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Corrosion protection
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Proceedings Papers
Proc. ASME. NAWTEC21, 2013 21st Annual North American Waste-to-Energy Conference, V001T03A001, April 21–25, 2013
Paper No: NAWTEC21-2703
Abstract
The prevention of corrosion on boiler tube-walls has been a most difficult and cost intensive problem in WTE plants. This is specifically the case where the incineration boilers are operating with increased saturated steam temperatures and their corresponding pressures. In addition, variations in the garbage mixtures, with differing values of chemical content and varying waste composition give importance to the prevention of boiler tube corrosion. Several refractory lining systems and types have been installed over the previous 80 years and can be compared. In the early stages it began with simple concrete installations and only later was it developed to use heat resistant ceramic products, now essentially silicon carbide. 20 years ago cement or chemically bonded SiC monolithics (gunning, trowelling or casting materials) were usually installed to protect boiler walls, but today fabricated and fired SiC tiles, with their enhanced properties, are mainly used. A distinction is made between hanging and bolted tiles, as well as between oxide bonded and nitride bonded SiC material and between mortared, backfilled and rear ventilated tiles. All these systems were carefully examined and assessed. It proved possible to develop a revolutionary heat conduction and corrosion protection system utilising air. An air gap between the refractory SiC tiles and the boiler wall proved to be both simple and successful. By means of detailed and systematic documentation and monitoring, including J + G’ s “Air” tiling system, it has, for a few years, been possible to offer and recommend long lasting refractory linings with the aim of protecting boiler walls against corrosion, reducing operating costs and using the energy of the waste in an optimum manner.
Proceedings Papers
Proc. ASME. NAWTEC20, 20th Annual North American Waste-to-Energy Conference, 237-242, April 23–25, 2012
Paper No: NAWTEC20-7035
Abstract
For the waste disposal of urban areas and major cities at the North American market place rather large scale energy from waste (EfW) plants are needed. This implies a mechanical input of approx. 40 Mg/h [39.36 tn l./h] and thermal input by waste per unit of 110 MW [375.3 MBTU/h] and more. There are basic design criteria that feature large scale EfW plants: - Layout of boiler with horizontal or vertical orientation of convective part. - Top or bottom suspension of boiler. - Flexible design of stoker regarding large throughput figures and heating values of waste with water or air cooled grate bars. - Design and geometry of combustion furnace in order to optimize the flow pattern. - Optimization of boiler steel structure: integrated steel structure for boiler and boiler house enclosure. - Optimization of corrosion protection and maintainability of large scale boilers: cladding versus refractory lining. - Maintenance aspects of the boiler. The paper gives information on the pros and cons regarding the design features with special focus on optimized solutions for large scale EfW plants. For the core component of the combustion system — the grate — Fisia Babcock Environment (FBE) is using forward moving grates as well as roller grates. The moving grate in STEINMÜLLER design, which is used in the great majority of all our plants, has specific characteristics for providing uniform combustion and optimal burnout. The automatic combustion rate control system is the key component in the combustion process in order to receive good burn out quality in slag and flue gas as well as constant steam production and oxygen content of flue gas. This paper includes a detailed report on a modern control system with focus on a simple and efficient control structure. Besides these measures regarding the combustion process, this paper also reports about the respective aspects and concepts for the flue gas cleaning systems. In this field the FBE CIRCUSORB ® process was presented in previous papers and is now compared with a multistage wet flue gas cleaning system. The latter is relevant in case of very low emission requirements.
Proceedings Papers
Proc. ASME. NAWTEC11, 11th Annual North American Waste-to-Energy Conference, 73-81, April 28–30, 2003
Paper No: NAWTEC11-1673
Abstract
The modern weld overlay applied by automatic gas-metal-arc welding (GMAW) process using Ni-Cr-Mo-Nb alloy 625 has been extremely successful in providing corrosion and erosion/corrosion protection for the waterwalls of waste-to-energy (WTE) boilers for over a decade. Without alloy 625 weld overlay protection, the carbon steel waterwall of a waste-to-energy boiler would be corroded through in a matter of months. The overlaid waterwalls for numerous WTE boilers have shown excellent performance results with services up to 10 years or more. Welding Services Inc. has developed a patented process for manufacturing weld overlay bimetallic tubes involving GMAW/GTAW process. Unifuse® 625 overlay tubing with carbon steel substrate has been successfully used as screen tubes, superheater tubes and generating banks in the convection section. The overlay tubes have successfully replaced such corrosion protection methods as stainless steel tube shields and refractories.
Proceedings Papers
Proc. ASME. NAWTEC12, 12th Annual North American Waste-to-Energy Conference, 111-119, May 17–19, 2004
Paper No: NAWTEC12-2216
Abstract
Corrosive conditions in waste to energy boilers produce rapid wastage rates of traditional boiler tube materials. It is not unusual to see corrosion rates in the range of 1 to 3 mm/y (40–120 mpy) on carbon steel boiler tubes and occasionally corrosion occurs at even higher rates. In the mid1980’s there were several boilers that experienced corrosion failures of carbon steel waterwall tubes in less than 6 months of service (1,2). Because of this experience, it has become accepted that some type of corrosion protection is required for boiler tubes in refuse-to-energy boilers. Over the years, many different alloys have been evaluated to improve tube life in waste-to-energy boilers. The most successful materials used for corrosion protection are nickel alloys.
Proceedings Papers
Proc. ASME. NAWTEC12, 12th Annual North American Waste-to-Energy Conference, 91-98, May 17–19, 2004
Paper No: NAWTEC12-2214
Abstract
The combustion of municipal solid waste in a boiler for power generation produces a very corrosive environment for the boiler tube materials. The environment contains HCl, SO 2 , various metal chlorides and sulfates along with typical combustion products. Due to their low melting points and high vapor pressures, metal chlorides are believed to be primarily responsible for the boiler tube corrosion problems encountered in waste-to-energy (WTE) boilers. Without some sort of corrosion protection method, the standard materials of the construction for the boiler, such as carbon and Cr-Mo steels, are subject to severe high temperature corrosion attack. The present paper discusses the possible modes of high temperature corrosion for waterwalls and boiler tubes in the convection section, and the prevailing protection method for these components as well as the performance of various alloys in these hostile combustion environments.