The model of non-Fourier heat conduction in a kind of two-phase mediums with great different heat conductivity is deduced by the idea and mathematics of dual phase lag. It is pointed out that the relaxation times to establish heat flux and temperature gradient include both kinds in this model: the relaxation time appeared under the conditions of applied high heat flux and rapid heating, the relaxation time introduced by the non-equilibrium heat exchange between the two-phase mediums. It is very important to distinguish the both kinds of relaxation times for analyzing and explaining the experimental phenomena of non-Fourier heat conduction in this kind of two-phase mediums.

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