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ASTM Selected Technical Papers
Composite Materials: Testing and Design (6th Conference)
By
IM Daniel
IM Daniel
1
Professor and Director
,
Experimental Stress Analysis Laboratory, Illinois Institute of Technology
,
Chicago,
Illinois
;
symposium chairman and editor
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ISBN-10:
0-8031-0695-5
ISBN:
978-0-8031-0695-6
No. of Pages:
597
Publisher:
ASTM International
Publication date:
1982

An experimental investigation was conducted to evaluate the effect of the matrix resin on the impact damage tolerance of graphite-epoxy composite laminates. The materials were evaluated on the basis of the damage incurred due to local impact and on their ability to retain compression strength in the presence of impact damage. Twenty-four different resin systems supplied by seven manufacturers in prepreg tape form were evaluated. Materials were not competitively submitted for the purpose of selecting a best material, but were voluntarily provided to study what improvements in damage tolerance the various resin improvements might make. Most of the materials tested had a smaller interior damage region, as determined by C-scan inspection, and less damage on the specimen surface than a baseline control resin which is widely used and whose damage tolerance characteristics have been documented. Five of the systems demonstrated substantial improvements compared with the baseline system, including retention of compression strength in the presence of impact damage. Examination of the neat resin mechanical properties indicates the resin tensile properties influence significantly the laminate damage tolerance, and that improvements in laminate damage tolerance are not necessarily made at the expense of room-temperature mechanical properties. Preliminary results indicate that a resin volume fraction on the order of 40 percent or greater may be required to permit the plastic flow between fibers necessary for improved damage tolerance. Test techniques for evaluating damage tolerance are discussed, including a newly developed multi-span beam shear test for which test results correlate well with damage tolerance trends from impact tests.

1.
Rhodes
,
M. D.
,
Williams
,
J. G.
, and
Starnes
,
J. H.
, “
Effect of Low-Velocity Impact Damage on the Compressive Strength of Graphite-Epoxy Hat-Stiffened Panels
,” NASA TN D-8411,
1977
.
2.
Starnes
,
J. H.
, Jr.
,
Rhodes
,
M. D.
, and
Williams
,
J. G.
in
Nondestructive Evaluation and Flaw Criticality for Composite Materials
, ASTM STP 696,
American Society for Testing and Materials
,
1979
, pp. 145-171.
3.
McGarry
,
F. J.
and
Willner
,
A.
, “
Toughening of an Epoxy Resin by an Elastomeric Second Phase
,” R68-6,
Massachusetts Institute of Technology
,
Cambridge
,
03
1969
.
4.
Rowe
,
E. H.
, “
Fractography of Thermoset Resins Toughened with Hycar CTBN
,”
26th Annual Technical Conference Reinforced Plastics/Composites Division
,
The Society of the Plastics Industry
,
1971
, Section 12-E, pp. 1-7.
5.
Perry
,
J. L.
,
Kirkhart
,
J. L.
, and
Adams
,
D. F.
, “
Third Phase Fiber Addition to Advanced Graphite Composites for Improvement of Impact Strength
,” Final Report Navy Contract N00019-73-0389,
Philco-Ford Corporation
,
03
1974
.
6.
Allred
,
R. E.
,
Street
,
H. K.
, and
Martinez
,
R. J.
, “
Improvement of Transverse Composite Strength-Test Specimens and Materials Development
,”
SAMPE 24th National Symposium
,
1979
, pp. 31-50.
7.
Furney
,
M. F.
, “
Rubber-Modified, Low-Density Encapsulant
,”
SAMPE Materials Review '75, Proceedings of 7th National Technical Conference
,
Albuquerque, N.M.
, 14–16 Oct. 1975, pp. 386-394.
8.
Byers
,
B. A.
, “
Behavior of Damaged Graphite-Epoxy Laminates under Compression Loading
,” NASA CR 159293,
08
1980
.
9.
Palmer
,
R. J.
, “
Investigation of the Effect of Resin Material on Impact Damage Due to Graphite-Expoxy Composites
,” NASA CR 165677,
03
1981
.
10.
Williams
,
J. G.
,
Anderson
,
M. S.
,
Rhodes
,
M. D.
,
Starnes
,
J. H.
, Jr.
, and
Stroud
,
W. J.
, “
Recent Developments in the Design, Testing, and Impact-Damage Tolerance of Stiffened Composite Panels
,”
Fibrous Composites in Structural Design (Proceedings of Fourth Conference on Fibrous Composites in Structural Design)
,
Plenum Press
,
New York
,
1980
, pp. 259-291.
11.
Greszczuk
,
L. B.
, “
Microbuckling Failure of Circular Fiber Reinforced Composites
,”
AIAA/ASME/SAE 15th Structures, Structural Dynamics and Materials Conference
, AIAA Paper 74-354, 17–19 April 1974.
12.
Rhodes
,
M. D.
,
Williams
,
J. G.
, and
Starnes
,
J. H.
, Jr.
, “
Low-Velocity Impact Damage In Graphite-Fiber Reinforced Epoxy Laminates
,” paper presented at
34th Annual Conference Reinforced Plastic/Composite Institute
,
The Society of the Plastics Industry
,
New Orleans
, 29 Jan. to 2 Feb. 1979.
13.
Hertzberg
,
P. E.
,
Smith
,
B. W.
, and
Miller
,
A. G.
, “
Effect of Matrix Resin on the Impact Fracture Characteristics of Graphite-Epoxy Laminates
,” NASA CR-165784,
1981
.
14.
Miller
,
A. G.
,
Hertzberg
,
P. E.
, and
Rantala
,
V. W.
,
SAMPE Quarterly
 0036-0821, Vol.
12
, No.
2
,
01
1981
, pp. 36-42.
15.
Bascom
,
W. D.
,
Bitner
,
J. L.
,
Moulton
R. J.
, and
Siebert
,
A. R.
,
Composites
 0010-4361, Vol.
11
, No.
1
,
01
1980
, pp. 9-18.
16.
Rhodes
,
M. D.
, “
Damage Tolerance Research on Composite Compression Panels
,” NASA Conference Publication 2142,
1980
, pp. 107-142.
17.
Rhodes
,
M. D.
and
Williams
,
J. G.
, “
Concepts for Improving the Damage Tolerance of Composite Compression Panels
,” paper presented at
5th DOD/NASA Conference on Fibrous Composites In Structural Design
,
New Orleans
, 27–29 Jan. 1981.
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