The Effect of Matrix Type on Self-Assembly of Nanoparticles for Mechanical and Magnetic Applications

The controlled synthesis of nanostructured particles with uniform size, shape, composition, and preferred orientation is a formidable task. Some conventional techniques have been demonstrated with limited success; however, reproducible processing schemes for heterogeneous multifunctional materials are still not satisfactory. To realize the advantageous technical applications of nanostructured materials, self-assembly or self-organizing methods are currently under investigation. Our results show that the matrix or template used for directed growth of nanoparticles (Fe, Ni) significantly affects the resultant mechanical properties of the multilayered structure. For example, a crystalline material like TiN, which grows epitaxially on silicon, results in embedded epitaxial nanoparticles. Conversely, an amorphous template like Al₂O₃ results in polycrystalline magnetic particles. In this work, we will discuss the effect of matrix type, specifically yttria stabilized zirconia (YSZ), on the orientation of nanoparticle assemblies. The resultant mechanical and magnetic properties of the multilayer structures will be discussed in the oral presentation.