Aspects of Fuel Behavior in Off-Normal and Accident Conditions
,
Espoo
,
Finland
,
09
1980
.
51.
MacDonald
,
P. E.
 et al
, “
Cladding Deformation During a Large Break LOCA
,” presented at
ANSENS Topical Meeting on Reactor Safety Aspects of Fuel Behavior
,
Sun Valley
,
Id.
,
08
1981
.
52.
Furuta
,
T.
 et al
, “
Zircaloy-Clad Fuel Rod Burst Behavior under Simulated Loss-of-Coolant Condition in Pressurized Water Reactors
,”
Journal of Nuclear Science and Technology
, Vol.
15
,
10
1978
, pp. 736-744.
53.
Hindle
,
E. D.
, “
Zircaloy Fuel Clad Ballooning Tests at 900-1070 K in Steam
,” ND-r-6 (s),
06
1977
, 1st supplement, Oct. 1977.
54.
Hindle
,
E. D.
and
Mann
,
C. A.
, “
An Experimental Study of the Deformation of Zircaloy PWR Fuel Rod Cladding under Mainly Convective Cooling
,” in
Zirconium in the Nuclear Industry (Fifth Conference)
, ASTM STP 754,
American Society for Testing and Materials
,
Philadelphia
,
1981
, pp. 284-302.
55.
Morize
,
P.
 et al
, “
Zircaloy Cladding Diametral Expansion During a LOCA, EDGAR programme
,” in
Proceedings
,
CSNI Specialist Meeting on the Behavior of Water Reactor Fuel Elements under Accident Conditions
, INIS-MF-3224,
Spatind
,
Norway
,
09
1976
, pp. 30-31.
56.
Friz
,
G.
 et al
, “
EOLO-JR: A Single Rod Burst Test Program in the ESSOR Reactor
,”
ANS-ENS Topical Meeting on Reactor Safety Aspects of Fuel Behavior
,
Sun Valley
,
Id.
,
08
1981
.
57.
Cheliotis
,
G.
 et al
, “
Verification of LOCA Clad Ballooning Behavior in Multi-Rod Tests by Means of Single Rod Investigations
,” in
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,
CSNI Specialist Meeting on Safety Aspects of Fuel Behaviour in Off-Normal and Accident Conditions
,
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,
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,
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1980
, pp. 111-140.
58.
Lehning
,
H.
 et al
, “
Berstversuche an Zircaloy-Hüllrohren unter kombinierter mechanisch-chemischer Beanspruchung (FABIOLA)
,” in
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59.
Bocek
,
M.
 et al
, “
Verification of Life Time Predictions by Means of Temperature-Transient Burst Tests on Zry-4 Fuel Rod Simulators
,” in
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,
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, pp. 223-237.
60.
Hofmann
,
P.
and
Raff
,
S.
, “
Verformungsverhalten von Zircaloy-4-Hüllrohren unter Schutzgas im Temperaturbereich zwischen 600 und 1200°C
,” KfK 3168,
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,
F.
 et al
, “
Out-of-Pile Experiments on Ballooning in Zircaloy Fuel Rod Claddings in the Low Pressure Phase of a Loss-of-Coolant Accident
,” presented at
Specialist Meeting on the Behavior of Water Reactor Fuel Elements under Accident Conditions
,
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,
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,
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,
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,
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, and
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K.
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Studies on Zircaloy Fuel Clad Ballooning in a Loss-of-Coolant Accident—Results of Burst Tests with Indirectly Heated Fuel Rod Simulators
,” in
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, ASTM STP 681,
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,
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,
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Burst Criterion of Zircaloy Fuel Claddings in a Loss-of-Coolant Accident
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,
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,
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, pp. 271-283.
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Neitzel
,
H. J.
and
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,
H. E.
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,” KfK 2893, AECL-6420,
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Kawasaki
,
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, “
Multirod Burst Tests under Loss-of-Coolant Conditions
,” presented at
OECD-NEACSN/IAEWA-Specialists' Meeting on Water Reactor Fuel Safety and Fission Product Release in Off-Normal and Accident Conditions
,
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,
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,
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Effect of Bundle Size on Cladding Deformation in LOCA Simulation Tests
,” in
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, ASTM STP 824,
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,
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, pp. 693-708.
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,
G.
and
Ortlieb
,
E.
, “
Parameteruntersuchungen über die Beeinflussung der Hüllrohre durch Nachbarstäbe beim Kühlmittelverlust-störfall
,”
Abschlußbericht Förderungsvorhaben
 BMFT RS 185 A, KWU Bericht R 914/022/80,
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Adroguer
,
B.
,
Hueber
,
C.
, and
Trotabas
,
M.
, “
Behavior of PWR Fuel in LOCA Conditions, PHEBUS Test 215 P
,” presented at
OECD-NEA-CSNI/IAEA Specialists' Meeting on Water Reactor Fuel Safety and Fission Product Release in Off-Normal and Accident Conditions
,
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,
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,
C. L.
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LOCA Simulation in the National Research Universal Reactor Program: Third Materials Experiment (MT-3)
,” NUREG/CR-2528, PNL-4166,
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,
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Influence of a Cold Control Rod Guide Thimble on the Ballooning Behavior of Zircaloy Claddings in a LOCA
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Adachi
,
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,” NUREG/CP-0041, Vol.
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