In recent years, Gas-to-Liquid (GTL) jet fuel is considered as an alternative jet fuel because of its cleaner combustion characteristics. The chemical and physical properties of GTL fuels are different from those of the conventional jet fuels. The objective of the present work is to investigate the effect of ambient conditions and fuel volatilization characteristics on the macroscopic spray features. To this end, the macroscopic spray performance is visualized using the shadowgraph imaging technique at elevated ambient conditions. The near nozzle spray parameters like spray cone angle, sheet breakup length, and the sheet velocity, are determined from the shadowgraph images using an in-house program. The effect of ambient conditions on the near nozzle spray characteristics for conventional fuels has been reported in the literature. However, these effects have not been reported in detail for the alternative, GTL jet fuels. The results show that the ambient gas pressure has a significant effect on the spray performance when compared to that of the ambient gas temperature. At atmospheric conditions, the spray performance of GTL fuel is comparable to those of Jet A-1 fuel. However, with the increase in ambient conditions, the difference in spray performance of GTL and Jet A-1 is significant.

In recent years, there has been an interest in finding a jet fuel alternative to the crude oil-based kerosene. Gas-to-liquid (GtL) fuel is being derived via Fischer-Tropsch synthesis processes by converting natural gas to longer-chain hydrocarbons which form the basis for jet fuel. In this study, new experimental ignition delay time measurements of GtL jet fuels have been determined at elevated pressures and temperatures. The measurements were conducted in a heated, high-pressure shock-tube facility capable of initial temperatures up to 200°C. Two GtL jet fuels were investigated, Shell GTL and Syntroleum S-8, which can be used in aviation applications at concentrations up to 50% blended with conventional oil-based kerosene. The ignition delay time measurements were conducted behind reflected shock waves for gaseous-phase fuel in air at a pressure around 10 atm and over a temperature range of 966 to 1266 K for two equivalence ratios, fuel lean (ϕ = 0.5) and stoichiometric (ϕ = 1.0). Ignition delay time was determined by observing the pressure and electronically excited OH chemiluminescence around 307 nm at the endwall location. Similar ignition delay times were observed for the two fuels at the fuel lean condition, while Syntroleum S-8 showed shorter ignition delay times at the stoichiometric condition. Comparisons are made with ignition delay time measurements for Jet-A previously conducted in the same facility and showed reasonable agreement over the tested conditions. The predictions from the available literature for GtL fuel surrogate kinetics models were obtained and compared with the experimental measurements.

New laminar flame speed experiments have been collected for multiple alternative liquid fuels. Understanding the combustion characteristics of these synthetic fuels is an important step in developing new chemical kinetics mechanisms that can be applied to real fuels. Included in this study are two synthetic Jet fuels: Syntroleum S-8 and Shell GTL. The precise composition of these fuels is known to change from sample to sample. Since these are low vapor pressure fuels, there are additional uncertainties in their introduction into gas-phase mixtures, leading to uncertainty in the mixture equivalence ratio. An in-situ laser absorption technique was implemented to verify the procedure for filling the vessel and to minimize and quantify the uncertainty in the experimental equivalence ratio. The diagnostic utilized a 3.39-μm HeNe laser in conjunction with Beer’s Law. The resulting spherically expanding flame experiments were conducted over a range of equivalence ratios from φ = 0.7 to φ = 1.5 at initial conditions of 1 atm and 403 K in the high-temperature, high-pressure constant-volume vessel at Texas A&M University. The experimental results show that both fuels have similar flame speeds with a peak value just under 60 cm/s. However, it is shown that when comparing the results from different data sets for these real fuels, equivalence ratio is not necessarily the best parameter to use. Fuel mole fraction may be a better parameter to use as it is independent of the average fuel molecule or fuel surrogate used to calculate equivalence ratio in these real fuel/air mixtures.

To achieve the goals of substantial improvements in efficiency and emissions set by Flightpath 2050, fundamentally different concepts are required. As one of the most promising solutions, electrification of the aircraft primary propulsion is currently a prime focus of research and development. Unconventional propulsion sub-systems, mainly the electrical power system, associated thermal management system and transmission system, provide a variety of options for integration in the existing propulsion systems. Different combinations of the gas turbine and the unconventional propulsion sub-systems introduce different configurations and operation control strategies. The trade-off between the use of the two energy sources, jet fuel and electrical energy, is primarily a result of the trade-offs between efficiencies and sizing characteristics of these sub-systems. The aircraft structure and performance are the final carrier of these trade-offs. Hence, full design space exploration of various hybrid derivatives requires global investigation of the entire aircraft considering these key propulsion sub-systems and the aircraft structure and performance, as well as their interactions. This paper presents a recent contribution of the development for a physics-based simulation and optimization platform for hybrid electric aircraft conceptual design. Modeling of each subsystem and the aircraft structure are described as well as the aircraft performance modeling and integration technique. With a focus on the key propulsion sub-systems, aircraft structure and performance that interfaces with existing conceptual design frameworks, this platform aims at full design space exploration of various hybrid concepts at a low TRL level.

Modern aircraft engines combine liquid fuel and air using an intricate flow device with many fuel and air flow passages. To date, the process by which the fuel atomizes within this swirler set has not been examined directly due to optical access limitations. In this work, high-speed x-ray phase-contrast imaging of a liquid spray inside a gas turbine engine swirler geometry is presented. Measurements were carried out at the 7-BM beam-line of the Advanced Photon Source at Argonne National Laboratory using the high-energy broadband x-ray beam. The synchrotron x-ray source provides the necessary photon energy and flux to capture time-resolved fluid phenomena within the confines of the relevant geometry while liquid and air are flowing. Spray nozzle hardware and geometries were provided by the National Jet Fuels Combustion Program, allowing for characterization of the spray using a commercially relevant configuration. Modified swirlers were 3D printed with acrylic to improve imaging access while maintaining influential internal features. Water was used as a surrogate fluid for these studies to demonstrate the visualization capabilities. The experiments were conducted at atmospheric exit pressure conditions with a pressure drop of 6% across the swirler. High-speed imaging of the pilot spray cone revealed sheet breakup several millimeters downstream of the orifice exit, upon interaction with the radial assist air flow. These droplets and ligaments were observed to impinge on the inner filming surface of the swirler and flow toward the exit while developing a tangential flow. Under these conditions, the liquid film grows up to several hundred microns in thickness on the filming surface, and subsequently forms ligaments up to several millimeters in length before breaking up. This work demonstrates the capability of x-ray diagnostics in visualizing liquid flows within solid geometries of technical relevance. Furthermore, the spatial quantification of filming flows and liquid interaction with the swirler air provides validation data for modeling of the multi-phase flows and surface interactions within the swirler.

For the purposes of combustion analysis, n-dodecane is used as the surrogate or a surrogate component for biodiesel and jet fuel. In order to capture kinetic effects in computational combustion, detailed and reduced models of n-dodecane are therefore used. This paper presents a comparative analysis of selected detailed chemical kinetic models of n-dodecane as well as reduction of these detailed models to more compact skeletal versions. The selected models are compared based on their ability to predict ignition phenomena. Measured ignition delay times from the literature are used as references. Both low- and high-temperature ignition simulations are considered. To further facilitate future computational combustion analysis, the detailed models are reduced using the Alternative Species Elimination (ASE) approach reported by Akih-Kumgeh and Bergthorson (Energy & Fuels, 2316–2326, 2013). The resulting skeletal models are compared in terms of their retained species, ranked species sensitivities, and kinetic parameters of the key reactions. Furthermore, within the framework of this paper, another model reduction technique is explored. The aim of this method is to further decrease model reduction time since this is often considered as a weakness of the otherwise effective ASE method. The resulting models from this exploratory reduction approach are compared with those obtained from the ASE method in terms of species retained and the accuracy with which combustion properties from the detailed models are predicted. Further chemical kinetic analysis of the reduced models is carried out with the aim of explaining observed similarities and differences.

The aim of the present work is the experimental investigation of the effects of the addition of water and urea into jet fuels, on the reduction of nitrogen oxides (NOx) emissions and eventually improvement of the lean flame stability in aeroengine combustors. Experiments have been carried out using a 300-kW liquid-fueled swirling combustor. Various urea and/or water concentrations have been tested at the same fuel/air ratio. In order to study the flame behavior, non-invasive optical diagnostic techniques, as charge-coupled device (CCD) cameras in different spectral ranges (Visible and UV ranges, with different optical filters), have been adopted to analyze the shape and the brightness of the flame structure. Measurements of exhaust emissions (NOx, SO2, CO, CO2 and O2) have also been performed in order to evaluate the impact of emulsification on the entire combustion process. Finally, the thermal efficiency losses with respect to the neat jet test case were also analyzed for each emulsified fuel condition.

In the last years, the development of synthetic aviation jet fuels has attracted much interest, to provide alternatives to crude-oil based kerosene. Synthetic jet fuels can be produced from a variety of feedstocks and processes. To limit possible harmful effects on the environment when burning a jet fuel, discussions are attributed to the effects of the specific composition of a synthetic fuel on its performance and its emission pattern. A numerical tool, if available, would also be helpful within the specification process any aviation jet fuel must pass. The present work contributes to the studies and efforts how to design a synthetic jet fuel to match predefined properties, e.g. the energy content or a less harmful emission characteristics compared to Jet A-1. The approach of a generic fuel will be followed in order to design a synthetic jet fuel with pre-defined chemical properties: A chemical kinetic reaction mechanism will be elaborated capable predicting the fundamental combustion properties of the generic fuel for each possible mixing ratio of the components included. In this work, a generic mixture serving as an innovative synthetic jet fuel was studied, with n -dodecane, cyclohexane, and iso -octane chosen as single fuel components; no aromatics were added to reduce the concentration of soot precursors. Then, their fundamental combustion properties, i.e. laminar burning velocity and ignition delay time, were measured in a burner test rig and applying the shock tube technique, respectively. These experimental data were used for the validation of the reaction mechanisms developed for each single fuel component, which were then combined to the reaction mechanism for the generic fuel under consideration. To allow a comparison of the combustion behavior of the synthetic jet fuel directly, with the same reaction mechanism, to Jet A-1, toluene was added as a model component for aromatics. A reduced surrogate reaction model was produced, too. All the reaction mechanisms elaborated are shown to reasonably predict the fundamental combustion properties within the parameter range considered. The compact reduced surrogate model can serve as a virtual jet fuel within numerical simulations. Thus, ultimately, an estimation of the suitability of an innovative synthetic jet fuel as a blending component to crude-oil kerosene is enabled. As a result, CFD simulations can be run efficiently tackling the combustion of a synthetic fuel in a jet engine under practical conditions and by taking into account the interaction between turbulence and chemistry.

Thermal stability is an important characteristic of alternative fuels that must be evaluated before they can be used in aviation engines. This characteristic is of great importance to the effectiveness of the fuel as a coolant and to the engine’s combustion performance. In this work, the thermal stability of Gevo fuel, an alcohol to jet fuel made from plant derived feedstock, was studied. This analysis was used to comment on the effectiveness of the current thermal stability test standard. This work was performed using a spectroscopic ellipsometer to measure the thickness of deposits left on aluminum substrates. It was observed that Gevo deposit thickness increased slowly up to 375 °C and much more rapidly after that point. Similar behavior was observed in JP-8 fuel. Comparisons were also made between color standard ratings and ellipsometric thickness measurements, and it was found that in some cases, darker colors did not indicate thicker deposits. Reference tubes were used to validate the optical models used in this work, and different optical constants were found to best model the results than what are published in the ASTM D3241 test method for thermal stability.

Burning leaner is an effective way to reduce emissions and improve efficiency. However, this increases the instability of the combustion and hence, increases the tendency of the flame to blowout. On the other hand, the ignition delay of a jet fuel is a crucial factor of the instability feedback loop. Shorter ignition delay results in faster feedback loop, and longer ignition delay results in slower feedback loop. This study investigates the potential effect of ignition delay on the lean blowout limit of a gas turbine combustion chamber. At the Low Carbon Combustion Centre of The University of Sheffield, a range of tests were carried out for a range of jet fuels on a Rolls-Royce Tay combustor rig. The ignition delay for each fuel was tested using Advanced Fuel Ignition Delay Analyser (AFIDA 2805). Lean blowout tests (LBO) was conducted on various air flows rates. High speed imaging was recorded using a high speed camera to give further details of the flame behavior near blowout limit for various fuels. The instability level was observed using the pressure, vibration and acoustic fluctuation. This paper presents results from an experimental study performed on a small gas turbine combustor, comparing Lean Blowout limit of different conventional, alternative and novel jet fuels with various ignition delay characteristics. It was observed that at higher cetane number, the blowout is improved remarkably. The Ignition plays an important role in determining the average instability level, and as result determines the Lean Blowout limit of a fuel.

In gas turbine combustors, ignition is achieved by using sparks from igniters to start a flame. The process of sparks interacting with fuel/air mixture and creating self-sustained flames is termed forced ignition. Physical and chemical properties of a liquid fuel can influence forced ignition. The physical effects manifest through processes such as droplet atomization, spray distribution, and vaporization rate. The chemical effects impact reaction rates and heat release. This study focuses on the effect of fuel composition on forced ignition of fuel sprays in a well-controlled flow with a commercial style igniter. A facility previously used to examine prevaporized, premixed liquid fuel-air mixtures is modified and employed to study forced ignition of liquid fuel sprays. In our experiments, a wall-mounted, high energy, recessed cavity discharge igniter operating at 15 Hz with average spark energy of 1.25 J is used to ignite liquid fuel spray produced by a pressure atomizer located in a uniform air coflow. The successful outcome of each ignition events is characterized by the (continued) presence of chemiluminescence 2 ms after spark discharge, as detected by a high-speed camera. The ignition probability is defined as the fraction of successful sparks at a fixed condition, with the number of events evaluated for each fuel typically in the range 600–1200. Ten fuels were tested, including standard distillate jet fuels (e.g., JP-8 and Jet-A), as well as many distillate and alternative fuel blends, technical grade n-dodecane, and surrogates composed of a small number of components. During the experiments, the air temperature is controlled at 27 C and the fuel temperature is controlled at 21 C. Experiments are conducted at a global equivalence ratio of 0.55. Results show that ignition probabilities correlate strongly to liquid fuel viscosity (presumably through droplet atomization) and vapor pressure (or recovery temperature), as smaller droplets of a more volatile fuel would lead to increased vaporization rates. This allows the kernel to transition to a self-sustained flame before entrainment reduces its temperature to a point where chemical rates are too slow. Chemical properties of the fuel showed little influence, except when the fuels had similar physical properties. This result demonstrates that physical properties of liquid fuels have dominating effects on forced ignition of liquid fuel spray in coflow air.

Alternative aviation fuels are evaluated for lean-flame NO x formation, lean-flame blowout (LFBO), and rich-flame soot threshold. The alternative aviation fuels evaluated are: hydro-processed renewable jet (HRJ) made from camelina and tallow, Fischer-Tropsch (FT) jet made from coal and natural gas, and alcohol-based jet. Chromatographic analysis (from another lab) shows that these fuels are composed mainly of iso-alkanes. These fuels are burned as received and with 10–20% aromatic added. For comparison, petroleum-based jet fuels are burned: JP5, JP8, Jet-A, and an aromatic blend. Additionally, we burn several pure fuels: n-hexane, cyclo-hexane, n-octane, iso-octane, n-dodecane, 1-3-5 tri-methyl benzene (TMB), and toluene. The NO x and blowout experiments are performed in a jet-stirred reactor (JSR), and the soot threshold experiments are performed on a Meker burner. The fuels are burned pre-vaporized, premixed, and preheated. NO x is measured by probe sampling and chemiluminescent analysis at a fixed temperature for each fuel. Soot tendency is measured as the fuel-air equivalence ratio (phi) for the first appearance of yellow tips in the flame. This is termed the soot threshold. LFBO is examined by measuring the JSR temperature immediately prior to blowout. Relatively small changes in NO x , LFBO, and soot threshold are measured for the petroleum-based and alternative jet fuels examined. HRJ-tallow is the cleanest burning jet fuel tested with respect to NO x and soot measurements. It exhibits the lowest NO x and the highest soot threshold among alternative fuels tested. A possible correlation between decreasing NO x and increasing soot threshold is explored. The impact of adding aromatic content to the alternative jet fuels is also examined. With 20% aromatic content added to the alternative jet fuels, the soot threshold decreases, though the HRJ-tallow with 20% aromatic added continues to maintain a higher soot threshold than petroleum-based jet fuels. The addition of 20% aromatic does not show a clear trend in NO x . Over the four alternative jet fuels tested, the 20% aromatic addition causes a maximum change in the NO x emission of ± 13% (relative); the average change is close to zero.

The National Jet Fuel Combustion Program (NJFCP) is an initiative, currently being led by the Office of Environment & Energy at the FAA, to streamline the ASTM jet fuels certification process for alternative aviation fuels. In order to accomplish this objective, the program has identified specific applied research tasks in several areas. The National Research Council of Canada (NRC) is contributing to the NJFCP in the areas of sprays and atomization and high altitude engine performance. This paper describes work pertaining to atomization tests using a reference injection system. The work involves characterization of the injection nozzle, comparison of sprays and atomization quality of various conventional and alternative fuels, as well as use of the experimental data to validate spray correlations. The paper also briefly explores the application viability of a new spray diagnostic system that has potential to reduce test time in characterizing sprays. Measurements were made from ambient up to 10 bar pressures in NRC’s High Pressure Spray Facility using optical diagnostics including laser diffraction, phase Doppler anemometry (PDA), LIF/Mie Imaging and laser sheet imaging to assess differences in the atomization characteristics of the test fuels. A total of nine test fluids including six NJFCP fuels and three calibration fluids were used. The experimental data was then used to validate semi-empirical models, developed through years of experience by engine OEMs and modified under NJFCP, for predicting droplet size and distribution. The work offers effective tools for developing advanced fuel injectors, and generating data that can be used to significantly enhance multi-dimensional combustor simulation capabilities.

This paper presents a numerical framework for characterizing fuel injection in modern combustors. The approach utilizes scaling analysis to describe the droplet evaporation in non-dimensional and fluid-independent terms. The results of the model are validated against published experimental data of isolated droplets evaporating at subcritical and near-critical conditions. The model is incorporated in a spray calculation framework and extended to the supercritical regime to assess the impact of different fluid-properties and evaporation models on temperature and fuel vapor distributions. The results suggest that in a non-convective environment the transient and quasi-steady evaporation rates vary exponentially with Lewis number. Furthermore, the results show fluid-independent behavior of the droplet evaporation, indicating that a single-component fluid can potentially be used as a modeling surrogate for jet fuel. The first-principles analysis demonstrates that classical evaporation models overestimate transient evaporation and underestimate quasi-steady evaporation, with discrepancies up to 70% at supercritical conditions. This is due to limitations in fuel-property description and the lack of non-isothermal droplet characterization at near-critical conditions. The temperature profiles are typically under-predicted and fuel vapor concentrations are over-predicted in standard spray calculations with subcritical evaporation models. As such the proposed framework breaks new ground in modeling of supercritical fuel injection. The improved quality in the predicted fuel concentration and temperature distribution can enable more accurate assessment of flame position, improving the estimation of combustion stability margins and NOx emissions. The model can be incorporated in commercial codes to guide the design of combustors operating at supercritical conditions.

Nitric oxide produced during combustion will be present in vitiated air used in many devices with exhaust gas recirculation. An experimental and modeling investigation of the effect of nitric oxide on the ignition of C 1 to C 3 hydrocarbon fuels, namely, CH 4 , C 2 H 4 , C 2 H 6 and C 3 H 6 , is presented. These molecules are important intermediate species generated during the decomposition of long-chain hydrocarbon fuel components typically present in jet fuels. Moreover, CH 4 and C 2 H 6 are major components of natural gas fuels. Although the interaction between NO x and CH 4 has been studied extensively, limited experimental work is reported on C 2 H 4 , C 2 H 6 and C 3 H 6 . NO x , even in very low concentrations, has previously been shown to effectively enhance the ignition of CH 4 . As a continuation of previous work with C 3 H 8 , ignition delay time measurements were obtained using a flow reactor facility with the alkanes (CH 4 and C 2 H 6 ) and olefins (C 2 H 4 and C 3 H 6 ) at 900 K and 950 K temperatures with 15 mole% and 21 mole% O 2 . Based on the experimental data, the overall effectiveness of NO in promoting ignition is found to be: CH 4 > C 3 H 6 > C 3 H 8 > C 2 H 6 > C 2 H 4 . CSE’s detailed kinetic mechanism, developed for natural gas fuel components, is used for model predictions as well as for sensitivity and species flux analyses. As expected, the reaction between HO 2 and NO plays a critical role in promoting the ignition by generating the OH radical while converting NO into NO 2 . In addition, various important fuel-dependent reaction pathways that promote the ignition of these fuels are identified. H-atom abstraction by NO 2 has significant contribution to the ignition of C 2 H 4 , and C 2 H 6 whereas the reaction between NO 2 and allyl radical (aC 3 H 5 ) is an important route for the ignition of C 3 H 6 .

This paper describes experimental measurements of forced ignition of prevaporized liquid fuels in a well-controlled facility that incorporates non-uniform flow conditions similar to those of gas turbine engine combustors. The goal here is to elucidate the processes by which the initially unfueled kernel evolves into a self-sustained flame. Three fuels are examined: a conventional Jet-A and two synthesized fuels that are used to explore fuel composition effects. A commercial, high-energy recessed cavity discharge igniter located at the test section wall ejects kernels at 15 Hz into a preheated, striated crossflow. Next to the igniter wall is an unfueled air flow; above this is a premixed, prevaporized, fuel-air flow, with a matched velocity and an equivalence ratio near 0.75. The fuels are prevaporized in order to isolate chemical effects. Differences in early ignition kernel development are explored using three, synchronized, high-speed imaging diagnostics: schlieren, emission/chemiluminescence, and OH planar laser-induced fluorescence (PLIF). The schlieren images reveal rapid entrainment of crossflow fluid into the kernel. The PLIF and emission images suggest chemical reactions between the hot kernel and the entrained fuel-air mixture start within tens of microseconds after the kernel begins entraining fuel, with some heat release possibly occurring. Initially, dilution cooling of the kernel appears to outweigh whatever heat release occurs; so whether the kernel leads to successful ignition or not, the reaction rate and the spatial extent of the reacting region decrease significantly with time. During a successful ignition event, small regions of the reacting kernel survive this dilution and are able to transition into a self-sustained flame after ∼1–2 ms. The low aromatic/low cetane number fuel, which also has the lowest ignition probability, takes much longer for the reaction zone to grow after the initial decay. The high aromatic, more easily ignited fuel, shows the largest reaction region at early times.

The effects of altitude and fuel composition on gaseous and particle emissions from a turbojet engine were investigated as part of the National Jet Fuels Combustion Program (NJFCP) effort. Two conventional petroleum based jet fuels (a “nominal” and a “worst-case” jet fuel) and two test fuels with unique characteristics were selected for this study. The “worst-case” conventional jet fuel with high flash point and viscosity resulted in reduced combustion efficiency supported by the reduced CO 2 emissions and corresponding increased CO and THC emissions. In addition, increased particle number (PN), particle mass (PM), and black carbon (BC) emissions were observed. Operating the engine on a bimodal fuel, composed of heavily branched C 12 and C 16 iso-paraffinic hydrocarbons with an extremely low cetane number did not significantly impact the engine performance or gaseous emissions but significantly reduced PN, PM, and BC emissions when compared to other fuels. The higher aromatic content and lower hydrogen content in the C-5 fuel were observed to increase PN, PM, and BC emissions. It is also evident that the type of aromatic hydrocarbons has a large impact on BC emissions. Reduction in combustion efficiency resulted in reduced CO 2 emissions and increased CO and THC emissions from this engine with increasing altitudes. PN emissions were moderately influenced by altitude but PM and BC emissions were significantly reduced with increasing altitude. The reduced BC emissions with increasing altitude could be a result of reduced combustion temperature which lowered the rate of pyrolysis for BC formation, which is supported by the NO x reduction trend.

Thermal stability is an important characteristic of alternative fuels that must be evaluated before they can be used in aviation engines. Thermal stability refers to the degree to which a fuel breaks down when it is heated prior to combustion. This characteristic is of great importance to the effectiveness of the fuel as a coolant and to the engine’s combustion performance. The thermal stability of Sasol IPK, a synthetic alternative to Jet-A, with varying levels of naphthalene has been studied on aluminum and stainless steel substrates at 300 to 400 °C. This was conducted using a spectroscopic ellipsometer to measure the thickness of deposits left on the heated substrates. Ellipsometry is an optical technique that measures the changes in a light beam’s polarization and intensity after it reflects from a thin film to determine the film’s physical and optical properties. It was observed that, as would be expected, increasing the temperature increased the deposit thickness for a constant concentration of naphthalene on both substrates. The repeatability of these measurements was verified using multiple trials at identical test conditions. Lastly, the effect of increasing the naphthalene concentration at a constant temperature was found to also increase the deposit thickness.

The development of higher thermal stability fuels and the development of onboard fuel deoxygenation systems may permit the preheating of fuel up to about 755 K before the onset of pyrolysis. At a sufficiently high fuel temperature for a given combustion chamber pressure, the flash vaporization of liquid or supercritical state fuel can ensue upon injection into the chamber. The performance of standard aviation turbine engine fuel nozzles, designed for mechanically breaking up liquid sprays, may thus be significantly altered by the employment of severely preheated fuel. An evaluation of heated and superheated Jet A-1 sprays from a pressure-swirl atomizer was implemented in a purpose-built test facility. Laser sheet imaging of the spray yielded simultaneous axial cross-sectional maps of Mie-scatter and fluorescence signals. In addition, particle image velocimetry was also used to measure the spray droplet velocity-field. The results indicated that increasing the fuel’s dimensionless level of superheat ΔT* from −1.8 to 0.6 yielded significant changes in the spray structure; specifically, finer droplet sizes, a more uniform dropsize distribution across the spray, increased spray cone angle till about ΔT* = −0.8 followed by a contraction thereafter, marginally increased spray penetration, and significantly higher localised near nozzle tip droplet velocities. The measurements supported the hypothesis that the initial hollow-cone spray structure evolves to a near solid-cone structure with a central vapour core as the fuel is superheated.

Recently, several studies have demonstrated that the addition of nanoscale high-energetic metal particles to liquid fuels as fuel additives has a positive effect not only on the combustion performance but also in reducing the pollutant formation. However, most of those studies were performed for conventional fuels with high volume concentrations of nanoparticles, which will have a considerable effect on the hydrodynamic and thermophysical properties of the fuel. Such a change in fuel properties can in turn affect the atomization, mixing and evaporation characteristics of the liquid fuels. This study investigates the spray performance of an alternative gas-to-liquid (GTL) jet fuel with the addition of alumina nanoparticles at atmospheric condition and compared with that of the pure fuel. Macroscopic and microscopic measurement of the spray characteristics are performed using optical diagnostic techniques. Results show that the addition of nanoparticles tends to reduce the liquid sheet breakup length when compared to that of the pure fuel case. Furthermore, the droplet size and droplet velocities are observed to be slightly different between the pure fuel and nanofuel cases.