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ASTM Selected Technical Papers
Water Quality Parameters
By
S Barabas
S Barabas
1
Head
, Analytical Methods Research Section,
Canada Centre for Inland Waters
,
Burlington, Ontario,
Canada
, general chairman
Search for other works by this author on:
ISBN-10:
0-8031-5526-3
ISBN:
978-0-8031-5526-8
No. of Pages:
590
Publisher:
ASTM International
Publication date:
1975

Mixtures of species may be analyzed by a method where differing rates of reaction with a common reagent serve to differentiate components. The rate constants are usefully regarded as the reciprocals of frequencies and the method may be called “kinetic spectrometry.” Literature on the stopped flow technique reports analyses of mixtures of metal ions and of mixtures of amino-polycarboxylates using convenient instrumentation. The prospects for automated direct analyses of metal complex species present in natural waters are discussed.

1.
Yatsimirskii
,
K. B.
,
Kinetic Methods of Analysis
,
Pergamon
,
Oxford
,
1966
.
2.
Mark
,
H. B.
and
Reichnitz
,
G. A.
,
Kinetics in Analytical Chemistry
,
Wiley (Interscience)
,
New York
,
1968
.
3.
Caldin
,
E. F.
,
Fast Reactions in Solution
,
Wiley
,
New York
,
1964
.
4.
Langford
,
C. H.
,
Inorganic and Nuclear Chemistry Letters
 0020-1650, Vol.
9
,
1973
, p. 679.
5.
Eigen
,
M.
,
Zeitschrift Fur Elektrochemie
, Vol.
64
,
1960
, p. 115.
6.
Margerum
,
D. W.
,
Pausch
,
J. B.
,
Nyssen
,
G. A.
, and
Smith
,
G. F.
,
Analytical Chemistry
 0003-2700, Vol.
41
,
1969
, p. 233.
7.
Coombs
,
L. C.
,
Vasiliades
,
J.
, and
Margerum
,
D. W.
,
Analytical Chemistry
 0003-2700, Vol.
44
,
1972
, p. 2325.
8.
Wills
,
G.
,
Woodruff
,
W. H.
,
Frysinger
,
J. R.
,
Margerum
,
D. W.
, and
Pardue
,
H. L.
,
Analytical Chemistry
 0003-2700, Vol.
42
,
1970
, p. 1350.
9.
Javier
,
A. C.
,
Crouch
,
S. R.
, and
Malmstadt
,
H. V.
,
Analytical Chemistry
 0003-2700, Vol.
41
,
1969
, p. 239.
10.
Langford
,
C. H.
and
Sastri
,
V. S.
,
Biennial Reviews of Chemistry, Inorganic Chemistry, Series One
, Vol.
9
, Chapter 6,
MTP—Butterworths
,
London
,
1972
.
11.
Durrum Instrument Co.
, Palo Alto, Calif.
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