In urban areas, pollutants are emitted from vehicles then disperse from the ground level to the downstream urban canopy layer (UCL) under the effect of the prevailing wind. For a hypothetical urban area in the form of idealized street canyons, the building-height-to-street-width (aspect) ratio (AR) changes the ground roughness which in turn leads to different turbulent airflow features. Turbulence is considered an important factor for the removal of reactive pollutants by means of dispersion/dilution and chemical reactions.

Three values of aspect ratio, covering most flow scenarios of urban street canyons, are employed in this study. The pollutant dispersion and reaction are calculated using large-eddy simulation (LES) with chemical reactions. Turbulence timescale and reaction timescale at every single point of the UCL domain are calculated to examine the pollutant removal. The characteristic mechanism of reactive pollutant dispersion over street canyons will be reported in the conference.

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