Metallurgy and Behavior of Alloys for Reformer Furnaces

This paper reviews the metallurgy and behavior of centrifugally cast heat-resistant alloys for ammonia, methanol, and hydrogen reformer furnaces. The alloys include HK and HP, as well as proprietary versions of these materials produced by various foundries. Alloying and metallurgical factors that affect resistance to oxidation, carburization, and high temperature creep are discussed. Examples of the effects of environment and temperature on material behavior are provided. Finally, the use of material properties to predict the long-term performance of reformer furnace components is reviewed.