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ASTM Selected Technical Papers
Adhesion Measurement of Thin Films, Thick Films, and Bulk Coatings
By
KL Mittal
KL Mittal
1
East Fishkill Facility, IBM Corporation
,
Hopewell Junction, N.Y. 12533
;
symposium chairman and editor
.
Search for other works by this author on:
ISBN-10:
0-8031-0272-0
ISBN:
978-0-8031-0272-9
No. of Pages:
412
Publisher:
ASTM International
Publication date:
1978

In this paper, the term “basic adhesion” is used to signify the summation of all interfacial intermolecular interactions, whereas the term “practical adhesion” is used to represent the forces or the work required for the disruption—either at the interface or in the interfacial region—of the adhering system. There are many factors which influence practical adhesion, and these are discussed in detail. The relationship between practical adhesion and basic adhesion is discussed. Basic adhesion cannot be determined by the commonly used techniques for measuring practical adhesion. The virtues of an ideal practical adhesion test are outlined. Some of the techniques for adhesion measurement of thin films, thick films, and coatings are discussed briefly, and references are made to the recent reviews on this topic.

For a given adhering system, different techniques yield different practical adhesion values. The difficulties involved in adhesion measurement are highlighted, and the unresolved problems are brought into sharper focus.

The failure surfaces should be examined using surface analytical tools to ascertain the locus of failure, which is important in understanding the mechanism of failure.

1.
Mittal
,
K. L.
,
Journal of Adhesion
 0021-8464, Vol.
7
,
1974
. p. 377–378.
2.
Bikerman
,
J. J.
,
The Science of Adhesive Joints
, 2nd edition,
Academic Press
,
New York
,
1968
.
3.
Nenadovic
,
T.
,
Bibic
,
N.
,
Kraljevic
,
N.
, and
Adamov
,
M.
,
Thin Solid Films
 0040-6090, Vol.
34
,
1976
, pp. 211–214.
4.
Lee
,
L. H.
, Ed.,
Recent Advances in Adhesion
,
Gordon and Breach
,
New York
,
1973
.
5.
Lee
,
L. H.
, Ed.,
Adhesion Science and Technology
, Vols.
9A
and
9B
,
Plenum Press
,
New York
,
1975
.
6.
Proceedings of Recent Conferences on Adhesion and Adhesives held in London,
England
. These are chronicled in the series
Aspects of Adhesion
,
Alner
D. J.
, Ed.,
CRC Press
,
Cleveland, Ohio
.
7.
Good
,
R. J.
,
Journal of Adhesion
 0021-8464, Vol.
8
,
1976
, pp. 1–9.
8.
Allen
,
K. W.
in
Aspects of Adhesion
,
Alner
D. J.
, Ed., Vol.
5
,
CRC Press
,
Cleveland, Ohio
,
1969
, pp. 11–24.
9.
Raevskii
,
R. J.
,
Journal of Adhesion
 0021-8464, Vol.
5
,
1973
, pp. 203–210.
10.
Mittal
,
K. L.
,
Journal of Vacuum Science and Technology
 0022-5355, Vol.
13
,
1976
, pp. 19–25.
11.
Mittal
,
K. L.
in
Adhesion Science and Technology
,
Lee
L. H.
, Ed.,
Plenum Press
,
New York
,
1975
, Vol.
9A
, pp. 129–168.
12.
Mittal
,
K. L.
,
Polymer Engineering and Science
 0032-3888, Vol.
17
,
1977
, pp. 467–473.
13.
Huntsberger
,
J. R.
in “
Treatise on Adhesion and Adhesive
,”
Patrick
R. L.
, Ed.,
Marcel Dekker
,
New York
,
1967
, Vol.
1
, pp. 119–149.
14.
Sharpe
,
L. H.
,
Journal of Adhesion
 0021-8464, Vol.
4
,
1972
, pp. 51–64.
15.
Chapman
,
B. N.
,
Journal of Vacuum Science and Technology
 0022-5355, Vol.
11
,
1974
, pp. 106–115.
16.
Mattox
,
D. M.
, this publication, 54–62.
17.
Bikerman
,
J. J.
,
Industrial and Engineering Chemistry
 0888-5885, Vol.
59
, No.
9
,
1967
, pp. 40–44.
18.
Bikerman
,
J. J.
,
Journal of Paint Technology
, Vol.
43
,
1971
, pp. 98ff.
19.
Crocker
,
G. J.
,
Rubber Chemistry and Technology
 0035-9475, Vol.
42
,
1968
, pp. 30–70.
20.
Bikerman
,
J. J.
, this publication, pp. 30–40.
21.
Good
,
R. J.
,
Journal of Adhesion
 0021-8464, Vol.
4
,
1972
, pp. 133–154.
22.
Good
,
R. J.
, this publication, pp. 18–29.
23.
Baun
,
W. L.
,
Journal of Adhesion
 0021-8464, Vol.
7
,
1976
, pp. 261–267.
24.
Wyatt
,
D. M.
,
Gray
,
R. C.
,
Carver
,
J. C.
,
Hercules
,
D. M.
, and
Masters
,
L. W.
,
Applied Spectroscopy
 0003-7028, Vol.
28
, No.
5
,
1974
, pp. 439–444.
25.
Murr
,
L. E.
, this publication, pp. 82–98.
26.
Campbell
,
D. S.
in
Handbook of Thin Film Technology
,
Maissel
L. I.
and
Glang
R.
, Eds.,
McGraw-Hill
,
New York
,
1970
, Chapter 12, pp. 12-3–12-47.
27.
Taylor
,
D.
, Jr.
, and
Rutzler
,
J. E.
, Jr.
,
Industrial and Engineering Chemistry
 0888-5885, Vol.
50
,
1958
, pp. 928–934.
28.
Mittal
,
K. L.
,
Electrocomponent Science and Technology
 0305-3091, Vol.
3
,
1976
, pp. 21–42.
29.
Mittal
,
K. L.
in
Properties of Electrodeposits: Their Measurement and Significance
,
Sard
R.
,
Leidheiser
,
H.
 Jr.
, and
Ogburn
F.
, Eds.,
The Electrochemical Society Princeton
,
N.J.
,
1975
, Chapter 17, pp. 273–306.
30.
Jacobsson
,
R.
,
Thin Solid Films
 0040-6090, Vol.
34
,
1976
, pp. 191–199.
31.
Goldstein
,
L. F.
and
Bertone
,
T. J.
,
Journal of Vacuum Science and Technology
 0022-5355, Vol.
12
,
1975
, pp. 1423–1426.
32.
Ahn
,
J.
,
Mittal
,
K. L.
, and
MacQueen
,
R.
, this publication, pp. 134–157.
33.
Stephens
,
A. W.
and
Vossen
,
J. L.
,
Journal of Vacuum Science and Technology
 0022-5355, Vol.
13
,
1976
, pp. 38–39.
34.
Vossen
,
J. L.
, this publication, pp. 122–133.
35.
Krongelb
,
S.
, this publication, pp. 107–121.
36.
Hitch
,
T. T.
and
Bube
,
K. R.
, “
Basic Adhesion Mechanisms in Thick and Thin Films
,” Report from
RCA Laboratories
, Princeton, N. J.,
31
01
1975
.
37.
Jacobson
,
L.
,
Proceedings
, IEEE and EIA Electronic Components Conference,
1971
, pp. 474–479.
38.
Anjard
,
R. P.
,
Microelectronics and Reliability
 0026-2714, Vol.
10
, No.
4
,
1971
, pp. 269–275.
39.
Hitch
,
T. T.
, this publication, pp. 211–232.
40.
Dini
,
J. W.
and
Johnson
,
H. R.
,
Metal Finishing
 0026-0576,
03
1977
, pp. 42–46;
04
1977
, pp. 48–51.
41.
Dini
,
J. W.
and
Johnson
,
H. R.
, this publication, pp. 305–326.
42.
Bullett
,
T. R.
and
Prosser
,
J. L.
,
Progress in Organic Coatings
 0300-9440, Vol.
1
,
1972
, pp. 45–73.
43.
Lewis
,
A. F.
and
Forrestal
,
L. J.
in
Treatise on Coatings
,
Myers
R. R.
and
Long
J. S.
, Eds.,
Marcel Dekker
,
New York
,
1969
, Vol.
2
, Part 1, pp. 57–98.
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