Within this study energetic and exergetic theoretical analyses of a novel IGCC power plant concept with CO2 capture are carried out. The core process of the concept examined is based on the high pressure steam gasification of high moisture low grade coals where CO2 is captured reacting exothermically with CaO-based sorbents and high hydrogen-content carbon-free fuel gas is produced without using additional shift reactors and CO2 separation stages. The carbonated sorbents are continuously fed to an oxygen blown calcination reactor where pure CO2 is released and active CaO is reproduced. This concept can be realised in a dual fluidised bed reactor system where coal gasification and CaCO3 calcination are taking place simultaneously. In this paper possible plant configurations are presented and detailed simulation of 400 MWe IGCC power plant based on a state of the art gas turbine cycle with a three pressure stage heat recovery steam generator is performed using the ASPEN Plus simulator. The calculated results demonstrate the capability of the power plant to deliver almost decarbonised electricity while achieving net plant efficiencies at about 38.4% of coal lower heating value (LHV). Based on the energy analysis and the data generated from the simulation an exergy analysis was performed in order to quantify and localize the thermodynamic irreversibility in each process component as well as to asses the overall thermodynamic imperfection of the proposed process.

1.
PCC (Intergovernmental Panel for Climate Change), “Third Assessment Report -Climate Change 2001”, www.ipcc.ch
2.
IEA, World Energy Outlook 2004.
3.
K. Thambimuthu, Paul Freund, “CO2 Capture and Sequestration from Power Generation”, Studies by the IEA Greenhouse Gas R&D programme
4.
European Commission, European CO2 Capture & Storage Projects, October 2004.
5.
U.S DOE-NETL, Carbon Sequestration Technology Roadmap & Program Plan 2004, April 2004. CO2NET Thematic Network, “Report on the current stage and the need for further research on CO2 Capture and Storage”, June 2004 www.co2net.org.
6.
Herzong H., Colomb C. “Carbon Capture and Storage from Fossil Fuel Use”, Enc. of Energy, Vol 1, 2004
7.
Daniel Chinn, Gerald N. Choi, Robert Chu & Bruce Degen, “Cost efficient amine plant design for post combustion co2 capture from powerplant flue gas”, Seventh International Conference on Greenhouse Gas Control Technologies, Toronto, 2004
8.
Currran P.G, Fink C.E, and Gorin E, CO2 acceptor gasification process, Adv. Chem Ser., 1967;69:141–65.
9.
Fink C, Gurran G, and Sabdury J, CO2 Acceptor Process Pilot Plant-1974 Rapid City, South Dacota, Paper presented at 6th Synthetic Pipeline Gas Symp., Chicago, October 1974.
10.
Abanades C.J, Alvarez D, Conversion Limits in the Reaction of CO2 with Lime Energy & Fuels 2003;17:308–315.
11.
Lin S., Harada M, Suzuki Y., Hatano H., Continuous experiment regarding hydrogen production by coal/CaO reaction with steam (1) gas products, Fuel 2004;83:869–874.
12.
Silaban, A.; Harrison, D.P. High temperature capture of carbon dioxide: characteristics of the reversible reaction between CaO(s) and CO2(g). Chem. Eng. Comm., 1995, 137, 177.
13.
Berger R., Hawthorne C., Scheffknecht G., Lime Enhanced Gasification of Solids, A Process Offering New Prospects in Fuel Chemistry. International Freiberg Conference on IGCC & XtL Technologies, 2005
14.
Salvador C., Lu D., Anthony E.J., Abanades J.C, Enhancement of CaO for CO2 capture in an FBC environment, Chem. Eng. J.2003;96:187–195.
15.
Ertesvag I.S., Kvamsdal H.M., Bolland O., Exergy Analysis of gas Turbine combined-cycle power plant with pre-combustion CO2 capture, Energy 2005;305–39
16.
Aspen Plus Version 13.1.0, Aspentech, www.aspenthech.com
17.
Gatecycle Version 5.51.0.r, The General Electric Company, www.gepower.com 10
18.
T.J. Kotas, The Exergy Method of Thermal Plant Analysis, Butterworths, 1985.
19.
Szargut, J., Morris, D. R. and Steward, F. R., Exergy Analysis of Thermal, Chemical and Metallurgical, Processes, Hemisphere Publishing Corporation, New York, 1988.
20.
IEA GHG, 2003, “Potential for Improvement in Gasification Combined Cycle Power Generation with CO2 capture”, IEA Greenhouse Gas R&D Programme, Report Nr PH4/19
21.
P. Klimantos, N. Koukouzas, E. Kakaras, I. Typou, Precombustion CO2 capture in low rank coal gasification combined cycle power plants, GHGT8, Trondheim, 2006.
This content is only available via PDF.
You do not currently have access to this content.