In this paper effect of on reduction a Cu-ZSM-5 catalyst of nitrogen oxides is investigated in a diesel engine. This research focuses to solve a problem that there is not enough THC to reduce nitrogen oxides in exhaust gas from a diesel engine. When diesel oil is directly supplied into the exhaust gas, the THC concentration sharply rises and the NOx conversion rate increases. The maximum NOx conversion rate reaches to 63% when the flow rate of diesel oil is 30 ml/min at a catalyst temperature 450 °C. The NOx reduction with less sacrifice of the specific fuel consumption is possible when the fuel is supplied into the exhaust pipe.