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ASTM Selected Technical Papers
Hydrocarbon Analysis
By
H. M. Smith
H. M. Smith
1
U. S. Bureau of Mines
,
Bartlesville, Okla. Chairman
, ASTM Committe D-2 on Petroleum Products and Lubricants
Search for other works by this author on:
ISBN-10:
0-8031-6620-6
ISBN:
978-0-8031-6620-2
No. of Pages:
426
Publisher:
ASTM International
Publication date:
1965

The title of this talk “The Basis For Future Developments of Hydrocarbon Analysis”, is a large order. It ia true that future work is always based on what has gone before, on what is currently known. It is also true that ideas and techniques currently unrelated to the petroleum industry may suddenly emerge as of primary importance in hydrocarbon analysis, because of the development of some previously unheard of analytical technique. In this paper, I will try to cover the development of hydrocarbon analysis up to the present time, and to do just a little speculating about the future. No matter how well this is done, I am sure that a few years hence some new factors will become important in hydrocarbon analysis, which we cannot now foresee. Hydrocarbon analysis seems to be that sort of a subject. The course of events is far from predictable, but this does not mean that a good knowledge of the background does not have real value. We believe that it has. In approaching this large order of historical material, I believe that the best feel for the forward march of events in hydrocarbon analysis can be achieved by considering periods. This means considering the advances in the petroleum industry broadly, since the analytical needs and demands changed and multiplied as the industry developed. I am not aware of any historical treatment of this subject in the literature, and therefore have undertaken to write a text for publication which, if I read it today, would keep me talking for several hours. I am supposed to wind up this talk in about 25 to 30 minutes, therefore I can only give you today a small part of what I am preparing for publication. In selecting items to present from the wealth of material available, I have tried to pick out what will be interesting, even though historically other items may be more important. Today, I hope to give you some feeling for the broad picture of analytical progress in our field over the last 110 years. I regret that the limitation of time will not permit a more precise historical balance than is possible in such a brief presentation.

1.
Silliman
,
Benjamin
 Jr.
,
Report on the Rock Oil, or Petroleum from Venango County
, Pennsylvania (With special reference to its use for illumination and other purposes) Dated 4/10/1855.
2.
Silliman
,
Benjamin
 Jr.
, Report on Rock Oil, Etc. “American Chemist, Vol.
2
, p. 18,
1871
.
3.
Rossini
F. D.
,
An Excursion in Petroleum Chemistry
, Marburg Lecture,
ASTM
, June, 1953,
ASTM Proceedings
, Vol.
53
, 545,
1953
.
4.
Mabery
C. F.
,
Composition of American Petroleum
,
Journal of American Chemical Society
 0002-7863, Vol.
28
, p. 415–430,
1906
.
5.
Gurwitsch
L.
and
Moore
H.
, “
The Scientific Principles of Petroleum Technology
,
Chapman Hall
, London,
1926
.
6.
Mendeleeff
D.
Ref , p. 7 and 8.
Mendeleeff
D.
,
Application of a New Fractionation Method to the Investigation of Petroleum from Baku
,
Journal of Russian Physical Chemical Society
 0372-9877, p. 189,
1883
7.
Markownikoff
W.
Ref , p. 20–23
Markownikoff
W.
,
Concerning the Field of Cyclic Compounds (Methylcyclopentane)
,
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 0170-2041 Vol.
307
, p. 335–6, especially p. 344,
1899
.
8.
Mabery
C. F.
and
Smith
A. W.
, The Sulfur Compounds in Crude Petroleum and in Petroleum Residues Berichte, Vol.
22
, 3303 (
1889
).
9.
Mabery
C. F.
,
Composition of Texas Petroleum
,
Journal of American Chemical Society
 0002-7863, Vol.
23
, p. 264–267 (
1901
).
10.
Mabery
C. F.
and
Goldstein
A. H.
,
On the Specific Heats and Heat of Vaporization of the Paraffin and Methylene Hydrocarbons
.
Journal of American Chemical Society
 0002-7863, Vol.
24
, R 443,
1902
Mabery
C. F.
and
Goldstein
A. H.
,
On the Specific Heats and Heat of Vaporization of the Paraffin and Methylene Hydrocarbons
.
American Chemical Journal
28
, 66–78,
1902
11.
Reid
E. C.
and
Sherwood
T. K.
,
Properties of Liquids and Gases
, p. 160,
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, New York,
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.
12.
Johnson
A.
and
Huang
C. J.
, p. 160 of Ref
13.
Gruse
W. A.
and
Stevens
D. R.
,
Chemical Technology of Petroleum
,
McGraw Hill
, New York,
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.
14.
Mair
B. J.
,
Composition of Petroleum and Petroleum Products
, Chapter II of Ref .
15.
De LaRue
Warren A.
and
Müller
Hugo
,
Chemical Examination of Burmese Naphtha or Rangoon Tar
, Page 39, Ref
De LaRue
Warren A.
and
Müller
Hugo
,
Chemical Examination of Burmese Naphtha or Rangoon Tar
,
Proceedings Royal Society of London
 0370-1662, Vol.
18
, p. 221–228,
1857
16.
Redwood
S. Boverton
, “
Petroleum and Its Products
,”
Griffin
, London,
1913
. Also Griffin, London,
1922
.
17.
Engler
C.
and
Hofer
H.
, “
Das Erdol
,”
Hirzel
, Leipzig,
1913
.
18.
Bacon
R. F.
and
Hamor
W. A.
, “
The American Petroleum Industry
,”
McGraw-Hill
, New York,
1916
.
19.
Hamor
W. A.
and
Padgett
W. F.
,
The Technical Examination of Petroleum
,
McGraw-Hill
, New York,
1920
.
20.
Day
D. T.
, Editor,
Handbook of Petroleum Chemistry
,
Wiley
, New York,
1922
.
21.
Brooks
B. T.
, “
The Chemistry of Non-Benzenoid Hydrocarbons
”,
Chemical Catalogue Company
, New York, New York,
1922
.
22.
Bell
H. S.
,
American Petroleum Refining
,
Van Nostrand
, New York,
1923
.
23.
Washburn
E. W.
, Vol
II
International Critical Tables
,
McGraw-Hill
, New York,
1927
.
24.
Page 122, Ref .
25.
Garfield
J. R.
, “
Plans for International Standards for Testing Mineral Oil Products
,” Senate Document 469, 60th Congress, 1st Session,
1908
.
26.
Rittman
W. F.
and
Dean
E. W.
,
Analytical Distillation of Petroleum
,
Industrial and Engineering Chemistry
 0019-7866, Vol.
7
, p. 185–195,
1915
.
27.
Rittman
W. F.
and
Dean
E. W.
,
Analytical Distillation of Petroleum II
,
Industrial and Engineering Chemistry
 0019-7866, Vol.
7
, p. 754–760,
1915
.
28.
Rittman
W. F.
and
Dean
E. W.
,
Analytical Distillation of Petroleum
, Bureau of Mines Bulletin 125, Washington D. C.,
1916
.
29.
Dean
E. W.
,
Hill
H. H.
,
Smith
N. A. C.
and
Jacob
W. A.
,
Analytical Distillation of Petroleum
, Bureau of Mines Bulletin 207, Washington, D. C.,
1922
.
30.
Smith
H. M.
and
Ball
J. S.
,
Crude Oil Characterization by Bureau of Mines Routine Method
,
Petroleum Engineer
, Vol.
26
, No.
6
, p. C12–C14, June, 1954.
31.
Kraemer
A. J.
and
Smith
H. M.
, Bureau of Mines Report 2595, “
Properties of Typical Crude Oils from the Producing Fields of California
,” Washington, D.C.
1924
.
32.
Brooks
B. T.
,
A Statistical Review of the Question of Gasoline Supply
,
Industrial and Engineering Chemistry
 0019-7866, Vol.
7
, p. 176–179, (
1915
).
33.
Brooks
B. T.
,
Bacon
R. F.
,
Padgett
F. W.
and
Humphrey
I. W.
,
Preparation of Gasoline and Kerosine from Heavier Hydrocarbons
,
Industrial and Engineering Chemistry
 0019-7866, Vol.
7
, p. 180–185,
1915
.
34.
Hill
H. H.
and
Dean
E. W.
,
Quality of Gasoline Marketed in the United States
, Bureau of Mines Bulletin 191,
1920
.
35.
Dean
E. W.
and
Hill
H. H.
, “
Determination of Unsaturated Hydrocarbons in Gasoline
,” Bureau of Mines Technical Paper 181,
1919
.
36.
Golodetz
A.
Page 9, Ref
Golodetz
A.
,
New Methods of Separating Liquids having boiling points near each other or forming mixtures of constant Boiling Point
,
Journal of Russian Physical Chemical Society
 0372-9877 
43
, 1041,
1911
.
37.
Page 290–294, Ref.
38.
Thole
F. B.
,
Estimation of Benzene and Toluene in Petroleum
,
Journal Society of Chemical Industry
 0368-4075, Vol.
38
, p. 39T,
1919
.
39.
Tizard
H. T.
and
Marshall
A. G.
, “
The Determination of Aromatic Hydrocarbons in Mixtures of Hydrocarbons
,”
Journal Society of Chemical Industry
 0368-4075, Vol.
40
, p. 20T,
1921
.
40.
Ormandy
W. R.
and
Cravin
E. C.
,
The Determination of Unsaturates in Petroleum Spirits
,
Journal of Institute of Petroleum
 0020-3068, Vol.
11
, p. 533,
1925
.
41.
Ormandy
W. R.
and
Cravin
E. C.
, “
The Action of Sulfuric Acid on Unsaturated and Aromatic Hydrocarbons
,”
Journal of Institute of Petroleum
 0020-3068, Vol.
13
, p. 311,
1927
.
42.
Johansen
E. M.
, “
Iodine and Bromine Values of Petroleum Products
,”
Industrial and Engineering Chemistry
 0019-7866, Vol.
14
, p. 288,
1922
.
43.
Mabery
C. F.
, “
Saturation” of Petroleum Lubricant Hydrocarbons as shown by their reaction with Bromine
Journal of American Chemical Society
 0002-7863, Vol.
48
, 2663
1926
.
44.
Francis
A. W.
, “
Estimation of Unsaturated Content of Petroleum Products
,”
Industrial and Engineering Chemistry
 0019-7866, Vol.
18
, p. 821,
1926
.
45.
Hill
J. B.
,
Motor Fuels
,
Industrial and Engineering Chemistry
 0019-7866, Vol.
19
, p. 1114,
1927
.
46.
Hill
J. B.
,
Henderson
L. M.
and
Ferris
S. W.
, “
The Composition of Gasoline as Indicated by Close Fractionation
,”
Industrial and Engineering Chemistry
 0019-7866, Vol.
19
, p. 128,
1927
.
47.
Brooks
B. T.
and
Humphrey
I. W.
, “
The Presence of Benzene Homologous in the High Boiling Distillates of Petroleum
,”
Journal of American Chemical Society
 0002-7863, Vol.
38
, p. 393–400,
1916
.
48.
Mabery
C. F.
and
Mathews
J. Howard
,
Viscosity and Lubrication
,
Journal of American Chemical Society
 0002-7863, Vol.
30
, p. 992–1001,
1908
.
49.
Mabery
C. F.
, “
The Lubricant and Asphaltic Hydrocarbons in Petroleum
,”
Industrial and Engineering Chemistry
 0019-7866, Vol.
15
, p. 1233,
1923
.
50.
Mabery
C. F.
, “
The Composition of Midcontinent Petroleum
,”
Industrial and Engineering Chemistry
 0019-7866, Vol.
18
, p. 814,
1926
.
51.
Mabery
C. F.
, “
A Study of Petroleum Lubricants
,”
Industrial and Engineering Chemistry
 0019-7866, Vol.
19
, p. 526,
1927
.
52.
Hill
J. B.
and
Ferris
S. W.
, “
The Relation Between Boiling Point and Some Other Properties of Petroleum Products
,”
Industrial and Engineering Chemistry
 0019-7866,
17
, 1250,
1925
.
53.
American Petroleum Institute Bulletin
, Vol.
VIII
, 5,
21
09
1927
.
54.
Gruse
W. A.
,
Petroleum and Its Products
,
McGraw-Hill
New York,
1928
.
55.
Dunstan
A. E.
,
Nash
W. A.
,
Brooks
B. T.
and
Tizard
H. T.
,
Science of Petroleum
,
Oxford Press
,
1938
.
56.
Ward
A. L.
and
Kurtz
,
S. S.
 Jr.
, “
Refraction, Dispersion and Related Properties of Pure Hydrocarbons (Arranged for use in the Analysis of Hydrocarbon Mixtures)
,”
Analytical Chemistry
 0003-2700, Vol.
10
, p. 559–576,
1938
.
57.
Doss
M. P.
,
Physical Constants of the Principal Hydrocarbons
,
Texas Company
, New York,
1939
.
58.
Egloff
G.
,
Physical Constants of Hydrocarbons
,
Reinhold
, New York, Vol.
1
,
1939
.
59.
Hill
J. B.
,
25 Years of API Research Project 6
, Proceedings of American Petroleum Institute, Vol.
32
, Section I, p. 183–189,
1952
.
60.
Rossini
F. D.
,
Mair
B. J.
and
Streiff
A. J.
Hydrocarbons from Petroleum
,”
Reinhold Publishing Corporation
, New York,
1953
.
61.
Rossini
F. D.
,
A Decade of Research on the Chemical Constitution of Petroleum
, American Petroleum Institute Proceedings, Vol.
18
, Section III, p. 36–61,
1937
.
62.
Mair
B. J.
and
White
J. D.
, “
The Separation of Petroleum Hydrocarbnns with Silica Gel
,”
Journal of Research, National Bureau of Standards
 0160-1741, Vol.
15
, p. 557,
1935
.
63.
Liddell
U.
and
Kasper
C.
, “
Spectral Determination of Pure Hydrocarbons, A Near Infrared Study
,”
Journal of Research, Bureau of Standards
 0160-1741, Vol.
10
, p. 599–618,
1933
.
64.
Liddel
U.
and
Wolf
O. R.
,
Character of the Absorption of some Amines in the Near Infrared
,
Journal of American Chemical Society
 0002-7863, Vol.
55
, 3574,
1933
.
65.
Rose
,
F. W.
 Jr.
,
Infrared Absorption of Nineteen Hydrocarbons Including Ten of High Molecular Weight
,
Journal of Research, National Bureau of Standards
 0160-1741, Vol.
19
, p. 143–161,
1937
.
66.
Rose
,
F. W.
 Jr.
,
Quantitative Analysis with Respect to the Component Structural Groups, of the Infrared (1 to 2 μ) molar absorptive indices of 55 Hydrocarbons
,
Journal of Research, National Bureau of Standards
 0160-1741,
20
, 129–157,
1938
.
67.
Podbielniak
W. J.
, “
Apparatus and Methods for Precise Fractional Distillation Analysis (New Method of Gas Analysis)
,”
Analytical Chemistry
 0003-2700, Vol.
3
, p. 177–178,
1931
.
68.
Podbielniak
W. J.
,
Apparatus and Methods for Precise Fractional Distillation Analysis, Part II Laboratory Columns for Precise and Rapid Fractionation of Gaseous Samples
,
Analytical Chemistry
 0003-2700, Vol
5
, p. 119–135,
1933
.
69.
Podbielniak
W. J.
,
Apparatus and Methods for Precise Fractional-Distillation Analysis Part IV Standardization of Low-temperature Fractionation-Analysis Apparatus and Method Using Automatic Recording and Control
,”
Analytical Chemistry
 0003-2700, Vol.
5
, p. 172–175,
1933
.
70.
Watson
K. M.
and
Ceaglske
N. H.
, “
Fuel-Gas Analysis for Heating Value and Combustion Calculations
,”
Analytical Chemistry
 0003-2700, Vol.
4
, p. 70–72,
1932
.
71.
Hurd
C. D.
and
Spence
L. U.
, “
The Pyrolysis of Hydrocarbons: Normal Butane and Isobutane
,”
Journal of American Chemical Society
 0002-7863, Vol.
51
, p. 3353,
1929
.
72.
Davis
H. S.
and
Daugherty
J. P.
,
Analysis of Hydrocarbon Gases
,
Analytical Chemistry
 0003-2700 
4
, p. 193–7,
1932
.
73.
Matuszak
M. P.
,
Sulfuric Acid Analysis of Gaseous Olefins
,
Analytical Chemistry
 0003-2700,
10
, 354–60,
1938
.
74.
Rosen
R.
and
Robertson
A. E.
,
Short Cut Method of Hydrocarbon Analysis
,
Analytical Chemistry
 0003-2700,
6
, 12,
1934
.
75.
Farragher
W. F.
,
Morrell
J. C.
and
Levine
I. M.
Determination of Olefin and Aromatic Hydrocarbons
,
Analytical Chemistry
 0003-2700,
2
, 18,
1930
.
76.
Howes
D. A.
, “
Chemical Examination of Gasolines and Light Mineral Oils
,”
Journal of Institute of Petroleum
 0020-3068, Vol.
16
, p. 54–85,
1930
.
77.
Fisher
C. H.
and
Eisner
A.
,
Graphic Analysis of Hydrocarbon Oils, Volume - Physical Constant Relationship Resulting From Successive Extractions With Sulfuric Acid
,
Analytical Chemistry
 0003-2700,
9
, 366–70,
1937
.
78.
Fisher
C. H.
and
Eisner
A.
,
Sulfuric Acid Extraction Methods For Determining Olefins and Aromatics in Hydrocarbon Oils Optimum Conditions and Concentrations of Acid
, U. S. Bureau of Mines Report of Investigations #3356,
1937
.
79.
Kurtz
,
S. S.
 Jr.
, and
Headington
C. E.
,
Analysis of Light Petroleum Fractions
,
Analytical Chemistry
 0003-2700, Vol.
9
, p. 21,
1937
.
80.
Ward
A. L.
and
Kurtz
,
S. S.
 Jr.
,
Refraction, Dispersion and Related Properties of Pure Hydrocarbons
,
Analytical Chemistry
 0003-2700, Vol.
10
, p. 559,
1938
.
81.
Thomas
C. L.
,
Bloch
H. S.
and
Hoekstra
James
, “
The Proximate Analysis of Gasoline
,”
Analytical Chemistry
 0003-2700, Vol.
10
, p. 559,
1938
.
82.
Ward
A. L.
and
Fulweiler
W. H.
,
Specific Refractive Dispersion as a Method for Distinguishing Between Different Series of Hydrocarbons
,
Analytical Chemistry
 0003-2700,
6
, 396–400,
1934
.
83.
Grosse
A. V.
and
Wacker
R. C.
, “
Quantitative Determination of Aromatic Hydrocarbons by New Method
Analytical Chemistry
 0003-2700,
11
, 614,
1939
.
84.
Anonymous,
PONA Analysis of Gasolines and Petroleum Fractions
, Method H-173-40 in Test Methods for Petroleum and Its Products,
Universal Oil Products Company
, Chicago,
1940
.
85.
Beard
L. C.
,
Shipp
V. L.
and
Spelshouse
W. E.
,
Standardization of Kauri Butanol Test for Paint and Lacquer Thinners
,
Analytical Chemistry
 0003-2700,
5
, 307,
1933
.
86.
Baldeschweiler
E. L.
,
Troeller
W. J.
and
Morgan
M. D.
The Kauri Butanol Test for Solvent Power
,
Analytical Chemistry
 0003-2700,
7
, 374,
1935
.
87.
Doolittle
A. K.
,
Strength of Nitrocellulose Solvents-Comparative Toluene Dilution Ratios
,
Industrial and Engineering Chemistry
 0019-7866, Vol.
30
, p. 189–203,
1938
.
88.
Kurtz
,
S. S.
 Jr.
,
Harvey
W. T.
and
Lipkin
M. R.
,
The Solvency of Petroleum Spirits-Resin Solvency of Commercial Spirits
,
Analytical Chemistry
 0003-2700,
11
, 476–483,
1939
.
89.
Anonymous, “
Report of Philadelphia Paint and Varnish Production Club on Thinning of Varnish with Mineral Spirits
”. Pages 7–19 of “Papers Presented at 1941 Convention in Chicago,” published as special issue of
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,
121 South Broad Street, Philadelphia, Pa.
90.
Kurtz
,
S. S.
 Jr.
,
Sweely
J. S.
and
Stout
W. J.
Tables 2, 3 and 4 of Chapter 2 in “
Plasticizer Technology
” edited by
Bruins
P. F.
,
Reinhold
, New York,
1965
.
91.
Hill
J. B.
and
Coates
H. B.
, “
Viscosity Gravity Constant of Petroleum Lubricating Oils
,”
Industrial and Engineering Chemistry
 0019-7866, Vol.
20
, p. 641,
1928
.
92.
Dean
E. W.
,
Davis
G. H. B.
, et al
,
Viscosity Variations of Oils with Temperature
,
Chemical and Metallurgical Engineering
,
36
, 618,
1929
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93.
Bestuzhev
I. M.
, “
Concerning the Chemical Composition of Lubricating Oils
,”
Erdol und Teer
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7
, 159–61, 191–3,
1931
.
94.
Bestuzhev
I. M.
,
Chemical Abstracts
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25
, 3816,
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95.
Ward
A. L.
,
Kurtz
,
S. S.
 Jr.
and
Fulweiler
F. W.
, Page 2582, Vol.
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,
Waterman
H. I.
and
Van Westen
H. A.
,
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Journal Institute of Petroleum Technology
,
18
, 735–750
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Vlugter
J. C.
,
Waterman
H. I.
and
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H. A.
, “
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1935
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99.
Mair
B. J.
and
Willingham
C. B.
,
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,
National Bureau of Standards, Journal of Research
 0160-1741,
17
, p. 923–942,
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.
100.
Mair
B. J.
,
Willingham
C. B.
and
Streiff
A. J.
Chemical Constitution of the “EXTRACT” Portion of the Lubricant Fraction from a Midcontinent Petroleum
,
Journal of Research, National Bureau of Standards
 0160-1741,
21
, p. 581–607,
1938
.
101.
Mikeska
L. A.
,
Chemical Structure of Lubricating Oil
,
Industrial and Engineering Chemistry
 0019-7866,
28
, 970–983,
1936
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Kurtz
,
S. S.
 Jr.
, and
Ward
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