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Ethylene-propylene rubber
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Proceedings Papers
Proc. ASME. ICONE24, Volume 2: Smart Grids, Grid Stability, and Offsite and Emergency Power; Advanced and Next Generation Reactors, Fusion Technology; Safety, Security, and Cyber Security; Codes, Standards, Conformity Assessment, Licensing, and Regulatory Issues, V002T05A008, June 26–30, 2016
Paper No: ICONE24-60729
Abstract
Nuclear power plants contain hundreds of kilometers of electrical cables including cables used for power, for instrumentation, and for control. It is essential that safety-related cable systems continue to perform following a design-basis event. Wholesale replacement of electrical cables in existing plants facing licensing period renewal may be both impractical and cost-prohibitive. It is therefore important to understand the long term aging of cable materials to have confidence that aged cables will perform when needed. It is equally important in support of cable aging management to develop methods to evaluate the health of installed cables and inform selective cable replacement decisions. The most common insulation materials for electrical cables in nuclear power plants are cross-linked polyethylene and ethylene-propylene rubber. The mechanical properties of these materials degrade over time in the presence of environmental stresses including heat, gamma irradiation, and moisture. Mechanical degradation of cable insulation beyond a certain threshold is unacceptable because it can lead to insulation cracking, exposure of energized conductors, arcing and burning or loss of the ability of the cable system to function during a design-basis accident. While thermal-, radiation-, and moisture-related degradation of polymer insulation materials has been extensively studied over the last few decades, questions remain regarding the long term performance of cable materials in nuclear plant-specific environments. Identified knowledge gaps include an understanding of the temperature-dependence of activation energies for thermal damage and an understanding of the synergistic effects of radiation and thermal stress on polymer degradation. Many of the outstanding questions in the aging behavior of cable materials relate to the necessity of predicting long-term field degradation using accelerated aging results from the laboratory. Materials degrade faster under more extreme conditions, but extension of behavior to long term degradation under more mild conditions, such as those experienced by most installed cables in nuclear power plants, is complicated by the fact that different degradation mechanisms may be involved in extreme and mild scenarios. The discrepancy in predicted results from short term, more extreme exposure and actual results from longer term, more mild exposures can be counter intuitive. For instance, due to the attenuation of oxidation penetration in material samples rapidly aged through exposure to high temperatures, the bulk of the samples may be artificially protected from thermal aging. In another example, simultaneous exposure of cable insulation material to heat and radiation may actually lead to less damage at higher temperatures than may be observed at lower temperatures. The Light Water Reactor Sustainability program of the United States (US) Department of Energy (DOE) Office of Nuclear Energy is funding research to increase the predictive understanding of electrical cable material aging and degradation in existing nuclear power plants in support of continued safe operation of plants beyond their initial license periods. This research includes the evaluation and development of methods to assess installed cable condition.
Proceedings Papers
Proc. ASME. ICONE24, Volume 1: Operations and Maintenance, Aging Management and Plant Upgrades; Nuclear Fuel, Fuel Cycle, Reactor Physics and Transport Theory; Plant Systems, Structures, Components and Materials; I&C, Digital Controls, and Influence of Human Factors, V001T01A007, June 26–30, 2016
Paper No: ICONE24-60311
Abstract
As part of the Light Water Reactor and Sustainability (LWRS) program in the U.S. Department of Energy (DOE) Office of Nuclear Energy, material aging and degradation research is currently geared to support the long-term operation of existing nuclear power plants (NPPs) as they move beyond their initial 40 year licenses. The goal of this research is to provide information so that NPPs can develop aging management programs (AMPs) to address replacement and monitoring needs as they look to operate for 20 years, and in some cases 40 years, beyond their initial, licensed operating lifetimes. For cable insulation and jacket materials that support instrument, control, and safety systems, accelerated aging data are needed to determine priorities in cable aging management programs. Before accelerated thermal and radiation aging of harvested, representative cable insulation and jacket materials, the benchmark performance of a new test capability at Oak Ridge National Laboratory (ORNL) was evaluated for temperatures between 70 and 135°C, dose rates between 100 and 500 Gy/h, and accumulated doses up to 200 kGy. Samples that were characterized and are representative of current materials in use were harvested from the Callaway NPP near Fulton, Missouri, and the San Onofre NPP north of San Diego, California. From the Callaway NPP, a multiconductor control rod cable manufactured by Boston Insulated Wire (BIW), with a Hypalon/ chlorosulfonated polyethylene (CSPE) jacket and ethylene-propylene rubber (EPR) insulation, was harvested from the auxiliary space during a planned outage in 2013. This cable was placed into service when the plant was started in 1984. From the San Onofre NPP, a Rockbestos Firewall III (FRIII) cable with a Hypalon/ CSPE jacket with cross-linked polyethylene (XLPE) insulation was harvested from an on-site, climate-controlled storage area. This conductor, which was never placed into service, was procured around 2007 in anticipation of future operation that did not occur. Benchmark aging for both jacket and insulation material was carried out in air at a temperature of 125°C or in a uniform 140 Gy/h gamma field over a period of 60 days. Their mechanical properties over the course of their exposures were compared with reference data from comparable cable jacket/insulation compositions and aging conditions. For both accelerated thermal and radiation aging, it was observed that the mechanical properties for the Callaway BIW control rod cable were consistent with those previously measured. However, for the San Onofre Rockbestos FRIII, there was an observable functional difference for accelerated thermal aging at 125°C. Details on possible sources for this difference and plans for resolving each source are given in this paper.
Proceedings Papers
Proc. ASME. ICONE18, 18th International Conference on Nuclear Engineering: Volume 5, 309-316, May 17–21, 2010
Paper No: ICONE18-30169
Abstract
At nuclear power plants, containment vessel acts as pressure barrier in such an emergency as a loss-of-coolant accident. It is important as safety equipment to prevent radiological from leaking outside. Rubber gaskets, which are used for sealing faces of containment vessel, are needed to maintain certain sealability not only in stable condition but also in an emergent situation. Among important characteristics of the rubber gasket are not only physical property changes after general aging test (for example, tensile strength changes after heat resistance test) that indicate long-term stability of gasket itself, but also after radiation resistance test which gives potential to good substitute characteristic in terms of sealability in such cases. Physical property changes after general aging test do not always substitute sealability in an emergency, because they do not reflect effects of radiation. That is why nuclear power plant engineers must choose suitable rubber materials that have high performance in radiation resistance. In Japan, silicone rubber gaskets have been used for containment vessel for a long time since 1970th, but in the United States, ethylene propylene diene terpolymer (EPDM) gaskets have been widely used. NICHIAS has silicone rubber and EPDM materials for containment vessel and these gaskets have been used in nuclear power plant. But it is not obvious why different materials have been used in two countries because few relative comparisons of the two materials have been carried out. Especially silicone rubber and EPDM gaskets have many combinations of chemical compositions, so it is difficult to evaluate gasket suitability for containment vessel. There are many kinds of studies concerning long-term stability and life of gasket, but we all must know what characteristics relate sealability under radiation exposure condition and are suitable for guidepost of sealability under previous condition. This report compares silicone rubber gasket with EPDM gasket on physical property changes under irradiation and thermal treatment. We report compression set test results about one each type of silicone rubber and EPDM gasket under irradiation from Co60. And we also report relationships in physical property changes between irradiation and thermal treatment. Finally NICHIAS predicts long-term and emergency sealability of these gaskets from the results of evaluation. We hope it will be a part of design guideline of rubber gasket for containment vessel.
Proceedings Papers
Proc. ASME. ICONE14, Volume 2: Thermal Hydraulics, 329-336, July 17–20, 2006
Paper No: ICONE14-89332
Abstract
Air-water two-phase flow patterns in a four by four square lattice rod bundle consisting of an acrylic channel box of 68 mm in width and transparent rods of 12 mm in diameter were observed by utilizing a high speed video camera, FEP (fluorinated ethylene propylene) tubes for rods, and a fiberscope inserted in a rod. The FEP possesses the same refractive index as water, and thereby, whole flow patterns in the bundle and local flow patterns in subchannels were successfully visualized with little optical distortion. The ranges of liquid and gas volume fluxes, < J G > and < J L >, in the present experiments were 0.1 < < J L > < 2.0 m / s and 0.04 < < J G > < 8.85 m / s , which covered typical two-phase flow patterns appearing in a fuel bundle of a boiling water nuclear reactor. As a result, the following conclusions were obtained: (1) the region of slug flow in the < J G > – < J L > flow pattern diagram is so narrow that it can be regarded as a boundary between bubbly and churn flows, (2) the boundary between bubbly and churn flows is close to the boundary between bubbly and slug flows of the Mishima & Ishii’s flow pattern transition model, and (3) the boundary between churn and annular flows is well predicted by the Mishima & Ishii’s model.