Concentrated Solar Power (CSP) is one of the most efficient mega-scale renewable Energy sources. However, the overall cost of energy production is not viable for commercial usage and supplanting with fossil fuels or energy produced by nuclear ways. Its operational cost mainly lies in the electrical and thermal systems of the plant. The thermal system comprises of heat storage and heat transfer system. Any enhancement to heat storage or transfer system will directly reduce the cost of operation and increase the yield. Conventionally, oils stable up to 400C were used to transfer and store heat, however more recently, molten salts have been operational in the field for purpose of heat transfer but still, their thermal storage and conduction are limited. The current work explores the possibility of boosting the thermal storage capacity of molten salts through the latent heat of added phase change materials and increasing the specific heat at the same time by adding silica encapsulated zinc nanoparticles. We studied the advantage of adding coated Zn nano-sized particles to carbonate eutectic mixture for enhanced thermal energy storage and heat capacity enhancement. Zinc particles (40nm–60nm) obtained from the commercial sources were coated with silica shells using the solgel process under alkaline conditions. The nano-capsules were then dispersed in a mixture of carbonate salts. A differential scanning calorimeter was employed to characterize the thermal properties of the mixture. Tranmission electron miocroscopy was employed to characterize nanoparticles and electron diffraction Spectroscopy was performed to characterize materials and strcutures involved.

A 1 MW t falling particle receiver prototype was designed, built and is being evaluated at Sandia National Laboratories, National Solar Thermal Test Facility (NSTTF). The current prototype has a 1 m 2 aperture facing the north field. The current aperture configuration is susceptible to heat and particle losses through the receiver aperture. Several options are being considered for the next design iteration to reduce the risk of heat and particle losses, in addition to improving the receiver efficiency to target levels of ∼90%. One option is to cover the receiver aperture with a highly durable and transmissive material such as quartz glass. Quartz glass has high transmittance for wavelengths less than 2.5 microns and low transmittance for wavelengths greater than 2.5 microns to help trap the heat inside the receiver. To evaluate the receiver optical performance, ray-tracing models were set up for several different aperture cover configurations. The falling particle receiver is modeled as a box with a 1 m 2 aperture on the north side wall. The box dimensions are 1.57 m wide × 1.77 m tall × 1.67 m deep. The walls are composed of RSLE material modeled as Lambertian surfaces with reflectance of either 0.9 for the pristine condition or 0.5 for soiled walls. The quartz half-shell tubes are 1.46 m long with 105 mm and 110 mm inner and outer diameters, respectively. The half-shell tubes are arranged vertically and slant forward at the top by 30 degrees. Four configurations were considered: concave side of the half-shells facing away from the receiver aperture with (1) no spacing and (2) high spacing between the tubes, and concave side of the half-shells facing the aperture with (3) no spacing and (4) high spacing between the tubes. The particle curtain, in the first modeling approach, is modeled as a diffuse surface with transmittance, reflectance, and absorptance values, which are based on estimates from previous experiments for varying particle flow rates. The incident radiation is from the full NSTTF heliostat field with a single aimpoint at the center of the receiver aperture. The direct incident rays and reflected and scattered rays off the internal receiver surfaces are recorded on the internal walls and particle curtain surfaces as net incident irradiance. The net incident irradiances on the internal walls and particle curtain for the different aperture cover configuration are compared to the baseline configuration. In all cases, just from optical performance alone, the net incident irradiance is reduced from the baseline. However, it is expected that the quartz half-shells will reduce the convective and thermal radiation losses through the aperture. These ray-tracing results will be used as boundary conditions in computational fluid dynamics (CFD) analyses to determine the net receiver efficiency and optimal configuration for the quartz half-shells that minimize heat losses and maximize thermal efficiency.

Particle-based power tower systems are a promising technology that can allow operation of concentrating solar power (CSP) systems at temperatures higher than what today’s commercial molten salt systems can achieve, making them suitable for use in a variety of applications, including supercritical CO 2 cycles, air Brayton cycles, and high-temperature process heat. In this concept, particles, instead of molten salt, are heated by the concentrated sunlight. In 2015, this concept was successfully tested at Sandia National Laboratories. In the mean time, an integrated system incorporating a particle heating receiver, a particle-to-air heat exchanger and a 100-kWe microturbine was designed, built, and tested at King Saud University in Riyadh, Saudi Arabia. The integrated system was run in 2018, and results from that test campaign were very promising, with temperatures of the particles leaving the receiver exceeding 600°C despite a number of challenges. The utility sponsoring the project is now planning to move forward with building a 1-MWe plant using the same concept, thereby moving closer to large-scale deployment, and making this facility the world’s first commercial concentrating solar power plant that uses the particle heating receiver concept. Moving from a 100-kWe scale to a 1-MWe scale requires modifications to the design of some components. The most likely plant location is the city of Duba in northwestern Saudi Arabia where the average daily total DNI is 7,170 Wh/m 2 and an integrated solar combined cycle power plant exists on the premises. This paper discusses the design features of the main components of the new plant. Those features include a north field design, a 7.22-m 2 single-sheet heliostat design, a cavity receiver to improve receiver efficiency by reducing radiative and convective losses, temperature-based particle flow regulation within the receiver, six hours of full-load thermal energy storage, with the tanks integrated into the tower structure and made of cost-effective masonry material, a shell-and-tube particle-to-air heat exchanger, a 45% efficiency recuperated intercooled gas turbine, and a high-temperature bucket elevator. The heliostat field was optimized using SolarPILOT. Results show that 1,302 heliostats are needed. The aperture area was found to be approximately 5.7 m 2 , while the total illuminated receiver surface area is about 16.8 m 2 . This design was found to be capable of achieving the particle temperature rise of 416°C, which is necessary to allow the turbine to rely entirely on the solar field to bring the temperature of air to the firing temperature of the turbine, thereby eliminating the need for fuel consumption except for back-up and for assistance at off-design conditions.

This paper presents an evaluation of alternative particle heat-exchanger designs, including moving packed-bed and fluidized-bed designs, for high-temperature heating of a solar-driven supercritical CO 2 (sCO2) Brayton power cycle. The design requirements for high pressure (≥ 20 MPa) and high temperature (≥ 700 °C) operation associated with sCO2 posed several challenges requiring high-strength materials for piping and/or diffusion bonding for plates. Designs from several vendors for a 100 kW-thermal particle-to-sCO2 heat exchanger were evaluated as part of this project. Cost, heat-transfer coefficient, structural reliability, manufacturability, parasitics and heat losses, scalability, compatibility, erosion and corrosion, transient operation, and inspection ease were considered in the evaluation. An analytical hierarchy process was used to weight and compare the criteria for the different design options. The fluidized-bed design fared the best on heat transfer coefficient, structural reliability, scalability and inspection ease, while the moving packed-bed designs fared the best on cost, parasitics and heat losses, manufacturability, compatibility, erosion and corrosion, and transient operation. A 100 kW t shell-and-plate design was ultimately selected for construction and integration with Sandia’s falling particle receiver system.

Researchers are committed to develop robust and responsive technologies for renewable energy sources to avert from reliance on fossil fuels, which is the main cause of global warming and climate change. Solar energy based renewable energy technologies are valued as an important substitute to bridge gap between energy demand and generation. However, due to varying and inconsistent nature of solar energy during weather fluctuations, seasonal conditions and night times, the complete utilisation of technology is not guaranteed. Therefore, thermal energy storage (TES) system is considered as an imperative technology to be deployed within solar energy systems or heat recovery systems to maximise systems efficiency and to compensate for varying thermal irradiance. TES system can capture and store the excess amount of thermal energy during solar peak hours or recover from systems that would otherwise discard this excess amount of thermal energy. This stored energy is then made available to be utilised during solar off peak hours or night times. Phase change material (PCM) based TES system is appraised as a viable option due to its excellent adoption to solar and heat recovery systems, higher thermal storage density and wide range of materials availability. However, due to its low thermal conductivity (≅ 0.2 W/mK), the rapid charging and discharging of TES system is a challenge. Therefore, there is a need for efficient and responsive heat exchange mechanism to boost the heat transfer within PCM. In this study, transient analysis of two-dimensional computational model of vertical shell and tube based TES system is conducted. Commercial grade paraffin (RT44HC) is employed in shell as thermal storage material due to its higher thermal storage density, thermo-physical stability and compatibility with container material. Water is made to flow in tubes as heat transfer fluid. In this numerical study, the parametric investigations are performed to determine the enhancement in charging rate, discharging rate and thermal storage capacity of TES system. The parametric investigations involve geometrical orientations of tubes in shell with and without fins, inlet temperature and volume flow rate of HTF. It is evident from numerical results that due to increase in effective surface area for heat transfer by vertical fins, the charging and discharging rate of paraffin based TES system can be significantly increased. Due to inclusion of vertical fins, conduction heat transfer is dominant mode of heat transfer in both charging and discharging processes. Furthermore, vertical fins do not restrict natural convection or buoyancy driven flow as compared to horizontal fins. Similarly, the inlet temperature has a noticeable impact on both charging and discharging process. In melting process, the sensible enthalpy is boosted due to rise in inlet temperature and thus the whole system thermal storage capacity is enhanced. Likewise, the effect of volume flow rate of HTF on charging and discharging rate is moderate as compared to inlet temperature of HTF. The numerical results are validated by experimental results. To conclude, these findings present an understanding into how to increase charging and discharging rate of TES system so as to provide feasible design solutions for widespread domestic and commercial utilisation of TES technology.

Efficient and cost-effective thermal energy storage system plays an important role in energy conservation. Elemental sulfur, the thirteenth most abundant element on earth, is actively being researched as a potential thermal storage medium due to its high energy storage density and low cost. The present work investigates the heat transfer behavior of elemental sulfur at temperatures between 50 degree Celsius and 250 degree Celsius. A shell and tube heat exchanger configuration with sulfur stored inside the tubes and heat transfer fluid flowing over the tubes through the shell is considered. A detailed computational model solving for the conjugate heat transfer and solid-liquid phase change dynamics of the sulfur based thermal energy storage system is developed to elucidate the complex interplay between the governing heat transfer and fluid flow phenomena during charge and discharge operations. The developed numerical model is compared with experimental results and a systematic parametric analysis of the effects of various design parameters on the performance of the thermal storage system is reported.

In European countries seasonal thermal energy storage is an emergent task due to availability of solar energy in summer and thermal energy demand in winter. In this study the performance of an uninsulated buried storage tank is analyzed. Summer temperatures reached 45 °C in the storage tank and 22 °C in the soil, 1 m from the tank shell. Wintertime temperature of the storage tank dropped to 8 °C, near the freezing limit of the heat pump, and soil cooled down to 9 °C. While in wintertime heat transfer from earth to water was the limiting factor, a summertime temperature difference of more than 20 °C allowed enough energy transport to charge the soil storage system. An analytical model showed that more than 50% of the solar energy stored could be recovered by this application.

The melting and solidification process of sodium nitrate, which is used as energy storage material, is studied in a vertical arranged energy storage device with two different bimetal finned tube designs (with and without transversal fins) for enhancing the heat transfer. The finned tube design consists of a plain steel tube while the material for the longitudinal (axial) fins is aluminum. The investigation analyses the influence of the transversal fins on the charging and discharging process. 3-dimensional transient numerical simulations are performed using the ANSYS Fluent 14.5 software. The results show that every obstruction given by transversal fins reduces the melting and solidification velocity in direction to the outer shell. In the present study also a comparison of the simulation results between 2D and 3D simulation of the melting and solidification behavior of the sodium nitrate is presented.

In this paper the results of a numerical investigation of the melting and solidification process of sodium nitrate, which is used as phase change material, will be presented. For the heat transfer to the sodium nitrate different finned tube designs, namely helical-, transversal- and longitudinal finned tubes, are used. The numerical results of the melting and solidification process for the different design cases will be compared. The numerical analysis of the melting process has shown that apart from the first period of the charging process natural convection is the dominant heat transfer mechanism. The numerical analysis of the melting process has also shown that for a fast melting process heat exchanger tubes should be designed in such a way that an unrestricted natural convection is guaranteed. The numerical investigation for the solidification process has shown that the dominant heat transfer mechanism is heat conduction. The investigation has also shown that the solidification front grows more uniformly from the tube surface to the outer shell compared to the melting front. Therefore no significant differences between the different tube designs are detected concerning the solidification process.

The Riyadh Techno Valley Solar Tower, an innovative type of concentrator solar power plant, is being developed by King Saud University (KSU) and Georgia Tech (GT). The facility is being constructed at the Riyadh Techno Valley development near the KSU campus and will store thermal energy collected from the sun in solid particles, which can be heated to higher temperatures than is currently possible using molten salts. The particles must be well insulated to stop energy loss to the environment. Hence, GT and KSU have incorporated an insulated storage bin into the plant design. The bin will be constructed in several layers: an inner layer of firebrick, which can endure direct exposure to the heated particles; a specially prepared refractory insulating concrete, which maintains good insulating value at high temperatures; and a conventional structural concrete shell surrounding the entire bin. This paper presents a thermal analysis of this storage device and discusses structural analyses. Simplified analytical solutions are compared with the finite element results from a 3D ANSYS model of the entire bin. A temperature distribution is obtained, and heat loss through the bin is also evaluated. Modeling of rebar and concrete cracking are described, and methods of reducing stress on the outer concrete shell are considered. Structural support for an access tunnel into the bin is also explored. The current tunnel design involves a material with a relatively high thermal conductivity, necessitating modifications to the bin. Finally, material selection is considered, particularly with regard to the insulating concrete layer. Limitations on the use of Portland cement based insulating concretes are discussed, and alternative base materials are evaluated.

An alternate to the two-tank molten salt thermal energy storage system using supercritical fluids is presented. This technology can enhance the production of electrical power generation and high temperature technologies for commercial use by lowering the cost of energy storage in comparison to current state-of-the-art molten salt energy storage systems. The volumetric energy density of a single-tank supercritical fluid energy storage system is significantly higher than a two-tank molten salt energy storage system due to the high compressibilities in the supercritical state. As a result, the single-tank energy storage system design can lead to almost a factor of ten decrease in fluid costs. This paper presents results from a test performed on a 5 kWht storage tank with a naphthalene energy storage fluid as part of a small preliminary demonstration of the concept of supercritical thermal energy storage. Thermal energy is stored within naphthalene filled tubes designed to handle the temperature (500 °C) and pressure (6.9 MPa or 1000 psia) of the supercritical fluid state. The tubes are enclosed within an insulated shell heat exchanger which serves as the thermal energy storage tank. The storage tank is thermally charged by flowing air at >500 °C over the storage tube bank. Discharging the tank can provide energy to a Rankine cycle (or any other thermodynamic process) over a temperature range from 480 °C to 290 °C. Tests were performed over three stages, starting with a low temperature (200 °C) shake-out test and progressing to a high temperature single cycle test cycling between room temperature and 480 °C and concluding a two-cycle test cycling between 290 °C and 480 °C. The test results indicate a successful demonstration of high energy storage using supercritical fluids.

Phase-change materials (PCMs) can store large amounts of heat without significant change of their temperature during the phase-change process. This effect may be utilized in thermal energy storage, especially for solar-thermal power plants. In order to enhance the rate of heat transfer into PCMs, one of the most common methods is the use of fins which increase the heat transfer area that is in contact with the PCM. The present work deals with a latent heat thermal storage device that uses a finned tube with an array of radial fins. A heat transfer fluid (HTF) flows through the tube and heat is conducted from the tube to the radial fins that are in contact with the bulk of the PCM inside a cylindrical shell. The thermal storage charging/discharging process is driven by a hot/cold HTF inside the tube that causes the PCM to melt/solidify. The main objective of the present work is to demonstrate that close-contact melting (CCM) can affect the storage unit performance. Accordingly, two different types of experiments are conducted: with the shell exposed to ambient air and with the shell submerged into a heated water bath. The latter is done to separate the PCM from the shell by a thin molten layer, thus enabling the solid bulk to sink. The effect of the solid sinking and close-contact melting on the fins is explored. It is found that close-contact melting shortens the melting time drastically. Accordingly, two types of models are used to predict the melting rate: numerical CFD model and analytical/numerical close-contact melting model. The CFD model takes into account convection in the melt and the PCM property dependence on temperature and phase. The analytical/numerical CCM model is developed under several simplifying assumptions. Good agreement is found between the predictions and corresponding experimental results.

Thermal energy storage (TES) is a vital component of concentrated solar power (CSP). TES makes up for intermittent solar radiation, bad weather, and peak power demand. Currently, a sensible heat storage system using two tanks containing molten salt is considered the most practical and economical TES. Yet further system development is needed in order to improve its performance and economics. In this study of molten salt storage tanks, spherical tanks were investigated as an alternative to cylindrical tanks. Structural and thermal aspects of cylindrical tanks with varying H/D ratios (0.25–5) and spherical tanks of the same volume were compared. Comparison showed that utilization of spherical instead of cylindrical tanks resulted in significant savings in shell building material (28–47%). Heat transfer from the spherical tank’s shell is at least 35% less than cylindrical tanks. Reduction in building material, foundation, and insulation cost can lead to significant cost savings.

A novel approach to storing thermal energy with supercritical fluids is being investigated, which if successful, promises to transform the way thermal energy is captured and utilized. The use of supercritical fluids allows cost-affordable high-density storage with a combination of latent heat and sensible heat in the two-phase as well as the supercritical state. This technology will enhance penetration of several thermal power generation applications and high temperature water for commercial use if the overall cost of the technology can be demonstrated to be lower than the current state-of-the-art molten salt using sodium nitrate and potassium nitrate eutectic mixtures. An additional attraction is that the volumetric storage density of a supercritical fluid can be higher than a two-tank molten salt system due to the high compressibilities in the supercritical state. This paper looks at different elements for determining the feasibility of this storage concept — thermodynamics of supercritical state with a specific example, naphthalene, fluid and system cost and a representative storage design. A modular storage vessel design based on a shell and heat exchanger concept allows the cost to be minimized as there is no need for a separate pump for transferring fluid from one tank to another as in the molten salt system. Since the heat exchangers are internal to the tank, other advantages such as lower parasitic heat loss, easy fabrication can be achieved. Results from the study indicate that the fluid cost can be reduced by a factor of ten or even twenty depending on the fluid and thermodynamic optimization of loading factor. Results for naphthalene operating between 290 °C and 475 °C, indicate that the fluid cost is approximately $3/kWh compared with $25-$50/kWh for molten salt. When the storage container costs are factored in, the overall system cost is still very attractive. Studies for a 12-hr storage indicate that for operating at temperatures between 290–450 °C, the cost for a molten salt system can vary between $66/kWh to $184/kWh depending on molten salt cost of $2/kg or a more recent quote of $8/kg. In contrast, the cost for a 12-hr supercritical storage system can be as low as $40/kWh. By using less expensive materials than SS 316L, it is possible to reduce the costs even further.

Palm kernel shell is an important by-product of oil palm production. It is often neglected and handled as waste in the product mix of palm oil production. One kilogram of PKS was pyrolized in a bench scale pyrolysis screw reactor at temperature range of 450°C to 500°C in 10mins. The process yielded 61 wt%, 24.5 wt% and 14 wt% bio-oil, bio-char and non condensable flammable gas respectively. Palm Kernel shell is relatively abundant in the tropical West Africa and Asia. Until recently PKS is commonly combusted for cooking purposes which contributes to total GHG emission. The products were characterized by determining their physical and chemical properties using standard methods. The thermochemical conversion shows that there is 29% and 26% increase in the higher heating values and lower heating values (on dry basis) respectively, of the bio-oil obtained when compared with the energy values of the original PKS. Similarly, the HHV of the bio-char is 62% higher than that of the original PKS. In addition the results of the GC-MS analysis of the bio-oil show that it contains useful chemicals that can be harnessed for industrial applications. The ash content of the bio-oil and the original PKS sample are 0.37% and 8.68% respectively, on as received, while the results of the elemental analyses show that there is < 0.08% and < 0.05% sulphur content of the PKS and its bio-oil respectively. This makes the products an environmentally suitable fuels for transportation and power generation. The results of this work show that the products compare well with those of other woody samples used for commercial pyrolysis process. PKS bio-char possesses the potential to be used as industrial absorbent in water treatment and process technology. Hence, PKS can be harnessed as potential future source of bio-energy and Activated carbon, and as such should be given adequate attention as a major product of oil palm processing for sustainable economic development of emerging economies.

Concentrated solar power plants (CSP) are being explored as the leading source of renewable energy for future power generation. Storing sun’s energy in the form of latent thermal energy of a phase change material (PCM) is desirable for use on demand including times when solar energy is unavailable. Considering a latent thermal energy storage (LTES) system incorporating heat pipes to enhance heat transfer between the heat transfer fluid (HTF) and the PCM, this paper explores the dynamic response of the LTES system subjected to repeated cycles of charging and discharging. A transient computational analysis of a shell-and-tube LTES embedded with two horizontal heat pipes (HHP) is performed for repeated charging and discharging of the PCM to analyze the dynamic performance of the LTES and the augmentation in the cyclic performance of the LTES embedded with heat pipes is investigated. A model low temperature phase change material system is considered in the present study, with the physical results being scalable to high temperature systems used in CSP plants.

Phase-change systems remain to be widely used for storage of thermal energy such as the energy harnessed by solar collectors. The major disadvantage of phase change materials (PCMs) is their low thermal conductivities, which drastically slows the phase change process and causes wide temperature variations within PCMs, while requiring heat transfer area. Metal foams are one class of porous media that possess thermal conductivities that are an order of magnitude higher than PCMs. When embedded in PCMs, the random internal structure and high porosity of metal foam enhance and accelerate the phase change process without significantly reducing PCMs’ heat storage capacity. Unlike traditional PCM systems, the distribution of the foam ligaments in PCMs makes the melting and solidification processes uniform and less dependent on location inside PCMs. This also leads to shorter charging and discharging times. The design, fabrication and characterization of a small PCM-metal-foam thermal storage system are described in this paper. The core of the system is a cylindrical shell composed of 90%-porous open-cell aluminum foam filled with Paraffin-based PCM. The foam occupies only 10% of the total volume. The shell walls were fabricated from copper. The system was tested in an open loop wind tunnel. Results for the convection heat transfer coefficient and the effect of volumetric flow rate on the system’s performance were obtained. The heat transfer rate from the system was computed and discussed.

In this paper, the new approach of Constructal theory has been employed to design shell and tube heat exchangers. Constructal theory is a new method for optimal design in engineering applications. The purpose of this paper is optimization of shell and tube heat exchangers by reduction of total cost of the exchanger using the constructal theory. The total cost of the heat exchanger is the sum of operational costs and capital costs. The overall heat transfer coefficient of the shell and tube heat exchanger is increased by the use of constructal theory. Therefore, the capital cost required for making the heat transfer surface is reduced. Moreover, the operational energy costs involving pumping in order to overcome frictional pressure loss are minimized in this method. Genetic algorithm is used to optimize the objective function which is a mathematical model for the cost of the shell and tube heat exchanger and is based on constructal theory. The results of this research represent more than 50% reduction in costs of the heat exchanger.

An experimental study on the effects of secondary combustion on efficiencies and emission reduction in the Diesel engine boiler system has been undertaken. The co-generation concept is utilized in that the electric power is produced by the generator connected to the Diesel engine, and heat is recovered from both combustion exhaust gases and the engine by the fin-and-tube and shell-and-tube heat exchangers, respectively. A specially designed secondary combustor is installed at the engine outlet in order to reburn the unburned fuel from the Diesel engine, thereby improving the system’s efficiency as well as reducing air pollution caused by exhaust gases. The main components of the secondary combustor are coiled Nichrome wires heated by the electric current and Diesel Oxidation Catalyst (DOC) housed inside a well insulated stainless steel shell. The performance tests were conducted at four water flow rates of 5, 10, 15 and 20 L/min and five electric power outputs of 3, 5, 7, 9 and 11 kW. The results show that at a water flow of 20 L/min and a power output of 9 kW, the total efficiency (thermal efficiency plus electric power generation efficiency) of this system reaches a maximum 94.4% which is approximately 20% higher than that of the typical Diesel engine boiler system. Besides, the use of the secondary combustor and heat exchangers results in 80%, 35%, and 90% reduction of carbon monoxide (CO), nitrogen oxide (NO x ) and particulate matter (PM), respectively.

Thermochemical conversion process has become a viable technology for managing excess waste from various industries while producing value added fuel products. In the work reported here, distribution of products (solid, liquid, and gas) by thermal conversion of wastes from biodiesel production process which are extracted physic nut and palm shell mixed with glycerol waste was carried out using a medium scale tubular reactor with feeding rate of 5 g/min. Several important operating parameters were studied including the proportion of each waste (100:0 – 70:30), reaction temperature (700 – 900°C) and air to fuel ratio (AF) 0.0 – 0.6. It was found that when the temperature increased, the quantity of solid and liquid product decreased while gas product increased. For conversion to CO 2 , CO, C x H y and H 2 , when the temperature increased, CO 2 decreased while yields of CO, CH 4 and H 2 increased. Greater conversion to CO 2 , CO, H 2 with AF increased from 0.0 to 0.3. Higher AF from 0.3 to 0.6 resulted in lesser CO and H 2 while conversion to CO 2 increased. On the other hand, C x H y decreased when AF changed from 0.0 to 0.6. The maximum heating values of gas product in this study are 3.48 MJ/m 3 and 2.27 MJ/m 3 for glycerol waste mixed with physic nut waste and palm shell waste, respectively (both at 30% glycerol wastes and reaction temperature of 900°C). The maximum of mole ratio of H 2 to CO obtained is 0.59 for physic nut and 0.37 for palm shell mixed wastes. Relatively high C x H y , low product gas heating value and H 2 to CO ratio indicated the need for further product upgrading before using as raw material for other advanced fuel production processes such as Fisher-Tropsch, DME, or methanol syntheses beside direct heat and power utilization.