Computational Fluid Dynamics (CFD) models allows the three-dimensional simulation of the complex electrochemical, fluid dynamics, and thermodynamic phenomena related to the temperature and pressure distribution in the channels and the porous media than occurs inside the fuel. This work presents a CFD Multiphysics simulation of a PEM Fuel Cell under different operational conditions in their inlet streams. The simulation was done by using COMSOL Multiphysics® software, and it takes into account the mass transfer of gases in the channels, the porous media and the electrochemistry from reactions in a 5 cm2 active area. From the electrochemical perspective, the relationship between the charge transfer and the overpotentials are taken into account by kinetic expressions. In addition, the ohm’s law is applied in conjunction with the charge transfer to describe the conduction of current in the electrodes and electrolytes. Gas diffusion layers (GDL) along with the catalyst layers are modeled as porous media restricting the electrochemical reaction. As the result of different simulation scenarios representing different operational conditions, the characteristic Polarization Curve of the fuel cell, the dependence between the voltage in the cell, and the demanded current by the load are obtained. A reduction in the electrical potential was evidenced due to the reaction activation potential, the ohmic losses due to the electrical resistance of the materials and the concentration losses as a result of deficiencies in the diffusion of the reactants through the porous medium. Currents distributions and water content are analyzed in order to understand the role of temperature, load, and humidity over the fuel cell performance.

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