Experimental Verification of Expedited Freezing of Nanoparticle-Enhanced Phase Change Materials (NEPCM)

Highly-conductive nano-sized particles are dispersed into phase change materials (PCM) to improve their effective thermal conductivity, thus leading to suspensions that are referred to as nanoparticle-enhanced PCM (NEPCM). In order to assess the extent of expedited phase change due to the enhanced thermal conductivity, the one-dimensional unidirectional freezing process of NEPCM in a finite slab was investigated experimentally. Thermocouple readings were recorded at several equally-spaced locations along the freezing direction in order to monitor the progress of the freezing front. As an example, cyclohexane (C₆H₁₂) and copper oxide (CuO) nanoparticles were chosen to develop the NEPCM with three different volume fractions (0.5, 1.0, and 2.0 vol%). It was shown that the freezing rate for the 0.5 vol% NEPCM is considerably raised as compared to pure cyclohexane. However, further increase of the fraction of nanoparticles to 1.0 and 2.0 vol% did not linearly expedite freezing. Significant sedimentation of nanoparticles was observed for the 2.0 vol% NEPCM. Additionally, in this case the undesirable supercooling phenomenon was enhanced, which suppresses the growth rate of the solidified NEPCM.