In order to reduce the hotspots in partial oxidation of methane, CeO2 supported BaCoO3 perogvskite-type oxides were synthesized using a sol-gel method and applied in chemical-looping steam methane reforming (CL-SMR). The synthesized BaCoO3-CeO2 was characterized by X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). XRD and XPS results suggested that the obtained BaCoO3 was pure crystalline perovskite, its crystalline structure and lattice oxygen could regenerate after calcining. The reactivity of perovskite-type oxides in CL-SMR was evaluated using a fixed-bed reactor. Gas production rates and H2/CO ratios showed that the optimal reaction temperature was about 860 °C and the properly reaction time in fuel reactor was about 180s when Weight Hourly Space Velocity (WHSV) was 23.57 h−1. The syngas production in fuel reactor were 265.11 ml/g, hydrogen production in reforming reactor were 82.53 ml/g. (CSPE)
- Power Division
- Advanced Energy Systems Division
- Solar Energy Division
- Nuclear Engineering Division
Synthesis of CeO2 Supported BaCoO3 Perovskites for Chemical-Looping Methane Reforming to Syngas and Hydrogen
Ding, H, Xu, Y, Xiang, L, Wang, Q, Shen, C, Luo, C, & Zhang, L. "Synthesis of CeO2 Supported BaCoO3 Perovskites for Chemical-Looping Methane Reforming to Syngas and Hydrogen." Proceedings of the ASME 2017 Power Conference Joint With ICOPE-17 collocated with the ASME 2017 11th International Conference on Energy Sustainability, the ASME 2017 15th International Conference on Fuel Cell Science, Engineering and Technology, and the ASME 2017 Nuclear Forum. Volume 1: Boilers and Heat Recovery Steam Generator; Combustion Turbines; Energy Water Sustainability; Fuels, Combustion and Material Handling; Heat Exchangers, Condensers, Cooling Systems, and Balance-of-Plant. Charlotte, North Carolina, USA. June 26–30, 2017. V001T04A023. ASME. https://doi.org/10.1115/POWER-ICOPE2017-3246
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