Numerical simulation of flow, combustion phenomena and pollutants emission characteristics have been obtained on an homogeneous-charged internal combustion engine having conventional flat piston and five other bowl-in-piston geometries. The code employed here uses the time marching procedure and solves the governing partial differential equations of multi-component chemically reactive flow by finite difference method. The transient solution is marched out in a sequence of time steps. The results show that the piston geometry affects the local flame properties which subsequently influences the pollutants emission level. The numerical results provide a cost effective means of developing advanced internal combustion engine chamber geometry design that provides high efficiency and low pollution. It is expected that increased computational tools will be used in the future for enhancing our understanding of the detailed combustion process in internal combustion engines and all other energy conversion systems. Such detailed information is critical for the development of advanced methods for energy conservation and environmental pollution control.