It has been proposed that compact ceramic heat exchangers can be used for high temperature, corrosive applications. This paper discusses the design development of a micro-channel heat exchanger for the decomposition of sulfuric acid as part of the hydrogen producing sulfur iodine thermo-chemical cycle. Corrosion studies of candidate materials indicate that ceramic materials have superior corrosion and creep resistance under these high temperature, high acid concentration environments. This compact heat exchanger utilizes micro-channels to enhance the heat transfer while maintaining low pressure drops within the system. Through modular stacking of these micro-channel networks, a "shell and plate" configuration enables the processing of commercial-scale processes. The ceramic materials provide for long-life applications. The design of the micro-channel features captures the enhanced heat transfer characteristics at the micro-scale; the modular assembly permits the integration into macro-scale processes. As a case study, the thermal performance and the economics were investigated to determine the feasibility of this compact heat exchanger for the hydrogen producing sulfur iodine thermo-chemical cycle. The results of this design effort with its associated performance goals and development status will be reported.

1.
Caprioglio, G.; McCorkle, K.H.; Besenbruch, G.E.; Rode, J.S.; “Thermochemical water-splitting cycle, bench-scale investigations and process engineering. Annual report, October 1, 1978 — September 30, 1979.” DOE annual Report GA-A-15788 (OSTI ID 5416940). General Atomic Co., San Diego, CA (USA).
2.
Forsberg, Charles; et. al.; “Nuclear Thermochemical Production of Hydrogen with a Lower Temperature Iodine-Westinghouse-Ispra Sulfur Process.”, OECD Nuclear Energy Agency, Second Information Exchange Meeting on Nuclear Production of Hydrogen; Argonne, Illinois; October 2-3, 2003. http://www.ornl.gov/~webworks/cppr/y2001/pres/118529.pdf.
3.
Besenbruch, G.E.; “General Atomic Sulfur-Iodine Thermochemical Water-Splitting Process.” Am Chem Soc, Div Pet Chem, 271, pp 48–53, American Chemical Society Annual Meeting; 27 Mar 1982; Las Vegas, NV, USA.
4.
Shultz, K.R.; “Use of the Modular Helium Reactor for Hydrogen Production”; World Nuclear Association Annual Symposium; 3–5 September, 2003; London, England. http://www.world-nuclear.org/sym/2003/pdf/schultz.pdf.
5.
Kays, W. M., London, A. L.; “Compact Heat Exchangers,” 2d ed., McGraw-Hill Book Company, New York, 1964.
6.
Kelly, Kevin W, et. al; “Crossflow Micro Heat Exchanger.” US Patent 6,415,860. Filed 9 Feb 2000.
7.
Bowdery, Tony; “LNG Applications of Diffusion Bonded Heat Exchangers”; AIChE Spring Meeting, 23–27 April 2006. Orlando, FL.
8.
Tiegs, T. N. (1981, July). Materials Testing for Solar Thermal Chemical Process Heat. Metals and Ceramics Division, Oak Ridge National Laboratory. Oak Ridge, Tennessee. ONRL/TM-7833, 1–59.
9.
Irwin, H.A., Ammon, R. L. Status of Materials Evaluation for Sulfuric Acid Vaporization and Decomposition Applications. Adv. Energy Syst. Div., Westinghouse Electric Corp., Pittsburg, PA, USA. Advances in Hydrogen Energy (1981), 2(Hydrogen Energy Prog., Vol. 4), 1977–99.
10.
Coen-Porisini, Fernanda. Corrosion Tests on Possible Containment Materials for H2SO4 Decomposition. Jt. Res. Counc., ERATOM, Ispra, Italy. Advances in Hydrogen Energy (1979), 1(Hydrogen Energy Syst., Vol. 4), 2091–112.
11.
Ishiyama, Shintaro and Maruyama, Shigeki. Hot Corrosion Resistant Ceramics for Compact Heat Exchanger. (Japan Atomic Energy Research Institute, Japan; Toshiba Corp.). Jpn. Kokai Tokkyo Koho (2005), 17pp.
12.
Gelbard, Fred; “Sulfuric Acid Decomposition Status Report.” UNLV HTHX Quarterly Review Meeting, 17 Mar 2005, Ceramatec, Inc. Salt Lake City UT. http://nstg.nevada.edu/heatpresentations/031705/Gelbard%202 005%203%2017%20UNLV%20presentation.pdf.
13.
Ishiyama, Shintaro, et al.; “Compact Heat Exchanger Made of Ceramics Having Corrosion Resistance at High Temperature”, US Patent Application Publication, US 2005/0056410 A1.
14.
Van Roode, Mark, Ferber, Mattison K., Richerson, David R.; “Ceramic Gas Turbine Design and Test Experience: Progress in Ceramic Gas Turbine Development: Volume 1.” Published by ASME, New York, NY, 2002.
15.
Narushima
T.
, et al.; “
High Temperature Oxidation of Silicon Carbide and Silicon Nitride,’
Materials Transactions
, JIM, Vol.
38
No.
10
(
1997
), pp
821
833
.
16.
Foster, Brian D. Patton, John B.; “Ceramics in Heat Exchangers: Advances in Ceramics — Volume 14.” Published by The American Ceramic Society; Columbus, Ohio; 1984.
17.
Jacobson
Nathan S.
(
1993
).
Corrosion of Silicon-Based Ceramics in Combustion Environments
.
J. Am. Ceram. Soc.
76
[
1
],
3
28
.
18.
Robinson
R. C.
and
Smialek
J. L.
(
1999
).
SiC Recession Caused by SiO2 Scale Volatility under Combustion Conditions: I, Experimental Results and Empirical Model
.
J. Am. Ceram. Soc.
82
[
7
],
1817
25
.
19.
Opila
Elizabeth J.
,
Smialek
James L.
,
Robinson
Raymond C.
,
Fox
Dennis S.
,
Jacobson
Nathan S.
(
1999
).
SiC Recession Caused by SiO2 Scale Volatility under Combustion Conditions: II, Thermodynamics and Gaseous-Diffusion Model
.
J. Am. Ceram. Soc.
82
[
7
],
1826
34
.
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