Magnetic fluids or ferrofluids are colloidal dispersions of magnetic nanoparticles in a liquid carrier. These nanoparticles have a specific size range in order to remain suspended in the liquid, about 3 to 15 nm. In this range Brownian motion (thermal molecular motion in the liquid) keeps the particles from settling out. Because magnetic particles tend to aggregate, and aggregates sediment faster than single particles, the particles are coated with a stabilizing dispersing agent. The surfactant must be matched to the carrier type and must overcome the attractive Van der Waals and magnetic forces between the particles to prevent agglomeration even when a strong magnetic field is applied to the ferrofluid. A device that can pump a fluid with no moving mechanical parts represents a very encouraging alternative since such device would be practically maintenance free. A magnetocaloric pump achieves this purpose by providing a pressure gradient to a ferrofluid placed inside a magnetic field while experiencing a temperature change. If the temperature change is produced by extracting heat out of an element that needs refrigeration, coupling this heat via a heat pipe with the magnetocaloric pump will result in a completely passive cooling system. For applications near ambient temperature the ferrofluid must have specific characteristics such as low Curie temperature, high pyromagnetic coefficient, high thermal conductivity and low viscosity. This work presents the detailed description of the synthesis of ferrofluids composed of Mn-Zn ferrite nanoparticles and the characterization of its magnetic and thermal properties. Different composition of Mn-Zn ferrites nanoparticles were produce and evaluated. This ferrite ferrofluid was compared with commercially available magnetite ferrofluid in a magnetocaloric pump prototype. Results of saturation magnetization, pyromagnetic coefficient, Curie temperature, particle size, viscosity and pressure increment inside the magnetocaloric pump are presented.

1.
Berkovsky, B.M. and Bashtovoy V., Magnetic Fluids and Applications Handbook, New York:
2.
Cengel, Y. A., Heat Transfer: a Practical Approach, New York, McGraw-Hill, 2003.
3.
Choi
S. U. S.
, “
Enhancing Thermal Conductivity of Fluids with Nanoparticles
,”
Developments and Applications of Non-Newtonian Flows
, D. A. Signer and H. P. Wang (Eds.), The American Society of Mechanical Engineers, New York, FED-Vol.231/MD-Vol.
66
, pp.
99
105
,
1995
.
4.
Eastman
J. A.
,
Choi
S. U. S.
,
Li
S.
,
Yu
W.
, and
Thompson
L. J.
, “
Anomalously increased effective thermal conductivities of ethylene glycol-based nanofluids containing copper nanoparticles
,”
Applied Physical Letters
, vol.
78
, pp.
718
720
,
2001
.
5.
Faghri, A., Heat Pipe Science and Tecnology, Taylor & Francis, Washington, 1995.
6.
Goodson
K.
et al.,
ElectronicsCooling
,
Technical Brief
, Vol.
8
, No.
4
, pp.
46
47
,
2002
.
7.
Ku, J., “Operating Characteristics of Loop Heat Pipes”. SAE paper No 1999-01-2007, 1999.
8.
Ku, J., “Start-up Issues of Capillary Pumped Loops”. 9th International Heat Pipe Conference, Albuquerque, New Mexico, May 1–5, 1995.
9.
Lee
S.
, and
Choi
S. U.
, “
Application of Metallic Nanoparticle Suspensions in advanced Cooling Systems
”,
ASME Publications
PVP-Vol. 342/MD-Vol.
72
, pp.
227
234
,
1996
.
10.
Lin, G.C. Xu, C.D. Zhang, J.X., “Magnetocaloric effect in La0.80-xCa0.20SrxMnO3 (x=0.05,0.08,0.10)” J. Magnetism, Magn. Materials, 283, 375–379, 2004.
11.
Love
L. J.
,
Jansen
J. F.
,
McKnight
T. E.
,
Roh
Y.
and
Phelps
T. J.
, “
A magnetocaloric pump for microfluidic applications
,”
IEEE Transactions on nanobioscience
, vol.
3
, no.
2
, pp
101
110
,
2004
.
12.
O’Neal
D. P.
,
Hirsch
L. R.
,
Halas
N. J.
,
West
J. L.
,
Nanoshellassisted photothermal ablation of colon carcinoma-derived tumors in mice
,
Cancer Letter
,
209
,
171
6
,
2004
.
13.
Pecharsky
V. K.
,
Gschneidner
K. A.
, “
Magnetocaloric efect and magnetic refrigeration
”,
J. of Magnetism Magn.
Materials
200
,
44
56
,
1999
.
14.
Peterson, G.P., An introduction to Heat Pipes: Modeling, Testing and Applications, Wiley, New York, 1994.
15.
Raj, K., Moskowitz, B., Casciari, R., Advances in ferrofluid technology, J. Magnetism, Magn. Materials 149 174–180, 1995
16.
Rosensweig, R. E., Ferrohydrodynamics, Dover Publications, Mineola, New York, 1997.
17.
Silverstein, C., Design and Technology of Heat Pipes for Cooling and Heat Exchange, Hemisphere Publishing Corporation, 550 pp., 1992.
18.
Swanson, T. D., “Thermal Control Technologies for Complex Spacecraft”. 13th International Heat Pipe Conference (13th IHPC), Shanghai, China, September 21–25, 2004
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